公开(公告)号：EP0949231A4

公开(公告)日：2004-02-04

申请号：EP97946802

申请日：1997-11-27

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MIYAZAWA KAZUTOSHI ,  TAKEUCHI HIROYUKI ,  MATSUI SHUICHI ,  HISATSUNE YASUSUKE ,  TAKESHITA FUSAYUKI ,  NAKAGAWA ETSUO

IPC分类号： C07C17/12 ,  C07C17/26 ,  C07C17/35 ,  C07C25/18 ,  C07C43/225 ,  C07C45/00 ,  C09K19/10 ,  C09K19/44 ,  C09K19/46 ,  C09K19/12 ,  C09K19/14 ,  C09K19/20 ,  G02F1/13

CPC分类号： C07C17/12 ,  C07C17/263 ,  C07C17/35 ,  C07C25/18 ,  C07C43/225 ,  C07C45/004 ,  C09K19/10 ,  C09K19/44 ,  C09K19/46 ,  C07C49/813

摘要： Liquid-crystalline compounds which have an extremeley high voltage retention, an extremely small temperature dependence of the retention, a low threshold voltage, and a large value of Δn; a liquid-crystal composition containing any of the liquid-crystal compounds; and a liquid-crystal display element containing the liquid-crystal composition. The compounds are represented by general formula (1), wherein R represents C1-20 alkyl, in which arbitrary non adjacent methylene groups (-CH2-) may have been replaced with oxygen atoms (-O-); Y1 to Y16 each independently represents hydrogen or fluorine, provided at least two of them are fluorine atoms and that at least two hydrogen atoms of each 1,4-phenylene group have not been replaced with fluorine atoms; X represents halogeno or C1-20 alkyl in which arbitrary non adjacent methylene groups may have been replaced with oxygen atoms and any hydrogen has optionally been replaced with fluorine; and Z1, Z2, and Z3 each independently represents -(CH2)2-, -(CH2)4-, -CH2O-, -OCH2-, -(CH2)3O-, -O(CH2)3- or a single bond; and each atom contained in this compound may have been replaced with an isotope thereof; provided when X is -OCF2CF2H, Z1 and Z3 are both single bonds, and Z2 is -(CH2)2-, then none of Y6, Y10, and Y12 is F, and none of Y1 to Y5, Y7 to Y9, Y11, and Y13 to Y16 is H; none of Y2, Y10, and Y12 is F, and none of Y1, Y3 to Y9, Y11, and Y13 to Y16 is H; or none of Y2, Y4, Y10, and Y12 is F and none of Y1, Y3, Y5 to Y9, Y11, and Y13 to Y16 is H.

公开(公告)号：EP0742275A4

公开(公告)日：1997-05-07

申请号：EP95900293

申请日：1994-11-11

申请人： CHISSO CORP

发明人： MIYAZAWA KAZUTOSHI ,  MATSUI SHUICHI ,  FUJITA ATSUKO ,  KONDO TOMOYUKI ,  GOTO YASUYUKI ,  NAKAGAWA ETSUO ,  SAWADA SHINICHI

IPC分类号： G02F1/13 ,  C07C17/16 ,  C07C17/18 ,  C07C22/00 ,  C07C22/08 ,  C07C43/12 ,  C07C43/172 ,  C07C43/192 ,  C07C45/00 ,  C07C45/29 ,  C07C45/59 ,  C09K19/04 ,  C09K19/30 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46

CPC分类号： C09K19/42 ,  C07C17/16 ,  C07C17/18 ,  C07C22/00 ,  C07C43/12 ,  C07C43/172 ,  C07C43/192 ,  C07C45/004 ,  C07C45/29 ,  C07C45/59 ,  C07C403/02 ,  C07C2601/14 ,  C09K19/0403 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3028 ,  C09K2019/0407 ,  C09K2019/0444 ,  C07C49/105 ,  C07C47/198 ,  C07C49/175

摘要： A novel liquid crystal compound represented by general formula (1), and a liquid crystal composition containing the same and having a high clearing point and a viscosity reducing effect suitable for use as a liquid crystal display element. In formula (1) R1 represents C1-C12 alkyl wherein one CH2 group may be replaced by oxygen or -CH=CH-; X represents hydrogen or fluorine; Y represents hydrogen or C1-C5 alkoxy; 1 and m represent each independently 0 or 1; and n and p represent each independently an integer of 0 to 10; provided n is at least 1 when p is 0, and X represents fluorine and p represents 0 when Y represents alkoxy.

