電磁鋼板用表面処理液、絶縁被膜付き電磁鋼板およびその製造方法
    1.
    发明专利
    電磁鋼板用表面処理液、絶縁被膜付き電磁鋼板およびその製造方法 有权
    电镀钢板表面处理液和绝缘涂层电工钢板及其制造方法

    公开(公告)号:JP2015004128A

    公开(公告)日:2015-01-08

    申请号:JP2014104440

    申请日:2014-05-20

    Abstract: 【課題】絶縁被膜中にクロム化合物を含まずとも耐食性が良好で、良好な被膜外観、耐水性および耐テンションパッド性が得られ、さらに高い層間抵抗を得ることが可能な絶縁被膜付き電磁鋼板を得るための表面処理液を提供する。【解決手段】本発明の電磁鋼板用表面処理液は、所定のアルコキシシラン(A)を0.1〜6.5質量%と、エポキシ基を有するシランカップリング剤(B)を1〜10質量%と、平均粒子径が300nm以下の酸化物微粒子(C)を、前記シランカップリング剤の含有量の15〜60質量%と、カルボン酸(D)を0.3〜5.0質量%と、を含有し、pHが5.0〜7.0であり、固形分の割合が3〜15質量%となるように調整されたことを特徴とする。【選択図】なし

    Abstract translation: 要解决的问题:提供一种用于获得具有优异耐腐蚀性的绝缘涂层的电工钢板的表面处理液体,即使绝缘涂层不含铬化合物,并且可以获得优异的涂层外观,耐水性和张力垫电阻 并进一步获得高层间电阻。解决方案:电工钢板用表面处理液含有0.1-6.5质量%的预定烷氧基硅烷(A),1-10质量%的具有环氧基的硅烷偶联剂(B) ,对于硅烷偶联剂的含量为15〜60质量%的平均粒径为300nm以下的氧化物微粒(C),和0.3〜5.0质量%的羧酸(D),调整为使pH 为5.0-7.0,固含量为3-15质量%。

    Electromagnetic steel sheet with semi-organic insulating film
    2.
    发明专利
    Electromagnetic steel sheet with semi-organic insulating film 有权
    具有半有机绝缘膜的电磁钢片

    公开(公告)号:JP2011099141A

    公开(公告)日:2011-05-19

    申请号:JP2009254271

    申请日:2009-11-05

    Abstract: PROBLEM TO BE SOLVED: To provide an electromagnetic steel sheet with a semi-organic insulating film which does not contain a chromium compound, and nonetheless is free from deterioration in corrosion resistance and water resistance, has excellent anti-powdering properties, flaw resistance, sticking properties, TIG weldability and punchability, and also has excellent appearance after stress relieving annealing. SOLUTION: In the semi-organic insulating film composed of inorganic components and an organic resin, as the inorganic components, a Zr compound, a B compound and an Si compound are respectively contained by at ratios in a dry film; the Zr compound (expressed in terms of ZrO 2 ): 20 to 70 mass%, the B compound (expressed in terms of B 2 O 3 ): 0.1 to 5 mass%, and the Si compound (expressed in terms of SiO 2 ): 10 to 50 mass%, and the balance organic resin is contained. COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 要解决的问题:为了提供一种不含铬化合物的半有机绝缘膜的电磁钢板,并且还具有耐腐蚀性和耐水性的劣化,具有优异的抗粉化性能,缺陷 电阻,粘着性,TIG焊接性和冲压性,并且在应力消除退火后也具有优异的外观。 解决方案:在由无机组分和有机树脂组成的半有机绝缘膜中,作为无机组分,在干膜中分别含有Zr化合物,B化合物和Si化合物, Zr化合物(以ZrO 2 SBS表示):20〜70质量%,B化合物(以B SB SB 2 SiO 2表示) >):0.1〜5质量%,Si化合物(以SiO 2 表示)为10〜50质量%,含有余量的有机树脂。 版权所有(C)2011,JPO&INPIT

