公开(公告)号：EP0609566A1

公开(公告)日：1994-08-10

申请号：EP93121021.5

申请日：1993-12-28

申请人： CHISSO CORPORATION

发明人： Takeshita, Fusayuki ,  Hirose, Taku ,  Terashima, Kanetsugu ,  Sawada, Shinichi

IPC分类号： C09K19/30 ,  C09K19/50 ,  C09K19/58

CPC分类号： C09K19/50 ,  C09K19/3001 ,  C09K19/586

摘要： Liquid crystal composition having a high voltage-holding ratio of liquid crystal element and being almost unchanged in the helical pitch even when subjected to purification treatment with adsorbents or the like,
   which composition is a liquid crystal mixture of an achiral liquid crystal compound of the following formula (IV) with a chiral compound having an adsorptivity to adsorbents, not greater than that of the achiral compound:

wherein A', B', C' and D' each independently are trans-1,4-cyclohexylene, 1-cyclohexene-1,4-diyl or 1,4-phenylene; g, h and i each are 0 or 1; (g+h+i)≧1 ; X', Y' and Z' each independently are a single bond, -CH₂-CH₂-, -CH=CH- or -C≡C-; R⁷ is C n H 2n+1 -, C n H 2n-1 or C n H 2n+1 OC k H 2k -; R⁸ is C m H 2m+1 -, C m H 2m+1 O-, F, CHF₂O or CF₃O-; n and m each independently are an integer of 1 to 18; k is an integer of 1 to 17; (n+k) is 2 to 18; at least one of X', Y' and Z' is single bond; when ring D' is 1,4-phenylene and R⁸ is F, CHF₂O- or CF₃O-, then H at ortho position as regards R⁸ may be replaced by F; and "Then" g is 1 and ring B' or C' is 1,4-phenylene, when H at the lateral position of the ring may be replaced by F.
It is preferred in order to exhibit a high voltage-holding ratio that the achiral liquid crystal compound have as a polar group, a functional group (such as F and CF 3 O-) limited to a halogen atom such as F, Cℓ, etc. or an ether bond, besides the C-C bond and the C-H bond.
As to chiral compounds those having a functional group restricted to only a halogen atom or an ether bond are preferred, in the same aspect, chiral agent compounds having a polar group of -CN group as a fuctional group are unsuitable.

摘要翻译： 液晶组合物具有高电压保持率的液晶元件，并且即使在用吸附剂等进行纯化处理时几乎没有变化，该组成是以下的非手性液晶化合物的液晶混合物 式（Ⅳ）与对吸附剂具有吸附性的手性化合物不大于非手性化合物：其中A'，B'，C'和D'各自独立地为反式-1,4-亚环己基，1 环己烯-1,4-二基或1,4-亚苯基; g，h和i各自为0或1; （G + H + I）> / = 1; X'，Y'和Z'各自独立地是单键，-CH 2 -CH 2 - ， - CH = CH-或-C≡CENTICALC-; R 7是C n H 2n + 1，C n H 2n-1或C n H 2n + 1 OC k H 2k-; R 8是C m H 2n + 1，C m H 2m + 10，F，CHF 2 O或CF 3 O-; n和m各自独立地为1〜18的整数; k为1〜17的整数。 （n + k）为2〜18; X'，Y'和Z'中的至少一个是单键; 当环D'为1,4-亚苯基且R 8为F，CHF 2 O-或CF 3 O-时，则R 8在邻位的H可被F取代; “然后”g为1，环B'或C'为1,4-亚苯基，当环的横向位置的H可以被F代替时，为了表现出高的电压保持率，优选为 除CC键和CH键之外，非手性液晶化合物具有极性基团，限于诸如F，C 1等卤素原子或醚键的官能团（如F和CF 3 O-）。 对于具有仅限于卤素原子或醚键的官能团的手性化合物是优选的，在同一方面，具有-CN基极性基团的手性试剂化合物作为官能团是不合适的。