公开(公告)号：EP0893421A4

公开(公告)日：1999-07-21

申请号：EP97908522

申请日：1997-03-27

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MATSUI SHUICHI ,  MIYAZAWA KAZUTOSHI ,  SEKIGUCHI YASUKO ,  NAKAGAWA ETSUO

IPC分类号： C07C43/176 ,  C07C43/188 ,  C07C43/225 ,  C07C69/753 ,  C07C69/76 ,  C07C69/773 ,  C09K19/04 ,  C09K19/16 ,  C09K19/30 ,  C09K19/34 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C07C13/28 ,  C07C15/50 ,  C07C22/00 ,  C07C25/24 ,  C07C43/14 ,  C07C43/215 ,  C07C69/75 ,  C07C321/10 ,  C07D213/04

CPC分类号： C07C43/225 ,  C07C43/176 ,  C07C43/188 ,  C07C69/753 ,  C07C69/76 ,  C09K19/04 ,  C09K19/16 ,  C09K19/3001 ,  C09K19/3048 ,  C09K19/3059 ,  C09K19/3402 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0448 ,  C09K2019/0451 ,  C09K2019/3422 ,  Y10T428/10

摘要： Liquid crystal compounds which exhibit a liquid crystal phase in a wide temperature range and are lowly viscous and excellent in chemical stability and compatibility with other liquid crystal materials; liquid crystal compositions containing the compounds; and liquid crystal display devices made by using the compositions. The above liquid crystal compounds are represented by the general formula (1): Ra-A1-Z1-A2-Z2-A3-Z3-A4-Rb wherein Ra is alkenyl or alkyl wherein one or more methylene groups may be replaced by -O-, -S-, -CO-, -C C- and so on; Rb is Ra, halogeno or cyano, with the proviso that at least either of Ra and Rb must be a group containing a double bond; A1, A2, A3 and A4 are each independently trans-1,4-cyclohexylene, 1,4-phenylene, cyclohexenediyl, pyridine-2,5-diyl, pyrimidine-2,5-diyl or 1,3-dioxane-2,5-diyl; and Z1, Z2 and Z3 are each independently C2-C4 alkenylene, -(CH2)2-, -COO-, -C C-, -CH2O-, a single bond or the like, at least one of Z1, Z2 and Z3 being C2-C4 alkenylene.

公开(公告)号：EP0872484A4

公开(公告)日：1998-12-23

申请号：EP96925097

申请日：1996-07-26

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MATSUI SHUICHI ,  HACHIYA NORIHISA ,  NAKAGAWA ETSUO

IPC分类号： C07F7/08 ,  C09K19/40 ,  C09K19/42 ,  C07F7/10 ,  C07F7/12

CPC分类号： C07F7/0896 ,  C09K19/40 ,  C09K19/406 ,  C09K19/42

摘要： Oragnosilicon compounds represented by the general formula (1): Ra-A-(-Z1-A1-)-m-(-Z2-A2-)-n-(-Z3-A3-)-o-Rb, excellent in the compatibility with other liquid-crystal materials, reduced in viscosity, and improved in threshold voltage, wherein at least one of Ra, Rb, Z1, Z2 and Z3 has an -SiH2 group; Ra represents hydrogen or C1-C2 alkyl wherein at least one -CH2- group may be substituted by -SiH2-, -O-, -S-, -CO-, -CH=CH-, -CC- or 1,4-cyclobutylene; Rb represents a group of any of the Ra groups, halogeno or CN; A, A1, A2 and A3 represent each a bivalent ring group; Z1, Z2 and Z3 represent each independently a covalent bond or -(CH2)p- wherein at least one -CH2- group may be substituted by -SiH2-, -O-, -S-, -CO-, -CH=CH- or -CC-; p represents an integer of 1 to 4; and m, n and o represent each independently 0 or 1.