    Method for manufacturing surface-treated steel sheet
    3.
    发明专利
    Method for manufacturing surface-treated steel sheet 审中-公开
    制造表面处理钢板的方法

    公开(公告)号:JP2010229522A

    公开(公告)日:2010-10-14

    申请号:JP2009080172

    申请日:2009-03-27

    Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a surface-treated steel sheet having adequate corrosion resistance and blackening resistance without performing a complicated manufacturing process.
    SOLUTION: This manufacturing method includes: bringing a surface of an Zn-Al-base plated steel sheet which contains 3-7 mass% Al into contact with an acidic aqueous solution which has a pH of 1.5-4.0 and contains nitrate ions that include HNO
    3 , KNO
    3 , NaNO
    3 , Ca(NO
    3 )
    2 or NH
    4 NO
    3 as an ion source; rinsing and drying the surface; and then forming a chromate-free chemical conversion coating on the resultant surface of the plated steel sheet.
    COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 要解决的问题:提供一种具有足够耐腐蚀性和耐黑变性的表面处理钢板的制造方法,而不进行复杂的制造工艺。 解决方案:该制造方法包括:将含有3-7质量%Al的Zn-Al基镀覆钢板的表面与pH为1.5-4.0的酸性水溶液接触并含有硝酸根离子 其中包括HNO 3,SBNO 3,SBNO 3,SBNO 3,SBN 3, SB>或NH 4 3 作为离子源; 冲洗和干燥表面; 然后在镀覆钢板的所得表面上形成不含铬酸盐的化学转化涂层。 版权所有(C)2011,JPO&INPIT

    Surface treatment composition and surface-treated steel sheet
    4.
    发明专利
    Surface treatment composition and surface-treated steel sheet 有权
    表面处理组合物和表面处理钢板

    公开(公告)号:JP2009275284A

    公开(公告)日:2009-11-26

    申请号:JP2008335387

    申请日:2008-12-27

    Abstract: PROBLEM TO BE SOLVED: To provide a surface treatment composition which contains no hexavalent chromium at all, exhibits excellent corrosion resistance, resistance to heat color change, and blackening resistance, and is excellent in adhesion with an organic resin layer formed in the upper layer. SOLUTION: The surface treatment composition includes, based on (A) 100 pts.mass of the solids in a titanium-containing aqueous solution obtained by mixing at least one titanium compound selected from the group consisting of a hydrolyzable titanium compound, a low condensate of a hydrolyzable titanium compound, titanium hydroxide, and a low condensate of titanium hydroxide with hydrogen peroxide water, 10-300 pts.mass of zirconium carbonate (B), and 50-200 pts.mass of an alkyl phosphate (C). The composition further includes a metal phosphate (D) in an amount of 5-20 mass% and silicon oxide (E) in an amount of 10-50 mass%, based on the total solids of the surface treatment composition. COPYRIGHT: (C)2010,JPO&INPIT

    Abstract translation: 要解决的问题:提供完全不含六价铬的表面处理组合物,其表现出优异的耐腐蚀性,耐热变色性和耐黑变性,并且与形成在有机树脂层中的有机树脂层的粘附性优异 上层。 解决方案:表面处理组合物包含基于(A)在通过混合至少一种选自下组的钛化合物的含钛水溶液中的100份固体的量,所述钛化合物选自可水解的钛化合物, 可水解钛化合物的低缩合物,氢氧化钛和氢氧化钛与过氧化氢水的低缩合物,10-300质量份的碳酸锆(B)和50-200磅的磷酸烷基酯(C) 。 基于表面处理组合物的总固体,组合物还包含5-20质量%的金属磷酸盐(D)和10-50质量%的氧化硅(E)。 版权所有(C)2010,JPO&INPIT

    Surface treated steel sheet
    5.
    发明专利
    Surface treated steel sheet 有权
    表面处理钢板

