Hydroxy-t-alkyl peroxyester
    4.
    发明公开
    Hydroxy-t-alkyl peroxyester 失效
    羟基-T-烷基过氧化物

    公开(公告)号:EP0126216A3

    公开(公告)日:1985-05-15

    申请号:EP84101830

    申请日:1984-02-22

    发明人: Sanchez, Jose

    CPC分类号: C07C409/38

    摘要: Hydroxy-t-alkyl peroxyesters having the general structure
    where R, R 1 , R 2 , R, and R 4 can be alkyl moieties and having 10 hour half-life temperatures below about 75°C (for example, 3-hydroxy-1,1-dimethylbutyl peroxy-neodecanoate) are described. These peroxyesters are used as initiators for vinyl monomer polymerization and as catalysts for curing unsaturated polyester resins in order to improve the efficiency of the systems.

    Low pressure preparation of ethylene copolymers in fluid bed reactor, copolymers obtained and films made therefrom
    7.
    发明公开
    Low pressure preparation of ethylene copolymers in fluid bed reactor, copolymers obtained and films made therefrom 失效
    流化床反应器中乙烯共聚物的低压制备,获得的共聚物和膜的膜

    公开(公告)号:EP0004645A3

    公开(公告)日:1979-10-31

    申请号:EP79100953

    申请日:1979-03-30

    摘要: Ethylene copolymers having a density of ≥ 0.91 to ≤ 0.96 and a melt flow ratio of ≥ 22 to ≤ 32 are readily produced in a low pressure gas phase process at a productivity of ≥ 50,000 pounds of polymer per pound of Ti with a particulate catalyst diluted with an inert carrier material and formed from selected organo aluminum compounds and a precursor composition of the formula:
    wherein ED is a selected electron donor compound.
    m is ≥ 0.5 to ≤ 56 n is 0 or 1 p is ≥ 6 to ≤ 116 q is ≥ 2 to ≤ 85 R is a C 1 to C 14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C, to C 14 aliphatic or aromatic hydrocarbon radical, and X is selected from the group consisting of Cl, Br, I or mixtures thereof. This application is a Continuation-in-Part of co-pending application Serial No. 892,325 filed March 31, 1978.

    摘要翻译: 在低压气相法中容易产生密度≥0.91〜0.96,熔体流动比> 22 = 32的乙烯共聚物,生产率≥50万磅 聚合物每磅Ti与用惰性载体材料稀释并由选定的有机铝化合物和下式的前体组合物MgMTi1(OR)nXp [ED] q形成的颗粒催化剂形成,其中ED是选择的电子给体化合物。 m为≥0.5至 / = 6至 / = 2至

    Catalyst and method of preparation and use thereof for polymerizing alpha-olefins
    10.
    发明公开
    Catalyst and method of preparation and use thereof for polymerizing alpha-olefins 失效
    催化剂及其制备方法及其用于聚合α-烯烃的方法

    公开(公告)号:EP0160413A3

    公开(公告)日:1987-03-11

    申请号:EP85302329

    申请日:1985-04-03

    IPC分类号: C08F10/00 C08F04/64 C08F02/34

    摘要: A catalyst composition for polymerizing alpha-olefins is prepared by treating a carrier containing OH groups with an organomagnesium composition and contacting the thus- formed magnesium-containing carrier with a solution of a titanium (IV) alkoxide and a brominating and/or chlorinating agent. The adjustment of the molar ratio of the brominating and/or chlorinating agent to the titanium alkoxide yields catalysts which produce polymers of varying molecular weight distribution, as measured by the melt flow ratio (MFR) values.