公开(公告)号：EP0808886A4

公开(公告)日：1998-04-01

申请号：EP96901953

申请日：1996-02-07

申请人： CHISSO CORP

发明人： MATSUI SHUICHI ,  KONDO TOMOYUKI ,  MIYAZAWA KAZUTOSHI ,  OHNISHI NORIYUKI ,  GOTO YASUYUKI ,  NAKAGAWA ETSUO ,  SAWADA SHINICHI

IPC分类号： C07C69/76 ,  C07C69/773 ,  C07C69/90 ,  C07C69/94 ,  C09K19/20 ,  C09K19/30 ,  C09K19/46

CPC分类号： C07C69/76 ,  C07C69/90 ,  C07C69/94 ,  C09K19/2007 ,  C09K19/3001 ,  C09K19/3068 ,  C09K19/46 ,  Y10T428/10

摘要： Liquid crystal compositions containing at least one compound represented by general formula (1') as a first component and at least one compound represented by any of general formulae (2-1) to (2-5) as a second component, wherein n represents an integer of 1 to 10; X represents H or F; and m represents 1 or 2.

公开(公告)号：EP0882696A4

公开(公告)日：1999-04-21

申请号：EP96938452

申请日：1996-11-13

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MATSUI SHUICHI ,  MIYAZAWA KAZUTOSHI ,  HACHIYA NORIHISA ,  NAKAGAWA ETSUO

IPC分类号： G02F1/13 ,  C07C43/188 ,  C07C43/192 ,  C07C43/215 ,  C07C43/225 ,  C07C255/46 ,  C07C255/54 ,  C07D239/26 ,  C09K19/04 ,  C09K19/20 ,  C09K19/30 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46

CPC分类号： C07C43/215 ,  C07C43/188 ,  C07C43/192 ,  C07C43/225 ,  C07C255/46 ,  C07C255/54 ,  C07C2601/14 ,  C09K19/0403 ,  C09K19/3059 ,  C09K19/3066 ,  C09K19/42 ,  C09K19/46 ,  C09K2019/0407 ,  C09K2019/0444

摘要： Liquid-crystal compounds represented by general formula (1) (wherein X1, X2 and X3 are each -CH2O-, -OCH2-, -(CH2)3O-, -O(CH2)3-, a covalent bond, -CF2O-, -OCF2-, -CH=CH-, -C C-, -CH2CH2-, -(CH2)4-, -CH=CH-CH2CH2- or -CH2CH2-CH=CH-, with the proviso that at least one of them is -CH2O-, -OCH2-, -(CH2)3O- or -O(CH2)3-; R1 is C2-C20 alkenyl; Y1 is halogeno, cyano or substituted or unsubstituted C1-C20 alkyl; the rings A1, A2, A3 and A4 are each substituted or unsubstituted 1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4-phenylene; and m and n are each 0 or 1); and a liquid-crystal composition and a liquid-crystal display element containing at least one of these compounds. The compounds exhibit steep threshold value characteristics, an excellent compatibility, a low viscosity, a quick response, and so on.

