RECYCLING METHOD FOR WASTE LITHIUM ION SECONDARY BATTERIES AND ELECTRODE RAW MATERIALS OBTAINED THEREFROM

    公开(公告)号:EP4509621A1

    公开(公告)日:2025-02-19

    申请号:EP24158882.1

    申请日:2024-02-21

    Abstract: An object of the invention is to provide a method for economically and eco-friendly recovering an electrode raw material for a positive electrode and a negative electrode from a waste lithium ion secondary battery, which is formed by the pyrolysis of a waste lithium ion secondary battery, and an electrode raw material for a positive electrode and a negative electrode, obtained therefrom. To accomplish the object, a recycling method of a waste lithium ion secondary battery according to the invention may include (a) loading a waste lithium ion secondary battery into a pyrolysis furnace, (b) increasing the internal temperature of the pyrolysis furnace to induce self-heating of the waste lithium ion secondary battery, (c) maintaining a self-heating reaction of the waste lithium ion secondary battery, (d) discharging a first powder formed after completing the self-heating reaction of the waste lithium ion secondary battery, and (e) injecting the first powder into water, dissolving a lithium component included in the first powder, and separating and recovering a lithium aqueous solution, a powder settled in the lithium aqueous solution, and a floating material on the surface of the lithium aqueous solution, separately.

    VERFAHREN ZUR GEWINNUNG VON LITHIUM BEI DER VORBEREITUNG DES RECYCLINGS VON LITHIUM-IONEN-BATTERIEN

    公开(公告)号:EP4509620A2

    公开(公告)日:2025-02-19

    申请号:EP24181512.5

    申请日:2024-06-11

    Abstract: Die Erfindung betrifft ein Verfahren zur Gewinnung von Lithium bei der Vorbereitung des Recyclings von Lithium-Ionen-Batterien (22), umfassend: Durchführen eines Zerkleinerungsvorgangs, wobei wenigstens eine Lithium-Ionen-Batterie (22) in Anwesenheit eines mit der Lithium-Ionen-Batterie (22) in Kontakt stehenden Schutzfluids (24) in Teilstücke (26) mechanisch zerkleinert wird, im Anschluss an den Zerkleinerungsvorgang, Hindurchleiten des Schutzfluids (24) durch ein Sorbens (20), wobei in dem Schutzfluid (24) enthaltene Lithiumionen durch das Sorbens (20) gebunden werden und ein mit Lithiumionen angereichertes Sorbens (20) erhalten wird, und Hindurchleiten eines Desorptionsfluids (32) durch das mit Lithiumionen angereicherte Sorbens (20), wobei Lithiumionen durch das Desorptionsfluid (32) von dem Sorbens (20) desorbiert werden und ein mit Lithiumionen angereichertes Desorptionsfluid (32) erhalten wird.

    SYSTEM FOR RECOVERING LITHIUM OF WASTE CATHODE MATERIAL

    公开(公告)号:EP4467673A1

    公开(公告)日:2024-11-27

    申请号:EP24173737.8

    申请日:2024-05-02

    Abstract: Disclosed is a system for recovering lithium of a waste cathode material, including: a heat-treating unit configured to heat-treat a waste cathode material to convert into soluble and insoluble materials; a water-leaching unit configured to leach the heat-treated waste cathode material with water to separate into an insoluble material and a water-leached solution comprising a lithium ion and a carbonate ion; and an reverse osmosis (RO) concentration unit configured to concentrate the water-leached solution using reverse osmosis, and a concentration of a lithium ion in the water-leached solution which is separated from the water-leaching unit may be 2,000 ppm or less.

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