公开(公告)号：EP0806466A3

公开(公告)日：1998-03-18

申请号：EP97105540.5

申请日：1997-04-03

申请人： CHISSO CORPORATION

发明人： Yamaguchi, Takashi ,  Murashiro, Katsuyuki ,  Takeshita, Fusayuki ,  Matsushita, Tetsuya ,  Nakagawa, Etsuo

IPC分类号： C09K19/50

CPC分类号： C09K19/50

摘要： A chiral nematic liquid crystal composition is provided, which has a broad d/P margin, particularly for corresponding to a large size of LCD panel, while satisfying various characteristics sought for STN display mode,
and which contains as a first component, at least one member of compounds expressed by the formulas (I-a) to (I-d), as a second component, at least one member of compounds expressed by the formulas (II) to (V), and as a third component, a chiral component expressed by the formula (X),

        R 5 -(B)-Z 2 -(C)-R 6      (II)
        R 7 -(D)-Z 3 -(E)-Z 4 -(G)-R 8      (III) In these formulas, R 1 to R 5 represent an alkyl group of 1 to 10 carbon atoms, etc.; Z 0 to Z 4 represent -CH 2 CH 2 -, etc.; B,C,E and G represent 1,4-cyclohexylene or 1,4-phenylene; D represents 1,4-cyclohexylene or 1,3-pyrimidine-2,5-diyl; Q 1 and Q 2 represent H or F; and q and m each independently represent 0 or 1; R 1 to R 12 represent an alkyl group of 1 to 10 carbon atoms or an alkenyl group of 2 to 10 carbon atoms. This composition may be used in STN mode, TN mode or AN mode liquid crystal display elements. This invention also describes the liquid crystal display elements containing such composition.

公开(公告)号：EP0609566B2

公开(公告)日：2006-03-29

申请号：EP93121021.5

申请日：1993-12-28

申请人： Chisso Corporation

发明人： Takeshita, Fusayuki ,  Hirose, Taku ,  Terashima, Kanetsugu ,  Sawada, Shinichi

IPC分类号： C09K19/30 ,  C09K19/50 ,  C09K19/58

CPC分类号： C09K19/50 ,  C09K19/3001 ,  C09K19/586

公开(公告)号：EP0609566B1

公开(公告)日：1999-12-01

申请号：EP93121021.5

申请日：1993-12-28

申请人： CHISSO CORPORATION

发明人： Takeshita, Fusayuki ,  Hirose, Taku ,  Terashima, Kanetsugu ,  Sawada, Shinichi

IPC分类号： C09K19/30 ,  C09K19/50 ,  C09K19/58

CPC分类号： C09K19/50 ,  C09K19/3001 ,  C09K19/586

公开(公告)号：EP0806466A2

公开(公告)日：1997-11-12

申请号：EP97105540.5

申请日：1997-04-03

申请人： CHISSO CORPORATION

发明人： Yamaguchi, Takashi ,  Murashiro, Katsuyuki ,  Takeshita, Fusayuki ,  Matsushita, Tetsuya ,  Nakagawa, Etsuo

IPC分类号： C09K19/50

CPC分类号： C09K19/50

摘要： A chiral nematic liquid crystal composition is provided, which has a broad d/P margin, particularly for corresponding to a large size of LCD panel, while satisfying various characteristics sought for STN display mode,

and which contains as a first component, at least one member of compounds expressed by the formulas (I-a) to (I-d),
as a second component, at least one member of compounds expressed by the formulas (II) to (V), and
as a third component, a chiral component expressed by the formula (X),


        R 5 -(B)-Z 2 -(C)-R 6      (II)



        R 7 -(D)-Z 3 -(E)-Z 4 -(G)-R 8      (III)




