摘要:
This method enables the use of nanowire or nano-textured forms of Polyaniline and other conductive polymers in energy storage components. The delicate nature of these very high surface area materials are preserved during the continuous electrochemical synthesis, drying, solvent application and physical assembly. The invention also relates to a negative electrode that is comprised of etched, lithiated aluminum that is safer and lighter weight than conventional carbon based lithium-ion negative electrodes. The invention provides for improved methods for making negative and positive electrodes and for energy storage devices containing them. The invention provides sufficient stability in organic solvent and electrolyte solutions, where the prior art processes commonly fail. The invention further provides stability during repetitive charge and discharge. The invention also provides for novel microstructure protecting support membranes to be used in an energy storage device.
摘要:
A method of producing an anode unit, whose active material consists of an alloy of an alkaline metal and a host metal therefore. An elongated element of the host metal is enclosed in a separator in form of a hollow fibre and is put in electrochemical contact with an organic solution of the alkaline metal, which migrates through the hollow fibre wall for alloying the host metal element. In a preferred embodiment strips are punched out at distances from each other in a sheet of the host metal and films of hollow fibre material, laid on the two surfaces of the sheet, are welded together in the openings left after the punching for forming hollow fibres.
摘要:
The present invention is a negative electrode active material for a negative electrode material of a non-aqueous electrolyte secondary battery, including a silicon-based material expressed by SiO x where 0.5‰¤x‰¤1.6 and either or both of a crystalized fluorine compound and a compound containing -CF 2 -CF 2 - units in at least a part of a surface layer of the negative electrode active material, the silicon-based material containing at least one of Li 6 Si 2 O 7 , Li 2 Si 3 O 5 , and Li 4 SiO 4 . There can be provided a negative electrode active material that can increase the battery capacity and improve the cycle performance and initial charge and discharge performance when used for a lithium-ion secondary battery, as well as a lithium-ion secondary battery having a negative electrode using this negative electrode active material.
摘要翻译:本发明是一种用于非水电解质二次电池的负极材料的负极活性材料,其包含以SiO x表示的硅基材料,其中0.5׉×1.6,并且结晶的氟化合物 以及在所述负极活性物质的表层的至少一部分中含有-CF 2 -CF 2 - 单元的化合物,所述硅基材料含有Li 6 Si 2 O 7,Li 2 Si 3 O 5和Li 4 SiO 4。 可以提供一种负极活性物质,该负极活性物质可以提高电池容量,提高用于锂离子二次电池时的循环性能和初期充放电性能,并且可以提供使用了负极的锂离子二次电池 这种负电极活性材料。
摘要:
The invention relates to a method for operating a lithium-ion battery including at least one cell that includes: a negative electrode (14) (the first electrode) and a positive electrode (11) (the second electrode), between which a lithium-ion-conducting electrolyte is placed, and a third lithium-ion source electrode. Said method includes: a) a step for preparing said first electrode, said step including a lithiation operation, via the third electrode, of an electrode including a material made of at least one metal or semi-metal element M capable of forming an alloy with lithium such as to obtain said first electrode, including an active material that includes an alloy of at least one metal or semi-metal element M and lithium in a molar ratio Li/M up to 5, said step also being carried out under conditions sufficient to obtain said active material having a molar ratio Li/M (M being the metal or semi-metal element M as defined above) at least equal to 1/3 of the molar ratio when said material is completely alloyed with lithium; and b) a step of operation of said battery via cycling in lithium, between said negative electrode and said positive electrode, without totally delithiating said negative electrode, said step being carried out in a capacity domain corresponding to, at most, 2/3 of the total reversible capacity of the active material of said negative electrode.
摘要:
A method for forming lithium electrodes having protective layers involves plating lithium (16) between a lithium ion conductive protective layer (18) and a current collector (14) of an 'electrode precursor'. The electrode precursor is formed by depositing the protective layer on a very smooth surface of a current collector. The protective layer is a glass such as lithium phosphorus oxynitride and the current collector is a conductive sheet such as a copper sheet. During plating, lithium ions move through the protective layer and a lithium metal layer plates onto the surface of the current collector. The resulting structure is a protected lithium electrode. To facilitate uniform lithium plating, the electrode precursor may include a 'wetting layer' which coats the current collector.