VERFAHREN ZUR VERWERTUNG EINER BATTERIE
    2.
    发明公开

    公开(公告)号:EP4435904A1

    公开(公告)日:2024-09-25

    申请号:EP23163520.2

    申请日:2023-03-22

    Abstract: Die Erfindung betrifft ein Verfahren zur Verwertung einer Batterie, umfassend die Schritte: (a) Bereitstellen einer zumindest teilweise entladenen Batterie, (b) Zerkleinern der zumindest teilweise entladenen Batterie in einem Prozessraum (11), um Batterieteile zu erhalten, (c) Trocknen der Batterieteile in einem Prozessraum (11), um getrocknete Batterieteile und ein abgetrenntes Gas zu erhalten, und (d) Verpacken der getrockneten Batterieteile in eine Verpackung, dadurch gekennzeichnet, dass die Schritte (b) und (c) im selben Prozessraum (11) durchgeführt werden. Die Erfindung betrifft weiters eine mobile Vorrichtung zur Verwertung einer Batterie mit dem Verfahren, und eine Verpackung, in welcher 1 bis 30 kg Batterieteile enthalten sind, erhältlich durch das Verfahren.

    RECYCLED CATHODE ACTIVE MATERIAL, METHOD FOR RECYCLING CATHODE ACTIVE MATERIAL, AND SECONDARY BATTERY COMPRISING SAME

    公开(公告)号:EP4428955A1

    公开(公告)日:2024-09-11

    申请号:EP23835730.5

    申请日:2023-06-26

    Abstract: The present invention relates to a recycled positive electrode active material, a method of recycling a positive electrode active material, and a secondary battery including the recycled positive electrode active material. More particularly, the present invention relates to a recycled positive electrode active material including one or more selected from the group consisting of a lithium nickel oxide (LNO)-based positive electrode active material, a nickel·cobalt·manganese (NCM)-based positive electrode active material, a nickel·cobalt·aluminum (NCA)-based positive electrode active material, and a nickel·cobalt·manganese·aluminum (NCMA)-based positive electrode active material, including 60 mol% or more of Ni, containing fluorine (F) in an amount of 250 mg/kg or less, and having a crystallite size of 122 nm or less, a method of recycling a positive electrode active material, and a secondary battery including the recycled positive electrode active material. According to the present invention, the present invention has an effect of providing a positive electrode active material prepared by introducing oxygen into a waste positive electrode containing a high-nickel (Ni) positive electrode material, performing oxidation heat treatment, performing first washing, adding a lithium precursor, performing annealing, and performing second washing to reduce the amount of fluorine (F) on the surface of a recycled positive electrode active material, wherein the oxidation heat treatment is performed in two steps to completely burn a binder, reduce fluorine (F) and residual lithium generated in the heat treatment step, and reduce a crystallite size; and having excellent capacity, resistance characteristics, and capacity characteristics. In addition, the present invention has an effect of providing a method of recycling a positive electrode active material, characterized in that eco-friendliness is secured by not using acids in recovery and recycling processes; process cost is reduced because neutralization and wastewater treatment are not required accordingly; no metal element is discarded by recycling a positive electrode active material in an intact state without disassembling the positive electrode active material; the risk of toxic gas generation or explosion is excluded by not using an organic solvent; and economic feasibility and productivity are greatly improved by omitting a washing process.

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