公开(公告)号：EP0857708A4

公开(公告)日：1998-11-18

申请号：EP96916337

申请日：1996-06-07

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MATSUI SHUICHI ,  SHIBATA KOUICHI ,  MIYAZAWA KAZUTOSHI ,  HACHIYA NORIHISA ,  NAKAGAWA ETSUO

IPC分类号： C07C17/16 ,  C07C22/04 ,  C07C22/08 ,  C07C25/18 ,  C07C25/24 ,  C07C43/174 ,  C09K19/04 ,  C09K19/30 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C07C22/00 ,  C07C22/02 ,  C07C31/13 ,  C07C33/14 ,  C07C33/24 ,  C07C33/34 ,  C07C33/38 ,  C07C33/40

CPC分类号： C07C43/1742 ,  C07C17/16 ,  C07C22/04 ,  C07C22/08 ,  C07C25/18 ,  C07C25/24 ,  C09K19/04 ,  C09K19/30 ,  C09K19/3001 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0448 ,  C09K2019/0451

摘要： Liquid crystal compounds being excellent in compatibility with other liquid crystal materials and stability and having a low viscosity and a high isotropic phase transition temperature; a liquid crystal composition containing at least one of the compounds, and a liquid crystal display element using the composition. The abovbe compounds are represented by the following general formula (I): R-A1-Z1-A2-Z2-A3-Z3-A4-(-CH2-)-mX, wherein R is H or C1 to C10 alkyl (one or more methylene (-CH2-) groups of which may be replaced by -O- or the like); m is an integer of 1 to 10; X is F, Cl, Br, I or OH; A1, A2, A3 and A4 are each trans-1,4-cyclohexylene or the like; and Z1, Z2 and Z3 are each independently -(CH2)2- or a covalent bond, with at least two of Z1, Z2 and Z3 being covalent bonds.

公开(公告)号：EP0688754A4

公开(公告)日：1996-04-17

申请号：EP94909299

申请日：1994-03-10

申请人： CHISSO CORP

发明人： OHNISHI NORIYUKI ,  MATSUI SHUUICHI ,  KONDO TOMOYUKI ,  GOTO YASUYUKI

IPC分类号： C07C17/04 ,  C07C17/23 ,  C07C17/26 ,  C07C17/358 ,  C07C25/24 ,  C07C45/51 ,  C07C45/59 ,  C09K19/30 ,  C07C25/18

CPC分类号： C07C17/23 ,  C07C17/04 ,  C07C17/2635 ,  C07C17/358 ,  C07C25/24 ,  C07C45/513 ,  C07C45/59 ,  C09K19/3001 ,  C09K19/3048 ,  C07C47/457 ,  C07C49/697

摘要： To provide a liquid crystal compound, a dicyclohexylethylene derivative, which has a wide liquid crystal phase temperaturerange, a low viscosity, a large Δ⊂ value, a high stability, and an excellent compatibility with other liquid crystal compounds. A dicyclohexylethylene derivative represented by general formula (I), wherein R represents C1-C10 linear alkyl; and X represents fluorine or trifluoromethyl. This compound can widen the working range of a liquid crystal display element because of its high NI point, can improve the response speed of the display element because of its low viscosity, and can lower the voltage for driving the display element because of its high positive Δ⊂ value. Furthermore, it is so stable against changes in environmental factors that it can be used in various liquid crystal display elements of, for example, active matrix drive type using TFT.

摘要翻译： 提供一种液晶化合物，具有宽的液晶相温度范围，低粘度，大Δε值，高稳定性和与其它液晶化合物的优异相容性的二环己基乙烯衍生物。 由通式（I）表示的二环己基乙烯衍生物，其中R表示C1-C10直链烷基; X代表氟或三氟甲基。 这种化合物由于其NI点高可以扩大液晶显示元件的工作范围，由于其低粘度可以提高显示元件的响应速度，并且由于其高正值可以降低用于驱动显示元件的电压 Δ⊂值。 此外，它对于环境因素的变化如此稳定，以至于它可用于例如使用TFT的有源矩阵驱动型的各种液晶显示元件。

