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    COMPOSITION FOR OPTICAL ARTICLES AND OPTICAL ARTICLES MADE THEREWITH
    1.
    发明公开
    COMPOSITION FOR OPTICAL ARTICLES AND OPTICAL ARTICLES MADE THEREWITH 有权

    公开(公告)号：EP3347383A1

    公开(公告)日：2018-07-18

    申请号：EP16770828.8

    申请日：2016-09-08

    申请人： PPG Industries Ohio, Inc.

    发明人： HEROLD, Robert, D. ,  BADARINARAYANA, Vivek

    IPC分类号： C08F18/24

    CPC分类号： C08G64/0291 ,  C08F18/24 ,  C09D4/00

    摘要： An exemplary polymerizable composition includes the reaction product of (a) diethyleneglycol bischloroformate; (b) allyl alcohol; (c) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (d) optionally, ethyleneglycol bischloroformate; and (e) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. Another exemplary polymerizable composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups is also described. A reaction product, a polymerizate including the polymerizable composition, and an optical article including the polymerizable composition are also provided.

    Plastic lens and process for preparing the lens
    2.
    发明授权
    Plastic lens and process for preparing the lens 有权
    塑料透镜，它们的制备方法

    公开(公告)号：EP1521102B1

    公开(公告)日：2006-12-27

    申请号：EP04022535.1

    申请日：2004-09-22

    申请人： HOYA CORPORATION

    发明人： Itoh, Shinsuke ,  Kosaka, Masahisa

    IPC分类号： G02B1/10 ,  C08F2/44 ,  C08F18/24

    CPC分类号： C08F18/24 ,  G02B1/041 ,  Y10T428/31507 ,  C08L69/00 ,  C08L31/00

    摘要： A plastic lens which comprises a plastic lens substrate obtainable by a process which comprises: mixing the following components (A) to (D): (A) a lens material monomer comprising diethylene glycol bisallylcarbonate or a monomer mixture comprising diethylene glycol bisallylcarbonate and monomers copolymerizable with diethylene glycol bisallylcarbonate, (B) an organic peroxide-based polymerization initiator, (C) a cobalt fluid comprising a cobalt compound represented by at least one of CoO.Al2O3 and Co.Al2O4 in a dispersant, and (D) at least one ultraviolet light absorbent selected from 2-hydroxy-4-octyloxybenzophenone, 2,2',4,4'-tetrahydroxy-4-octyloxybenzophenone and 2,2',4'-trihydroxy-4-octyloxybenzophenone; and casting the mixed fluid obtained by the mixing into a mold and polymerizing the fluid to obtain a plastic lens substrate are provided.

    Plastic lens and process for preparing the lens
    4.
    发明公开
    Plastic lens and process for preparing the lens 有权
    Kunststofflinse和Verfahren zu ihrer Herstellung

    公开(公告)号：EP1521102A1

    公开(公告)日：2005-04-06

    申请号：EP04022535.1

    申请日：2004-09-22

    申请人： HOYA CORPORATION

    发明人： Itoh, Shinsuke ,  Kosaka, Masahisa

    IPC分类号： G02B1/10 ,  C08F2/44 ,  C08F18/24

    CPC分类号： C08F18/24 ,  G02B1/041 ,  Y10T428/31507 ,  C08L69/00 ,  C08L31/00

    摘要： A plastic lens which comprises a plastic lens substrate obtainable by a process which comprises: mixing the following components (A) to (D): (A) a lens material monomer comprising diethylene glycol bisallylcarbonate or a monomer mixture comprising diethylene glycol bisallylcarbonate and monomers copolymerizable with diethylene glycol bisallylcarbonate, (B) an organic peroxide-based polymerization initiator, (C) a cobalt fluid comprising a cobalt compound represented by at least one of CoO·Al 2 O 3 and Co·Al 2 O 4 in a dispersant, and (D) at least one ultraviolet light absorbent selected from 2-hydroxy-4-octyloxybenzophenone, 2,2',4,4'-tetrahydroxy-4-octyloxybenzophenone and 2,2',4'-trihydroxy-4-octyloxybenzophenone; and casting the mixed fluid obtained by the mixing into a mold and polymerizing the fluid to obtain a plastic lens substrate are provided.

    摘要翻译： 一种塑料透镜，其包括可通过以下方法获得的塑料透镜基材：包括以下组分（A）至（D）：（A）包含二甘醇双烯丙基碳酸酯的透镜材料单体或包含二甘醇双烯丙基碳酸酯和单体可共聚的单体混合物 （B）有机过氧化物基聚合引发剂，（C）包含由分散剂中的CoO.Al 2 O 3和CoAl 2 O 4中的至少一种表示的钴化合物的钴液，和（D）至少一种 选自2-羟基-4-辛氧基二苯甲酮，2,2'，4,4'-四羟基-4-辛氧基二苯甲酮和2,2'，4'-三羟基-4-辛氧基二苯甲酮的紫外线吸收剂; 并将通过混合获得的混合流体浇铸到模具中并使流体聚合以获得塑料透镜基板。

    Process for preparing organic glasses
    8.
    发明公开
    Process for preparing organic glasses 失效
    制备有机玻璃的方法

    公开(公告)号：EP0346996A3

    公开(公告)日：1991-03-20

    申请号：EP89201532.2

    申请日：1989-06-14

    申请人： GREAT LAKES CHEMICAL ITALIA S.r.l.

