PROCESS FOR THE PREPARATION OF NOVOLAC ALKYLPHENOL RESINS

    公开(公告)号:EP3426502A1

    公开(公告)日:2019-01-16

    申请号:EP17712026.8

    申请日:2017-03-09

    摘要: Process for the preparation of a novolac alkylphenol resin using a defined mixture of mono- and dialkylphenols, an aldehyde, and an acid catalyst. The mixture of mono- and dialkylphenols comprises 20 to 70 mol % mono-alkylphenols having an alkyl group of 1 to 18 carbon atoms, and 30 to 80 mol % of dialkylphenols having alkyl groups of 1 to 18 carbon atoms. The molar ratio of aldehyde in comparison to the mono- and dialkylphenol mixture is greater than or equal to 1. Novolac alkylphenol resins prepared according to this invention contain, of each individual starting material phenolic monomer component, less than 0.5 mass %, and in the best case, less than 0.1 mass % in comparison to the total obtained alkylphenol resin.

    ENERGY-SENSITIVE RESIN COMPOSITION
    10.
    发明公开
    ENERGY-SENSITIVE RESIN COMPOSITION 审中-公开
    能量敏感型树脂组合物

    公开(公告)号:EP3275940A1

    公开(公告)日:2018-01-31

    申请号:EP16772560.5

    申请日:2016-03-24

    摘要: The present invention provides an energy-sensitive resin composition with which it is possible, even if the precursor polymer is heat-treated at low temperatures, to produce a film or molded article comprising an imide ring-containing polymer having excellent heat resistance, tensile elongation and chemical resistance with a low dielectric constant, or a film or molded article comprising an oxazole ring-containing polymer having excellent heat resistance, tensile elongation and chemical resistance. Also provided are a method of manufacturing the film or molded article; a method of forming a pattern using the energy-sensitive resin composition; and a permanent film having excellent heat resistance, tensile elongation and chemical resistance. The energy-sensitive resin composition comprises an imidazole compound (A) represented by formula (1a), a resin precursor component (B), and a solvent (S), wherein the resin precursor component (B) is at least one resin precursor component selected from the group consisting of: a monomer component comprising a diamine compound represented by formula (2), a dicarbonyl compound represented by formula (3a) and/or a tetracarboxylic acid dianhydride represented by formula (3b); and a precursor polymer having a repeating unit represented by formula (4).

    摘要翻译: 本发明提供一种能量敏感性树脂组合物,即使该前体聚合物在低温下进行热处理,也能够制造包含具有优异耐热性,拉伸伸长率的含酰亚胺环聚合物的膜或模制品 低介电常数的耐化学品性,或者含有具有优异的耐热性,拉伸伸长率和耐化学性的含恶唑环的聚合物的膜或模塑制品。 还提供了制造膜或模制品的方法; 使用能量敏感性树脂组合物形成图案的方法; 以及具有优异的耐热性,拉伸伸长率和耐化学性的永久性膜。 能量敏感性树脂组合物包含由式(1a)表示的咪唑化合物(A),树脂前体组分(B)和溶剂(S),其中树脂前体组分(B)为至少一种树脂前体组分 (2)表示的二胺化合物,式(3a)表示的二羰基化合物和/或式(3b)表示的四羧酸二酐的单体成分。 和具有由式(4)表示的重复单元的前体聚合物。