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公开(公告)号：JP2002263476A
公开(公告)日：2002-09-17
申请号：JP2001393138
申请日：2001-12-26
申请人： SHELL INT RESEARCH
发明人： WAMBAUGH JAMES ALLEN
IPC分类号： B01J19/24 , B01J23/50 , B01J23/74 , B01J23/85 , B01J35/04 , B01J37/02 , C07B61/00 , C07C5/333 , C07C15/46
摘要： PROBLEM TO BE SOLVED: To provide a method of equalizing heat distribution in a reactor tube housing a catalyst. SOLUTION: When a catalyst monolith is used, reaction heat can be dispersed as desired and consequently a heat gradient is lowered and efficiently and catalyst performance are improved. The method of equalizing the heat distribution on the catalyst of the tubular reactor is provided and this method comprises packing >=1 catalytic monolith into the respective tubes of the tubular reactor.
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公开(公告)号：JPH11323289A
公开(公告)日：1999-11-26
申请号：JP7043299
申请日：1999-03-16
申请人： SHELL INT RESEARCH
IPC分类号： C09J109/00 , C08L53/00 , C08L53/02 , C08L57/00 , C08L93/00 , C09J123/20 , C09J153/02
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition capable of exhibiting excellent adhesiveness to both a woven fabric and a soft film made of a polyolefin, useful in the field of packing of plastic base and a disposable article by including a specific conjugated diene polymer. SOLUTION: This composition comprises (A) a poly-1-butene polymer, (B) a tackifier resin and (C) 3-25 wt.% of a (semi)liquid (partially) hydrogenated conjugated diene polymer having =75 wt.% hydrogenation ratio). Preferably the composition has 20-60 wt.% of the component A, 30-75 wt.% of the component B, a fixed amount of the component C and (D) 0-5 wt.% of a stabilizer such as an antioxidant.
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公开(公告)号：JPH11245340A
公开(公告)日：1999-09-14
申请号：JP37548498
申请日：1998-12-16
申请人： SHELL INT RESEARCH
摘要： PROBLEM TO BE SOLVED: To obtain a polyketone/polyamide multilayer structure useful for many applications. SOLUTION: The multilayer polymer structure comprises a polyketone polymer layer made of at least one type of polyketone polymer, a connecting layer made of at least one type of polyamide copolymer or polyamide monomer, and a polyamide layer made of at least one type of polyamide having a long aliphatic chain segment. In this case, the polyketone layer is adhered to the connecting layer. And, the connecting layer is connected to the polyamide layer. And, a method for manufacturing the multilayer polymer structure is provided.
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公开(公告)号：JPH11152238A
公开(公告)日：1999-06-08
申请号：JP23853098
申请日：1998-08-25
申请人： SHELL INT RESEARCH
IPC分类号： B01J27/228 , C07B61/00 , C07C27/22 , C07C29/16 , C07C45/50
摘要： PROBLEM TO BE SOLVED: To provide a method for hydroformylating an ethylene-based unsaturated compound. SOLUTION: In this method for hydroformylating an ethylene unsaturated compound with carbon monoxide and hydrogen in the presence of a catalyst system composed of (a) a platinum group cation, (b) a nonhalide, (c) at least one bidentate ligand of the formula; R R M RM R R (in the formula, M and M are each independently phosphorus, arsenic or antimony atom; Ra bifunctional cross-linking group containing 1-4 atoms) and (d) a halide anion selected from the group consisting of a chloride, an iodide, a bromide and its mixture, water in an amount larger than 0.6 wt.% based on the total of the reaction mixture and equal to or smaller than the solubility limit under the reaction conditions.
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公开(公告)号：JPH1128350A
公开(公告)日：1999-02-02
申请号：JP14042498
申请日：1998-05-08
申请人： SHELL INT RESEARCH
摘要： PROBLEM TO BE SOLVED: To enhance reaction efficiency by providing a draft tube equipped with a window or a slot in a reactor and circulating a process fluid through the window or the slot by the rotation of the impeller in the tube. SOLUTION: A reactor 10 suitable in use of reaction such as polymn., crystallization or the like for a polycondensation polymer has a draft tube having a slot 18 formed thereto built therein and an impeller 14 is arranged in the draft tube 16. The impeller 14 is rotated by external power through a shaft 12 and a process fluid is forcibly directed downwardly within the draft tube 16. At this time, a part of the process fluid is taken out of an outlet 24 as a product but the greater part thereof is repelled from the bottom part 10a of the reactor 10 to upwardly flow through an annular part 19 provided with a barrier plate 20 and heated/cooled by a heat exchange coil 28 to be returned into the draft tube 16 through the slot 18.