In these formulas, R 1 to R 5 represent an alkyl group of 1 to 10 carbon atoms, etc.; Z 0 to Z 4 represent -CH 2 CH 2 -, etc.; B,C,E and G represent 1,4-cyclohexylene or 1,4-phenylene; D represents 1,4-cyclohexylene or 1,3-pyrimidine-2,5-diyl; Q 1 and Q 2 represent H or F; and q and m each independently represent 0 or 1; R 1 to R 12 represent an alkyl group of 1 to 10 carbon atoms or an alkenyl group of 2 to 10 carbon atoms.
This composition may be used in STN mode, TN mode or AN mode liquid crystal display elements. This invention also describes the liquid crystal display elements containing such composition.

摘要翻译： 提供了具有宽d / P余量的手征向列液晶组合物，特别是对应于大尺寸LCD面板，同时满足STN显示模式所要求的各种特性，并且其包含作为第一组分的至少一种 由式（Ia）至（Id）表示的化合物的成分，作为第二组分，由式（II）至（V）表示的至少一种化合物，作为第三组分，由 式（X）， R 5 - （B）-Z 2 - （C）-R 6 R 7 - （D）-Z 3 - （E） 在这些式中，R 1〜R 5表示碳原子数1〜10的烷基等。 Z 0至Z 4表示-CH 2 CH 2 - 等; B，C，E和G表示1,4-亚环己基或1,4-亚苯基; D代表1,4-亚环己基或1,3-嘧啶-2,5-二基; Q 1和Q 2代表H或F; q和m各自独立地表示0或1; R 1〜R 12表示碳原子数1〜10的烷基或碳原子数2〜10的烯基。 该组合物可用于STN模式，TN模式或AN模式液晶显示元件。 本发明还描述了含有这种组合物的液晶显示元件。

公开(公告)号：EP4025660A1

公开(公告)日：2022-07-13

申请号：EP20772481.6

申请日：2020-09-01

申请人： Sun Chemical Corporation

发明人： JACOT, Roger ,  KLAUS, Kurt ,  KÜFFER, Stefan

IPC分类号： C09D11/50 ,  C09D11/037 ,  C09D11/14 ,  C09D11/105 ,  C09D11/107 ,  C09D11/033 ,  C09D11/54 ,  C09D5/26 ,  C09K19/36 ,  C09K19/50 ,  B65D81/34 ,  B41M3/14

公开(公告)号：EP2754650A4

公开(公告)日：2015-05-27

申请号：EP12829443

申请日：2012-09-05

申请人： FUJIFILM CORP

发明人： UEMURA MINORU ,  ISHIWATA YASUHIRO ,  YOSHIKAWA MASARU ,  TAGUCHI TAKAO ,  TASAKA TOMOKI

IPC分类号： C07C69/94 ,  C08F20/30 ,  C09K19/04 ,  C09K19/20 ,  C09K19/38 ,  C09K19/50 ,  C09K19/54 ,  G02B1/10 ,  G02B1/11 ,  G02B5/20 ,  G02B5/26 ,  G02B5/30 ,  G03H1/02

CPC分类号： G02B1/14 ,  C09K19/3838 ,  C09K19/50 ,  C09K2019/0448 ,  C09K2019/2078 ,  C09K2219/03 ,  G02B1/10 ,  G02B1/105 ,  G02B1/11 ,  G02B5/208 ,  G02B5/3016 ,  G02B5/3083 ,  G03H2001/0264

摘要： A polymerizable liquid-crystal compound represented by the general formula (I) can be used as an additive effective for preventing crystal deposition after coating with the polymerizable liquid crystal (II) or a polymerizable liquid crystal similar thereto. P represents a polymerizable functional group; Sp represents a spacer or a single bond; Z 1 and Z 2 each represent -CO-O-; R 0 represents a linear alkyl group having from 1 to 15 carbon atoms; R 2 , R 3 and R 4 each independently represent an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyloxy group having from 2 to 5 carbon atoms, an acyl group having from 2 to 4 carbon atoms, an amide group having from 2 to 5 carbon atoms, a cyano group, an amino group, a hydroxyl group, or a halogen atom; r 1 , r 2 and r 3 indicate an integer of from 0 to 4; when r 1 , r 2 and r 3 each are 2 or more, then R 2 , R 3 and R 4 each may be the same or different; however, when R 0 is a methyl group, then r 2 is not 1.

