BIODEGRADABLE POLYESTER COMPOSITION
    1.
    发明公开
    BIODEGRADABLE POLYESTER COMPOSITION 有权
    生物可降解聚酯组合物

    公开(公告)号:EP3260498A1

    公开(公告)日:2017-12-27

    申请号:EP17762460.8

    申请日:2017-02-24

    摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of a cyclic ester compound having a structure shown as formula (I) is 100ppm-950ppm;

    and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5ppm-85ppm. In the present invention, by adding the cyclic ester compound and cyclopentanone into the composition and controlling the content of the cyclic ester compound and the content of cyclopentanone in a certain range in the composition, an anti-thermal oxidative aging property of the biodegradable polyester composition can be greatly improved. Besides, after being digested with 95% ethanol at 40°C for 240 hours, a film prepared by blow molding or a part prepared by injection molding has little precipitate separating out of the surface and has an excellent surface appearance property. In addition, the lubrication degree of film during the blow molding process of the biodegradable polyester can be improved. When the velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2µm and a relative deviation of the film thickness is less than 1%. Bubble stability and continuity of film blowing are guaranteed.

    摘要翻译: 本发明公开了一种生物可降解聚酯组合物,其中基于生物可降解聚酯组合物的总重量,具有式(I)所示结构的环状酯化合物的重量含量为100ppm-950ppm; 基于生物可降解聚酯组合物的总重量,环戊酮的重量含量为0.5ppm-85ppm。 在本发明中,通过将环状酯化合物和环戊酮添加到组合物中,并且在组合物中控制环酯化合物的含量和环戊酮的含量在一定范围内,可生物降解的聚酯组合物的抗热氧化老化性能 可以大大提高。 此外,用95%乙醇在40℃下消化240小时后,通过吹塑或通过注塑制备的部件制备的膜具有很少的从表面析出的沉淀,并具有优异的表面外观性能。 另外,可生物降解聚酯的吹塑成型过程中膜的润滑度可以得到改善。 当吹膜速度为176Kg / h时,膜厚范围小于0.2μm,膜厚相对偏差小于1%。 泡沫稳定性和吹膜连续性得到保证。

    HÄRTUNG VON EPOXIDHARZ-ZUSAMMENSETZUNGEN, WELCHE CYCLISCHE CARBONATE ENTHALTEN, MIT GEMISCHEN VON AMINOHÄRTERN
    9.
    发明公开
    HÄRTUNG VON EPOXIDHARZ-ZUSAMMENSETZUNGEN, WELCHE CYCLISCHE CARBONATE ENTHALTEN, MIT GEMISCHEN VON AMINOHÄRTERN 审中-公开
    固化环氧组合物,其环状碳酸酯混合体AMINOHÄRTERN含

    公开(公告)号:EP2758470A1

    公开(公告)日:2014-07-30

    申请号:EP12756475.5

    申请日:2012-09-10

    申请人: BASF SE

    IPC分类号: C08L63/00 C08G59/00 C08K5/156

    摘要: A process for curing epoxy resins which comprises curing epoxy resin compositions comprising a) epoxy resins and b) a compound of the general formula I in which R
    1 and R
    2 independently of one another are hydrogen, C
    1 -C
    6 -alkyl, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, C
    5 -C
    6 -cycloalkyl, phenyl, phenyl-C
    1 -C
    4 -alkyl, C
    2 -C
    6 -alkenyl or C
    2 -C
    6 -alkynyl, or R
    1 and R
    2 together are a C
    3 -C
    11 -alkylene group; R
    3 and R
    4 independently of one another are hydrogen, C
    1 -C
    6 -alkyl, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, C
    5 -C
    6 -cycloalkyl, phenyl, phenyl-C
    1 -C
    4 -alkyl, C
    2 -C
    6 -alkenyl or C
    2 -C
    6 -alkynyl, or R
    3 and R
    4 together are a C
    4 -C
    6 -alkylene group; by adding amino hardeners, 0.1% to 50% by weight of the amino hardeners being aliphatic, cycloaliphatic or aromatic amine compounds having 1 to 4 primary amino groups and optionally further functional groups, selected from secondary amino groups, tertiary amino groups, and hydroxyl groups, the primary amino groups in the case of the cycloaliphatic and aromatic amine compounds being attached as aminomethylene groups (H
    2 N-CH
    2 -) to the cycloaliphatic or aromatic ring system (referred to below for short as co-hardeners).

    POLYPROPYLENE FOR FILM CONDENSER, BIAXIAL STRETCHING FILM FOR FILM CONDENSER, FILM CONDENSER AND MANUFACTURING METHODS THEREFOR
    10.
    发明公开
    POLYPROPYLENE FOR FILM CONDENSER, BIAXIAL STRETCHING FILM FOR FILM CONDENSER, FILM CONDENSER AND MANUFACTURING METHODS THEREFOR 审中-公开
    用于薄膜冷凝器的聚丙烯,用于薄膜冷凝器的双轴拉伸薄膜,薄膜冷凝器及其制造方法

    公开(公告)号:EP3279254A1

    公开(公告)日:2018-02-07

    申请号:EP16772925.0

    申请日:2016-03-30

    摘要: It is an object of the present invention to provide a polypropylene (F) for a film capacitor having excellent stretchability and uniformity in stretching, which is preferable for a biaxially stretched film that has a small thermal shrinkage ratio and sufficient breakdown voltage even in a harsh environment with a high temperature and a high frequency current and a film capacitor including the biaxially stretched film. The polypropylene (F) of the present invention includes a propylene homopolymer and an α crystal nucleating agent having a melting point of not more than 290°C, wherein the propylene homopolymer satisfies: (1) MFR (JIS K 7210, 230°C, a load of 2.16 kg) is within a range of 1 to 10 (g/10 min); (2) the mmmm fraction is not less than 93%; (3) the proportion of erythro regio defects is less than 0.1% by mol, as determined using 13 C-NMR; (4) the ash amount is not more than 50 ppm, as obtained by completely burning the propylene homopolymer in the air; (5) the chlorine amount is not more than 5 ppm, as determined by ion chromatography; and (6) the molecular weight distribution Mw/Mn is 6.5 to 12, as measured by GPC.

    摘要翻译: 本发明的目的在于提供拉伸性和拉伸均匀性优异的薄膜电容器用聚丙烯(F),对于热收缩率小,即使在恶劣条件下也具有充分的耐压的双轴拉伸薄膜 高温和高频电流的环境以及包含该双轴拉伸膜的薄膜电容器。 本发明的聚丙烯(F)包括丙烯均聚物和熔点不超过290℃的α晶体成核剂,其中丙烯均聚物满足:(1)MFR(JIS K 7210,230℃, 2.16kg的负荷)在1至10(g / 10min)的范围内; (2)mmmm分数不小于93%; (3)使用13C-NMR测定,<2,1>赤型区域缺陷的比例小于0.1摩尔%; (4)通过在空气中完全燃烧丙烯均聚物而获得的灰分量不超过50ppm; (5)离子色谱法测定的氯含量不超过5ppm; (6)通过GPC测定的分子量分布Mw / Mn为6.5〜12。