摘要:
PROBLEM TO BE SOLVED: To provide a method for recovering metal from non-ferrous metal refinement debris, capable of efficiently removing arsenic from copper refinement debris with a high arsenic content and recovering valuable metals such as copper and lead in a high yield. SOLUTION: The non-ferrous metal refinement debris containing 0.1-30 mass% arsenic is heated in an inert gas atmosphere at 400-1,200°C for 1-8 hr to separate arsenic through volatilization. Then, the heated non-ferrous metal refinement debris is soaked in an acidic aqueous solution having a pH of >1.5 and COPYRIGHT: (C)2008,JPO&INPIT
摘要:
PROBLEM TO BE SOLVED: To provide a method for stably and continuously producing granulated sodium iodide, in focusing on sodium iodide among metal iodides, in particular. SOLUTION: The production method for granulated sodium iodide involves processes of drying and granulating sodium iodide by feeding a sodium iodide aqueous solution with 45-60 mass% concentration under the atmosphere at 151-200°C; and accumulating further the solution onto the surfaces of the resultant dried sodium iodide powders one by one. Where, more suitably, the aqueous solution is fed under the atmosphere at 170-180°C. COPYRIGHT: (C)2009,JPO&INPIT
摘要:
PROBLEM TO BE SOLVED: To produce an aromatic nitrile from a halide without increasing the number of carbons. SOLUTION: In the method for producing an aromatic nitrile of formula (1): Ar-CN (wherein Ar is a substituted or nonsubstituted aromatic ring), an aromatic compound of formula (2): Ar-CH 2 -X (wherein Ar is a substituted or nonsubstituted aromatic ring and X is any of chlorine, bromine, and iodine) is reacted with ammonia water and simple substance iodine. COPYRIGHT: (C)2010,JPO&INPIT
摘要:
PROBLEM TO BE SOLVED: To provide a method for recovering iodine from waste fluids from a polarizing film production process which can easily and efficiently recover iodine and boron from waste fluids in a polarizing film production process. SOLUTION: The waste fluid in polarizing film production contains 2-35 g/l of iodine in terms of the total amount of iodine, 0.2-8 g/l of boron, and 0.6-11 g/l of potassium. The waste fluid is adjusted to have a pH of less than 7 and then subjected to electrodialysis by an electrodialyzer 1 to separate iodine as potassium iodide to reduce the total amount of iodine in the waste fluid to 0.5 g/l or less. Next, the waste fluid after the electrodialysis is passed through a strongly basic anion-exchange resin 6 to allow the remaining iodine to be adsorbed to the strongly basic anion-exchange resin 6 to reduce the total amount of iodine in the waste fluid to 0.01 g/l or less. Then, iodine is recovered from the potassium iodide and the strongly basic anion-exchange resin 6. COPYRIGHT: (C)2008,JPO&INPIT
摘要:
PROBLEM TO BE SOLVED: To provide a method for recovering iodine by which iodine can be recovered from a gas containing a volatile organic iodine compound with low energy and without the need for the thermal processing at a high temperature. SOLUTION: Air containing a volatile organic iodine compound such as methyl iodide and the like is introduced in a reaction tube 1 packed with a metal oxide catalyst 3 and then oxidation to decompose the volatile organic iodine compound in the air is performed by being in contact with the metal oxide catalyst 3 under a temperature condition of 80-250°C. Free iodine is separated from a produced oxidation gas by introducing the air containing the produced oxidation gas into an iodine recovering vessel 4 in which an iodine absorbing liquid such as a sodium hydroxide aqueous solution and the like is charged and then recovered. COPYRIGHT: (C)2007,JPO&INPIT
摘要:
PROBLEM TO BE SOLVED: To provide a metallic iodide product having excellent quality stabilization and easy to handle, such as the one represented by potassium iodide and to provide a package of the same. SOLUTION: Raw material powder having ≤1000 μm particle diameter is supplied between rolls to form a spherical potassium iodide granular body having ≥3 mm diameter in a compression granulation apparatus using a pair of the rolls having semi-spherical packets having ≥3 mm diameter. The potassium iodide product is manufactured from a mixture of the granular body with the powder housed together with the granular body. COPYRIGHT: (C)2004,JPO&NCIPI
摘要:
PROBLEM TO BE SOLVED: To provide a method for producing a pyrazole derivative and a method for producing an isoxazole derivative each using an easily available raw material in the absence of an acid catalyst.SOLUTION: The method for producing a pyrazole derivative comprises performing a first step of mixing a terminal alkyne and a strong basic compound and then further mixing and reacting with an aldehyde compound, a second step of mixing and reacting an oxidizing agent and a weak basic compound after the first step, and a third step of mixing and reacting a hydrazine derivative after the second step to produce a pyrazole derivative.
摘要:
PROBLEM TO BE SOLVED: To produce, by one-pot process, a three-coordinate hypervalent iodine compound from an organic iodine compound.SOLUTION: A three-coordinate hypervalent iodine compound is produced by one-pot by mixing an organic iodine compound with a chlorine-based oxidizing agent in a non-aqueous solvent under the coexistence of an organic salt comprising organic anion and some one cation selected from metal cation, ammonium cation which may be substituted and poly-ammonium cation which may be substituted.