    发明人： Renzi, Fiorenzo ,  Rivetti, Franco ,  Gagliardi, Claudio ,  Romano, Ugo

    IPC分类号： C08F18/24 ,  G02B1/04 ,  C09D131/00

    CPC分类号： C08F290/061 ,  C08F18/24 ,  G02B1/04 ,  C08L31/00

    摘要： Organic glasses and surface coatings are prepared, with short hardening cycles, by submitting to the action of U.V. light a liquid polymerizable composition containing at least one di-(allyl carbonate) or poly-(allyl carbonate) of a diol or polyol, a photoinitiator and a vinyl ester monomer and/or an organic peroxide. The composition can additionally contain small amounts of an organic compound selected from among those compounds which are used in the art in order to stabilize the organic polymers to the degrading action of U.V. light. The composition is preferably heated before being treated with U.V. iight.

    Liquid composition polymerizable to yield organic glasses with low water absorption and high thermal stability
    9.
    发明公开
    Liquid composition polymerizable to yield organic glasses with low water absorption and high thermal stability 失效
    用于生产具有低的吸水性和高的热稳定性的有机液体眼镜聚合性组合物。

    公开(公告)号：EP0321057A1

    公开(公告)日：1989-06-21

    申请号：EP88202886.3

    申请日：1988-12-14

    申请人： ENICHEM SYNTHESIS S.p.A.

    发明人： Renzi, Fiorenzo ,  Rivetti, Franco ,  Romano, Ugo

    IPC分类号： C07C69/96 ,  C08F18/24 ,  C08G64/00 ,  G02B1/04

    CPC分类号： C08G64/0291 ,  C08F18/24 ,  G02B1/04 ,  C08L31/00

    摘要： A liquid composition, polymerizable by free-radical polymerization to yield organic glasses which are endowed with characteristics of low water absorption and high thermal stability, is constituted by the product of transesterification of diallyl-carbonate with a cycloaliphatic diol or a mixture of cycloaliphatic diols, from among said diols 1,4-cyclohexane-di-methanol and 3(4),8(9)-bis-(hydroxymethyl)tricyclo[5.2.1.0 2.6 ]decane being preferred.

    摘要翻译： 的液体组合物，可聚合的通过自由基聚合，得到哪些被赋予了低吸水性和高的热稳定性的特性的有机眼镜，由二烯丙基碳酸酯的酯交换反应的产物与环脂族二醇或环脂族二醇的混合物构成， 从所述中间二醇1,4-环己烷二甲醇和3（4），8（9）双（羟甲基）三环[5.2.1.0 <2.6>]癸烷是优选的。

    Polyol(allyl carbonate) compositions and polymerizates prepared therefrom
    10.
    发明公开
    Polyol(allyl carbonate) compositions and polymerizates prepared therefrom 失效
    多元醇（烯丙基 - 碳酸酯） - 紫杉醇和天冬酰胺多糖。

    公开(公告)号：EP0144782A2

    公开(公告)日：1985-06-19

    申请号：EP84113443.0

    申请日：1984-11-07

    申请人： PPG INDUSTRIES, INC.

    发明人： Crano, John Carl ,  Haynes, Ronald Louis

    IPC分类号： C08F18/24 ,  C08F263/06

    CPC分类号： C08F18/24 ,  C08F263/06

    摘要： Polyol(allyl carbonate), e.g., diethylene glycol bis (allyl carbonate), are polymerized in solution, i.e., in an organic solvent, until from 15 to 50 percent of the allylic carbon-carbon linkages are consumed. The solvent is then removed yielding a product that is gel-free, syrupy viscous liquid of unpolymerized monomer and polymer. This liquid polymer can be polymerized to a hard, transparent material with less shrinkage. Also described is the addition of mono- or polyfunctional acrylates to the liquid polymer to produce a polymerizable mixture that can be cured quickly with the addition of a free-radical initiator.

    摘要翻译： 多元醇（碳酸烯丙酯），例如二甘醇双（碳酸烯丙酯）在溶液中，即在有机溶剂中聚合，直至消耗15至50％的烯丙基碳 - 碳键。 然后除去溶剂，得到无凝胶，未聚合单体和聚合物的糖浆状粘稠液体的产物。 该液体聚合物可以聚合成具有较小收缩率的硬质透明材料。 还描述了向液体聚合物中加入单官能或多官能丙烯酸酯以产生可通过添加自由基引发剂快速固化的可聚合混合物。