摘要翻译： 由通式（I）表示的可聚合液晶化合物可以用作在用可聚合液晶（II）或类似于其的可聚合液晶涂覆之后防止结晶沉积的添加剂。 P表示可聚合官能团; Sp表示间隔基或单键; Z 1和Z 2各自表示-CO-O-; R 0表示具有1至15个碳原子的直链烷基; R 2，R 3和R 4各自独立地表示具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基，具有2至5个碳原子的烷氧基羰基，具有2个 5个碳原子，具有2至4个碳原子的酰基，具有2至5个碳原子的酰胺基，氰基，氨基，羟基或卤素原子; r 1，r 2和r 3表示0〜4的整数， 当r 1，r 2和r 3各自为2或更大时，则R 2，R 3和R 4各自可以相同或不同; 然而，当R 0为甲基时，则r 2不为1。

公开(公告)号：EP0806466B1

公开(公告)日：2003-07-02

申请号：EP97105540.5

申请日：1997-04-03

申请人： CHISSO CORPORATION

发明人： Yamaguchi, Takashi ,  Murashiro, Katsuyuki ,  Takeshita, Fusayuki ,  Matsushita, Tetsuya ,  Nakagawa, Etsuo

IPC分类号： C09K19/50

CPC分类号： C09K19/50

公开(公告)号：EP0891961A4

公开(公告)日：1999-06-16

申请号：EP97903621

申请日：1997-02-27

申请人： CHISSO CORP

发明人： SHIBATA KOICHI ,  KONDO TOMOYUKI ,  MATSUI SHUICHI ,  MIYAZAWA KAZUTOSHI ,  HACHIYA NORIHISA ,  NAKAGAWA ETSUO

IPC分类号： C07C43/174 ,  C09K19/30 ,  C09K19/46 ,  C09K19/50 ,  C09K19/42 ,  G02F1/13

CPC分类号： C09K19/3001 ,  C07C43/1747 ,  C07C2601/14 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/46 ,  C09K19/50

摘要： Compounds represented by general formula (1), which exhibit nematic liquid crystal phases over widened temperature ranges and are lowered in viscosity and improved in low-temperature compatibility with other liquid crystal compounds and chemical stability as compared with the liquid crystal compounds of the prior art, wherein H1 to H8 are each hydrogen or halogeno, with at least one member of them being halogeno; R1 is C2-C20 alkyl wherein one methylene (-CH2-) group or two or more methylene groups that are not adjacent to each other are replaced by ethereal oxygen (-O-); Y1 is C1-C20 alkyl wherein one or more methylene groups may be replaced by oxygen, sulfur, dihydroxysilyl, dimethylsilylene, -CH=CH-, and/or -CC-; and X1 to X3 are each a covalent bond, 1,2-ethylene or 1,4-butylene.

摘要翻译： 通式（1）表示的化合物与现有技术的液晶化合物相比，在宽的温度范围内呈现向列型液晶相，粘度降低，与其他液晶化合物的低温相容性和化学稳定性提高 其中H1至H8各自为氢或卤代，其中至少一个为卤代; R1是C2-C20烷基，其中彼此不相邻的一个亚甲基（-CH2-）或两个或更多个亚甲基被醚氧（-O-）代替; Y 1是其中一个或多个亚甲基可被氧，硫，二羟基甲硅烷基，二甲基亚甲硅烷基，-CH = CH-和/或-CC-代替的C 1 -C 20烷基; X1至X3各自为共价键，1,2-亚乙基或1,4-亚丁基。