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公开(公告)号：JPH10287805A
公开(公告)日：1998-10-27
申请号：JP9439498
申请日：1998-04-07
申请人： SHELL INT RESEARCH
发明人： MODIC MICHAEL JOHN
摘要： PROBLEM TO BE SOLVED: To obtain a polymer composition having high toughness as well as excellent processability by compounding a modifying agent containing a specific block copolymer and a low-density polyolefin to a polyphenylene ether/ polystyrene blend. SOLUTION: A polyphenylene ether(PPE)/polystyrene(PS) blend is compounded with a modifying agent containing (A) a hydrogenated elastomeric block copolymer containing at least two dendrite terminal blocks composed of a polymerizable monovinyl aromatic compound (preferably styrene) and an elastomeric middle block composed of a polymerizable conjugated diene (preferably butadiene) and (B) a polyolefin having a density of
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公开(公告)号：JPH10130453A
公开(公告)日：1998-05-19
申请号：JP25903897
申请日：1997-09-24
申请人： SHELL INT RESEARCH
发明人： MODIC MICHAEL JOHN
摘要： PROBLEM TO BE SOLVED: To obtain a soft rubberlike thermoplastic elastomer compsn. which strongly adheres to a rigid (polar) substrate such as a polycarbonate or ABS by compounding a hydrogenated elastomeric block copolymer having a specified structure with a plasticiazer, an olefin-acrylate polymer, and a polyolefin. SOLUTION: The hydrogenated elastomeric block copolymer has terminal resin blocks each formed from at least two kinds of monovinylarom. compd. and a central elastomer block formed from a conjugated diene. The compsn. pref. contains 15-60wt.% block copolymer, 15-45wt.% plasticizer, 5-20wt.% olefin- acrylate polymer (pref. an ethylene-acrylate polymer), and 0.1-20wt.% polyolefin (pref. polypropylene).
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公开(公告)号：JP2731426B2
公开(公告)日：1998-03-25
申请号：JP21840789
申请日：1989-08-24
申请人： SHELL INT RESEARCH
IPC分类号： C08F4/658 , C08F4/60 , C08F4/654 , C08F4/6592 , C08F10/00
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公开(公告)号：JPH1036421A
公开(公告)日：1998-02-10
申请号：JP9239497
申请日：1997-04-10
申请人： SHELL INT RESEARCH
发明人： DE BOER ERIC JOHANNES MARIA , HESSEN BART , VAN DER HUIZEN ADRIAAN ALBERT , DE JONG WOUTER , VAN DER LINDEN ADRIANUS JOHANN , RUISCH BART JOHAN , SCHOON LODEWIJK , DE SMET HELEEN JOHANNA AUGUSTA , VAN DER STEEN FREDERIK HENDRIK , VAN STRIEN HUBERTUS CORNELIS T , VILLENA ALAN , WALHOF JUDITH JOHANNA BERENDIN
IPC分类号： C08F4/642 , B01J31/22 , C07F17/00 , C08C19/02 , C08F4/659 , C08F4/6592 , C08F8/04 , C08F36/04
摘要： PROBLEM TO BE SOLVED: To provide a catalyst which is more effective than a known catalysts, is stable, is active even when used in sufficiently low concentrations and is suitable for use in the hydrogenation of a polymer having ethylenic unsaturations by using a plurality of specified compounds. SOLUTION: This composition comprises a titanium compound represented by formula I, an alkali metal hydride which is initially added or produced in situ from an alkali-metal-terminated living polymer and/or an added alkyl alkali metal and hydrogen in the polymer solution, the molar ratio of the alkali metal to the titanium being at least 2:1, and a boron compound represented by formula II (wherein A1 and A2 are each cyclopentadienyl or indenyl; X1 and X2 are each H, a halogen, a lower alkyl, a lower alkoxyl or the like; and R1 , R2 and R3 are each a halogen, a lower alkyl, a lower alkoxyl or the like).
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