公开(公告)号：EP0885875A4

公开(公告)日：1999-10-13

申请号：EP97902613

申请日：1997-02-07

申请人： CHISSO CORP

发明人： KONDO TOMOYUKI ,  MATSUI SHUICHI ,  MIYAZAWA KAZUTOSHI ,  SEKIGUCHI YASUKO ,  NAKAGAWA ETSUO

IPC分类号： C07C69/75 ,  C07C69/753 ,  C07C69/76 ,  C07D213/79 ,  C07D213/80 ,  C07D239/28 ,  C07D239/34 ,  C07D319/06 ,  C09K19/04 ,  C09K19/30 ,  C07D213/24 ,  C07D239/24 ,  C09K19/20 ,  C09K19/34 ,  G02F1/13

CPC分类号： C07D213/79 ,  C07C69/75 ,  C07C69/753 ,  C07C69/76 ,  C07D213/80 ,  C07D239/28 ,  C07D239/34 ,  C07D319/06 ,  C09K19/04 ,  C09K19/3001 ,  C09K19/3068

摘要： Liquid-crystal compounds represented by the general formula (1): Ra-A1-Z1-A2-Z2-A3-(-Z3-A4-)-m-Rb and having a liquid-crystal phase over a wide temperature range, a low viscosity, and an improved threshold voltage; a liquid-crystal composition; and a liquid-crystal display element containing the liquid-crystal composition (1), wherein Ra represents C1-20 alkyl in which at least one -CH2- may be replaced with -O-, etc. and at least one hydrogen atom may be replaced with a halogen atom; Rb is the same as Ra or is halogeno or cyano; A1, A2, A3, and A4 each independently represents a divalent ring group; Z1, Z2, and Z3 each independently represents C2-C4 alkenylene, -COO-, a covalent bond, etc., provided that at least one of Z1, Z2, and Z3 represents C2-C4 alkenylene and at least one of them represents -COO- or -OCO-; and m is 0 or 1.

公开(公告)号：EP0891961A4

公开(公告)日：1999-06-16

申请号：EP97903621

申请日：1997-02-27

申请人： CHISSO CORP

发明人： SHIBATA KOICHI ,  KONDO TOMOYUKI ,  MATSUI SHUICHI ,  MIYAZAWA KAZUTOSHI ,  HACHIYA NORIHISA ,  NAKAGAWA ETSUO

IPC分类号： C07C43/174 ,  C09K19/30 ,  C09K19/46 ,  C09K19/50 ,  C09K19/42 ,  G02F1/13

CPC分类号： C09K19/3001 ,  C07C43/1747 ,  C07C2601/14 ,  C09K19/3003 ,  C09K19/3028 ,  C09K19/46 ,  C09K19/50

摘要： Compounds represented by general formula (1), which exhibit nematic liquid crystal phases over widened temperature ranges and are lowered in viscosity and improved in low-temperature compatibility with other liquid crystal compounds and chemical stability as compared with the liquid crystal compounds of the prior art, wherein H1 to H8 are each hydrogen or halogeno, with at least one member of them being halogeno; R1 is C2-C20 alkyl wherein one methylene (-CH2-) group or two or more methylene groups that are not adjacent to each other are replaced by ethereal oxygen (-O-); Y1 is C1-C20 alkyl wherein one or more methylene groups may be replaced by oxygen, sulfur, dihydroxysilyl, dimethylsilylene, -CH=CH-, and/or -CC-; and X1 to X3 are each a covalent bond, 1,2-ethylene or 1,4-butylene.

摘要翻译： 通式（1）表示的化合物与现有技术的液晶化合物相比，在宽的温度范围内呈现向列型液晶相，粘度降低，与其他液晶化合物的低温相容性和化学稳定性提高 其中H1至H8各自为氢或卤代，其中至少一个为卤代; R1是C2-C20烷基，其中彼此不相邻的一个亚甲基（-CH2-）或两个或更多个亚甲基被醚氧（-O-）代替; Y 1是其中一个或多个亚甲基可被氧，硫，二羟基甲硅烷基，二甲基亚甲硅烷基，-CH = CH-和/或-CC-代替的C 1 -C 20烷基; X1至X3各自为共价键，1,2-亚乙基或1,4-亚丁基。