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    DICYCLOPENTADIENE COMPOUND-MODIFIED PHENOLIC RESIN PRODUCTION METHOD
    7.
    发明公开
    DICYCLOPENTADIENE COMPOUND-MODIFIED PHENOLIC RESIN PRODUCTION METHOD 审中-公开

    公开(公告)号：EP3309191A4

    公开(公告)日：2018-07-11

    申请号：EP16834802

    申请日：2016-07-28

    申请人： JFE CHEMICAL CORP

    发明人： TAKEMURA KAZUYA

    IPC分类号： C08G61/02 ,  B01J27/32 ,  B01J38/52 ,  B01J38/56

    CPC分类号： C08G61/02 ,  B01J27/32 ,  B01J38/52 ,  B01J38/56 ,  C08G2261/12 ,  C08G2261/1422 ,  C08G2261/3424 ,  C08G2261/65 ,  C08G2261/71 ,  Y02P20/584

    摘要： Provided is a method for producing a dicyclopentadiene-modified phenolic resin, in which resin properties and the color tone stabilize when a catalyst is repeatedly used and the catalyst can be repeatedly used enough times. The method for producing a dicyclopentadiene-modified phenolic resin includes reusing a fluorine-based ion-exchange resin as a catalyst in a reaction between a phenol and a dicyclopentadiene, the fluorine-based ion-exchange resin having been used as a catalyst when a phenol and a dicyclopentadiene are allowed to react with each other to produce a dicyclopentadiene-modified phenolic resin. In the method, the fluorine-based ion-exchange resin to be reused, the fluorine-based ion-exchange resin having been washed with an organic solvent, is used at least once when reused. Also provided is a production method including purifying a product, the method being capable of preventing coloring of a resin obtained in the production of a dicyclopentadiene-modified phenolic resin. The dicyclopentadiene-modified phenolic resin obtained by the production method of the present invention has a stable quality and a high purity and is inexpensive.

    DICYCLOPENTADIENE COMPOUND-MODIFIED PHENOLIC RESIN PRODUCTION METHOD
    8.
    发明公开
    DICYCLOPENTADIENE COMPOUND-MODIFIED PHENOLIC RESIN PRODUCTION METHOD 审中-公开
    二环戊二烯复合改性酚醛树脂生产方法

    公开(公告)号：EP3309191A1

    公开(公告)日：2018-04-18

    申请号：EP16834802.7

    申请日：2016-07-28

    申请人： JFE Chemical Corporation

    发明人： TAKEMURA, Kazuya

    IPC分类号： C08G61/02

    CPC分类号： C08L61/14 ,  B01J27/32 ,  B01J31/08 ,  B01J38/52 ,  B01J38/56 ,  C08G61/02 ,  C08G61/08 ,  C08G2261/12 ,  C08G2261/1422 ,  C08G2261/3424 ,  C08G2261/65 ,  C08G2261/71

    摘要： Provided is a method for producing a dicyclopentadiene-modified phenolic resin, in which resin properties and the color tone stabilize when a catalyst is repeatedly used and the catalyst can be repeatedly used enough times. The method for producing a dicyclopentadiene-modified phenolic resin includes reusing a fluorine-based ion-exchange resin as a catalyst in a reaction between a phenol and a dicyclopentadiene, the fluorine-based ion-exchange resin having been used as a catalyst when a phenol and a dicyclopentadiene are allowed to react with each other to produce a dicyclopentadiene-modified phenolic resin. In the method, the fluorine-based ion-exchange resin to be reused, the fluorine-based ion-exchange resin having been washed with an organic solvent, is used at least once when reused. Also provided is a production method including purifying a product, the method being capable of preventing coloring of a resin obtained in the production of a dicyclopentadiene-modified phenolic resin. The dicyclopentadiene-modified phenolic resin obtained by the production method of the present invention has a stable quality and a high purity and is inexpensive.

    摘要翻译： 本发明提供一种二环戊二烯改性酚醛树脂的制造方法，其中，反复使用催化剂时的树脂性和色调稳定，并且能够反复使用足够的次数。 作为二环戊二烯改性酚醛树脂的制造方法，在苯酚与二环戊二烯的反应中，作为催化剂使用氟系离子交换树脂，作为催化剂使用氟系离子交换树脂时， 和二环戊二烯相互反应生成二环戊二烯改性酚醛树脂。 在该方法中，重复使用至少一次使用经过有机溶剂洗涤的基于氟的离子交换树脂的重新使用的氟基离子交换树脂。 还提供了一种包括纯化产物的生产方法，所述方法能够防止在二环戊二烯改性的酚醛树脂的生产中获得的树脂的着色。 用本发明的制造方法得到的二环戊二烯改性酚醛树脂质量稳定，纯度高，价格便宜。