公开(公告)号：JPH1036421A

公开(公告)日：1998-02-10

申请号：JP9239497

申请日：1997-04-10

申请人： SHELL INT RESEARCH

发明人： DE BOER ERIC JOHANNES MARIA ,  HESSEN BART ,  VAN DER HUIZEN ADRIAAN ALBERT ,  DE JONG WOUTER ,  VAN DER LINDEN ADRIANUS JOHANN ,  RUISCH BART JOHAN ,  SCHOON LODEWIJK ,  DE SMET HELEEN JOHANNA AUGUSTA ,  VAN DER STEEN FREDERIK HENDRIK ,  VAN STRIEN HUBERTUS CORNELIS T ,  VILLENA ALAN ,  WALHOF JUDITH JOHANNA BERENDIN

IPC分类号： C08F4/642 ,  B01J31/22 ,  C07F17/00 ,  C08C19/02 ,  C08F4/659 ,  C08F4/6592 ,  C08F8/04 ,  C08F36/04

摘要： PROBLEM TO BE SOLVED: To provide a catalyst which is more effective than a known catalysts, is stable, is active even when used in sufficiently low concentrations and is suitable for use in the hydrogenation of a polymer having ethylenic unsaturations by using a plurality of specified compounds. SOLUTION: This composition comprises a titanium compound represented by formula I, an alkali metal hydride which is initially added or produced in situ from an alkali-metal-terminated living polymer and/or an added alkyl alkali metal and hydrogen in the polymer solution, the molar ratio of the alkali metal to the titanium being at least 2:1, and a boron compound represented by formula II (wherein A1 and A2 are each cyclopentadienyl or indenyl; X1 and X2 are each H, a halogen, a lower alkyl, a lower alkoxyl or the like; and R1 , R2 and R3 are each a halogen, a lower alkyl, a lower alkoxyl or the like).

公开(公告)号：JP2000159707A

公开(公告)日：2000-06-13

申请号：JP6909999

申请日：1999-03-15

申请人： SHELL INT RESEARCH

发明人： DRENT EIT ,  VAN DER STEEN FREDERIK HENDRIK ,  MOENE ROBERT

IPC分类号： B01J31/24 ,  C07B41/02 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C29/36 ,  C07C31/125 ,  C07C45/50

摘要： PROBLEM TO BE SOLVED: To efficiently carry out hydroformylation by reacting a raw material comprising compounds having a single ethylenically unsaturated group with carbon monoxide and hydrogen in the liquid phase in the presence of a catalyst system comprising a source of palladium cations, a source of anions, a source of bidentate ligands and a source of halides. SOLUTION: A feedstock comprising compounds having a single ethylenically unsaturated group is reacted with carbon monoxide and hydrogen in the liquid phase in the presence of a catalyst system comprising (A) a source of palladium cations, (B) a source of anions, (C) a source of one or more bidentate ligands represented by the formula R1R2M1RM2R3R4 (M1 and M2 are each phosphorus, arsenic or the like; R is a bivalent bridging group having 1-4 atoms in the bridge part; R1 to R4 are each a hydrocarbyl or the like) and (D) a source of halides such as chlorides or iodides and thereby hydrofromylated. The feedstock contains one or more dienes and/or further multiply unsaturated alkenes in an amount of 0.005-10 wt.% based on the total amount of the ethylenically unsaturated compounds and the component B contains the source of anions of an acid having a pKa value of -1 to +4 at 18 deg.C.

公开(公告)号：JPH1053614A

公开(公告)日：1998-02-24

申请号：JP13678997

申请日：1997-05-27

申请人： SHELL INT RESEARCH

发明人： DE BOER ERIC JOHANNES MARIA ,  HESSEN BART ,  VAN DER HUIZEN ADRIAAN ALBERT ,  DE JONG WOUTER ,  VAN DER LINDEN ADRIANUS JOHANN ,  RUISCH BART JOHAN ,  SCHOON LODEWIJK ,  DE SMET HELEEN JOHANNA AUGUSTA ,  VAN DER STEEN FREDERIK HENDRIK ,  VAN STRIEN HUBERTUS CORNELIS T ,  VILLENA ALAN ,  WALHOF JUDITH JOHANNA BERENDIN

IPC分类号： B01J31/22 ,  C07F17/00 ,  C08C19/02 ,  C08F8/04

摘要： PROBLEM TO BE SOLVED: To obtain a catalyst composition containing a titanium compound and an alkali metal compound, capable of exhibiting an excellent effect in a low concentration and capable of being effectively used for the hydrogenation of a polymer containing ethylenic unsaturated bonds. SOLUTION: This catalyst composition contains at least (A) a titanium compound of the formula (A1 is a heterocyclic five-membered ring containing a heteroatomic phosphorus or nitrogen; A2 is A1 , cyclopentadienyl, etc.; L1 , L2 are each H, a halogen, a lower alkyl, phenyl, etc.), and (B) an alkali metal hydride itself or the alkali metal hydride prepared from an alkali metal- terminated living polymer in the polymer solution in situ. The molar ratio of the alkali metal: titanium is preferably at least 2:1. The employment of the catalyst composition enables to hydrogenate an olefinic unsaturated polymer in a state dissolved in a hydrocarbon solvent, and also to hydrogenate the polymer after polymerized in a hydrocarbon solvent.

公开(公告)号：JPH1017607A

公开(公告)日：1998-01-20

申请号：JP5962797

申请日：1997-03-13

申请人： SHELL INT RESEARCH

发明人： DE BOER ERIC JOHANNES MARIA ,  HESSEN BART ,  VAN DER HUIZEN ADRIAAN ALBERT ,  DE JONG WOUTER ,  VAN DER LINDEN ADRIANUS JOHANN ,  RUISCH BART JOHAN ,  SCHOON LODEWIJK ,  DE SMET HELEEN JOHANNA AUGUSTA ,  VAN DER STEEN FREDERIK HENDRIK ,  VAN STRIEN HUBERTUS CORNELIS T ,  VILLENA ALAN ,  WALHOF JUDITH JOHANNA BERENDIN

IPC分类号： C07F7/28 ,  B01J31/12 ,  B01J31/22 ,  C07C17/00 ,  C07F17/00 ,  C08C19/02 ,  C08F4/64 ,  C08F4/6592 ,  C08F8/04 ,  C08F36/04

摘要： PROBLEM TO BE SOLVED: To obtain a catalyst compsn. which is useful for hydrogenating an ethylenially unsatd. polymer, is active at a sufficiently low concn., and it not required to be removed from the resultant hydrogenated polymer by incorporating a specific Ti compd. and a specific alkali metal hydride into the same. SOLUTION: This compsn. contains a Ti compd. represented by formula I wherein A1 is an indenyl group represented by formula II [wherein R1 and R2 are each a halogen, (substd.) phenyl, a lower alkyl, a (phenyl)alkoxy, phenoxy, benzyl, or a bulky group having at least one hetero atom (e.g. a tri- lower-alkylsilyl or -NPh2 ); n is 0-4; and m is 0-3]; A2 is A1 or (substd.) cyclopentadienyl; and L1 and L2 are each H, a halogen, a lower alkyl, phenyl, phenyloxy, etc.}, and an alkali metal hydride (e.g. lithium hydride) which is added as such or synthesized in situ in a polymer soln. from an alkyli-metal- terminated living polymer and/or an alkyli metal alkyl further added.