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公开(公告)号：EP0486698B1
公开(公告)日：1995-11-08
申请号：EP91910631.0
申请日：1991-06-07
发明人： MORITA, Mitsuru, Nippon Steel Corporation , KIMURA Keiichi, Nippon Steel Corporation , MIYAMOTO, Katsuyoshi, Nippon Steel Corporation , SAWANO, Kiyoshi, Nippon Steel Corporation , TAKEBAYASHI, Seiki, Nippon Steel Corporation , TANAKA, Masamoto, Nippon Steel Corporation
CPC分类号： H01L39/2419 , C04B35/4508 , C04B35/653 , C30B11/00 , C30B29/225 , H01L39/128 , Y10S505/778 , Y10S505/779 , Y10S505/78 , Y10S505/785
摘要： A superconductor comprising a composite oxide of rare earth elements (RE), barium and copper, wherein RE2BaCuO5 phases (211 phases) are finely dispersed in a single crystal REBa2Cu3O7-x phase (123 phase) and the 123 phase is composed of a multiplicity of layers corresponding to the composition of the RE arranged in the order of the 123 phase forming temperature; and a process for producing the superconductor which comprises forming a layer from a powdery mixture of oxides of the RE, barium and copper and also layers from other powdery mixtures of oxides of RE, barium and copper corresponding to other compositions of RE having different 123 phase forming temperatures from that of the abovementioned composition of RE to give a multilayered structure wherein the multiplicity of the layers are laminated in the ascending or descending order of the 123 phase forming temperatures thereof, press forming the laminate into a precursor, placing the precursor on a support material in such a manner that the layer having the highest 123 phase forming temperature among them forms the outermost layer, bringing it into a semi-molten state by heating in a temperature range where solid and liquid are coexistent, and cooling it slowly in the 123 phase forming temperature range, optionally after seeding with seed crystals, to grow 123 phase crystals at a rate of 5 mm/hr or less.
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2.发明授权Method of manufacturing oxide superconductor, and method of manufacturing composite oxide powder which is the precursor of the oxide superconductor 失效一种生产用于制备混合氧化物粉末，这超导氧化物的前体的超导氧化物和处理过程。
公开(公告)号：EP0303249B1
公开(公告)日：1995-05-24
申请号：EP88112998.5
申请日：1988-08-10
发明人： Uno, Naoki , Enomoto, Noritsugu , Tanaka, Yasuzo , Shiga, Shoji
CPC分类号： C04B35/4504 , C01G3/006 , C01P2004/61 , C04B35/4512 , C04B35/4521 , H01L39/2419 , Y10S505/725 , Y10S505/778
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公开(公告)号：EP0651909A1
公开(公告)日：1995-05-10
申请号：EP93916112.0
申请日：1993-07-21
CPC分类号： C01G21/006 , C01P2002/30 , C01P2002/34 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2002/78 , C01P2002/85 , C04B35/4504 , H01L39/126 , Y10S505/778 , Y10S505/779 , Y10S505/783
摘要： A superconductor that is free of Tl and may have a sharp transition from metallic to superconducting behaviour at temperatures up to about 80K at least is characterized by the formula (Pba(A)1-a)(SrbBa1-b)2(Cac(B)1-c)Cu2O7 in which at least half the (A) atoms are Hg and the remainder, if any, are selected from one or more of Zn, Cd, Tl, Sc, Mg, and Cu; (B) is selected from Y and the rare earth elements; a is from 0.3 to 0.7; b is from 0 to 1; and c is from 0.2 to 0.5 (all limits inclusive).
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公开(公告)号：EP0413581B1
公开(公告)日：1995-05-10
申请号：EP90308994.4
申请日：1990-08-16
申请人： INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER , KYOCERA CORPORATION , MITSUBISHI METAL CORPORATION , THE TOKYO ELECTRIC POWER CO., INC.
发明人： Wada, Takahiro , Koriyama, Shinichi , Sakurai, Takeshi , Suzuki, Nobuo , Miyatake, Takayuki , Yamauchi, Hisao , Koshizuka, Naoki , Tanaka, Shoji
CPC分类号： H01L39/126 , Y10S505/778
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5.发明公开Composite mixed conductor membranes for producing oxygen 无效Gemischt leitende Verbundmembranen zur Herstellung von Sauerstoff。
公开(公告)号：EP0592809A1
公开(公告)日：1994-04-20
申请号：EP93114421.6
申请日：1993-09-08
发明人： Thorogood, Robert Michael , Srinivasan, Rajagopalan Sree , Yee, Terrence Fu , Drake, Miles Patrick
CPC分类号： C01B13/0255 , B01D71/024 , B01D2325/26 , C01B2210/0046 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： The present invention relates to novel multi-layer composite solid state membranes which are capable of separating oxygen from oxygen-containing gaseous mixtures at elevated temperatures. The membranes comprise a multicomponent metallic oxide porous layer having an average pore radius of less than about 10 micrometers and a multicomponent metallic oxide dense layer having no connected through porosity wherein the porous and dense layers are contiguous and such layers conduct electrons and oxygen ions at operating temperatures.
摘要翻译： 本发明涉及新的多层复合固态膜，其能够在高温下从含氧气体混合物中分离氧气。 膜包含平均孔半径小于约10微米的多组分金属氧化物多孔层和多孔和致密层连续的多组分金属氧化物致密层，其中多孔和致密层是连续的，并且这些层在操作时传导电子和氧离子 温度。
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6.发明公开Process for recovering oxygen from gaseous mixtures containing water or carbon dioxide which process employs ion transport membranes 无效一种用于氧气的水或含二氧化碳的气体混合物，使用离子迁移膜的恢复过程。
公开(公告)号：EP0585820A2
公开(公告)日：1994-03-09
申请号：EP93113687.3
申请日：1993-08-26
发明人： Thorogood, Robert Michael , Carolan, Michael Francis , Labar, James Marlow, Sr. , Dyer, Paul Nigel
CPC分类号： C01B13/0255 , B01D53/326 , B01D71/024 , C01B2210/0051 , C01B2210/0062 , C01B2210/007 , Y10S505/701 , Y10S505/778 , Y10S505/785
摘要： The invention is a process for recovering oxygen from an oxygen-containing gaseous mixture containing one or more components selected from water, carbon dioxide or a volatile hydrocarbon which process utilizes ion transport membranes comprising a multicomponent metallic oxide containing strontium, calcium or magnesium. The process utilizes a temperature regime which overcomes problems associated with degradation of strontium-, calcium- and magnesium-containing multicomponent oxides caused by carbon dioxide.
摘要翻译： 本发明是用于在从回收氧的方法的气态混合物含有选自水，二氧化碳或方法利用离子传输膜，其包括多组分金属氧化物含有锶，钙或镁挥发性烃中的一种或多种组分的含氧。 该方法利用哪个过来与锶，钙和由二氧化碳引起的含镁多组分氧化物的降解相关联的问题的温度制度。
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公开(公告)号：EP0452423A1
公开(公告)日：1991-10-23
申请号：EP90907789.0
申请日：1990-01-03
申请人： AlliedSignal Inc.
CPC分类号： C01B13/185 , C01B13/32 , C01G3/006 , C01P2002/72 , C01P2002/88 , C01P2006/40 , Y10S502/525 , Y10S505/738 , Y10S505/742 , Y10S505/778 , Y10S505/779 , Y10S505/78 , Y10S505/781
摘要： On a mis au point un procédé de production d'oxydes métalliques mélangés uniformes, tels que des mélanges supraconducteurs comprenant Y1Ba2Cu3O7-x, dans lequel lesdits métaux sont précipités sous forme d'oxalates obtenus à partir de solutions des métaux sous forme de sels d'un acide carboxylique dans un alcool.
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8.发明公开Method of manufacturing oxide superconductor, and method of manufacturing composite oxide powder which is the precursor of the oxide superconductor 失效氧化物超导体的制造方法和制造氧化物超导体前驱体的复合氧化物粉末的方法
公开(公告)号：EP0303249A3
公开(公告)日：1990-04-25
申请号：EP88112998.5
申请日：1988-08-10
发明人： Uno, Naoki , Enomoto, Noritsugu , Tanaka, Yasuzo , Shiga, Shoji
CPC分类号： C04B35/4504 , C01G3/006 , C01P2004/61 , C04B35/4512 , C04B35/4521 , H01L39/2419 , Y10S505/725 , Y10S505/778
摘要： Disclosed is a method of manufacturing an oxide superconductor containing at least an alkaline earth metal and copper. This method comprises the steps of heating a material substance containing elements constituting the oxide superconductor, in an atmosphere having an oxygen partial pressure of at most 50 Torr at a temperature ranging from 500°C to 1000°C, and then heating the material substance in an oxygen-containing atmosphere. Also disclosed herein is a method of manufacturing composite oxide powder which is the precursor of the oxide superconductor. This method comprises the steps of heating the material substance in an atmosphere having an oxygen partial pressure of at most 50 Torr at a temperature ranging from 500°C to 1000°C, and crushing the material substance into powder.
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公开(公告)号：EP0641750B1
公开(公告)日：2001-03-21
申请号：EP94113700.2
申请日：1994-09-01
发明人： Den, Tohru , Kaneko, Norio , Kobayashi, Tamaki
CPC分类号： H01L39/2419 , C04B35/4508 , Y10S505/777 , Y10S505/778 , Y10S505/779 , Y10S505/78
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公开(公告)号：EP0660424B1
公开(公告)日：2000-04-12
申请号：EP94309597.6
申请日：1994-12-20
发明人： Adachi, Seiji , Jin, Changqin , Wu, Xiao-Jing , Yamauchi, Hisao , Tanaka, Shoji
IPC分类号： H01L39/12
CPC分类号： H01L39/126 , Y10S505/776 , Y10S505/778
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