    公开(公告)号:JP2009161781A

    公开(公告)日:2009-07-23

    申请号:JP2007338975

    申请日:2007-12-28

    Abstract: PROBLEM TO BE SOLVED: To provide s surface treated steel sheet, wherein hexavalent chromium is not contained in a surface treatment composition and coating film, and excellent corrosion resistance and blackening resistance are ensured. SOLUTION: The surface of a galvanized steel sheet or aluminum plated steel sheet is provided with a surface treatment film of 0.1 to 3.0 kg/m 2 in adhesion amount formed by applying and drying a surface treatment composition (I) containing, based on 100 pts.mass, solid content of titanium-containing aqueous solution (A) obtained by mixing a titanium compound, such as a hydrolyzable titanium compound, and its low condensation product, with hydrogen peroxide water, 0.01 to 10 pts.mass nickel component (B), 1 to 100 pts.mass aluminum compound (C), 1 to 800 pts.mass fluorine-containing compound (D). and 30 pts.mass water soluble organic resin and/or water dispersible organic resin (H), and if necessary, containing one or more of a phosphoric acid compound, vanadic acid compound, and zirconium carbonate compound. COPYRIGHT: (C)2009,JPO&INPIT

    Abstract translation: 要解决的问题:提供表面处理组合物和涂膜中不含有六价铬的表面处理钢板,并且确保优异的耐腐蚀性和耐黑变性。 解决方案:镀锌钢板或镀铝钢板的表面设置有通过施加和干燥表面处理而形成的粘合量为0.1至3.0kg / m 2 SPF的表面处理膜 含有以100质量份计含有钛含量的钛化合物等钛化合物及其低缩合物的钛含量的水溶液(A)与过氧化氢水的混合量(I)为0.01 至10质量份镍成分(B),1〜100质量份铝化合物(C),1〜800质量份含氟化合物(D)。 和30重量份水溶性有机树脂和/或水分散性有机树脂(H),如果需要,含有一种或多种磷酸化合物,钒酸化合物和碳酸锆化合物。 版权所有(C)2009,JPO&INPIT

    Electromagnetic steel sheet having insulating coating
    6.
    发明专利
    Electromagnetic steel sheet having insulating coating 有权
    具有绝缘涂层的电磁钢板

    公开(公告)号:JP2014025139A

    公开(公告)日:2014-02-06

    申请号:JP2012168913

    申请日:2012-07-30

    Abstract: PROBLEM TO BE SOLVED: To provide an electromagnetic steel sheet having an insulating coating excellent in insulation properties, tension pad resistance and punchability even without containing chromium in the insulation film.SOLUTION: An electromagnetic steel sheet having an insulation film of the present invention comprises an insulation film formed by applying a surface treatment agent containing: at least one selected from trialkoxysilane and dialkoxysilane with a substituent connected to Si comprising solely of at least one nonreactive substituent selected from hydrogen, alkyl group and phenyl group and tetraalkoxysilane (A); a silane coupling agent (B); silica particle (C); and water on at least one surface of the electromagnetic steel sheet, followed by drying, in which the content of the silica particle in the insulation film is 10 to 60% based on Si and the average maximum diameter of the particle aggregate on the surface of the insulation film is 3.50 μm or less.

    Abstract translation: 要解决的问题:提供一种电绝缘涂层,其绝缘性能,张力垫耐受性和冲压性甚至不含绝缘膜中的铬。电解钢板具有本发明的绝缘膜的电磁钢板包括: 通过涂布表面处理剂形成的绝缘膜,所述表面处理剂含有选自三烷氧基硅烷和二烷氧基硅烷的至少一种,所述取代基与仅包含至少一个选自氢,烷基和苯基的非反应性取代基和四烷氧基硅烷(A)的Si连接; 硅烷偶联剂(B); 二氧化硅颗粒(C); 和水在电磁钢板的至少一个表面上,然后干燥,其中绝缘膜中的二氧化硅颗粒的含量基于Si为10至60%,并且表面上的颗粒聚集体的平均最大直径 绝缘膜为3.50μm以下。

    Insulating film treating liquid for magnetic steel sheet, and magnetic steel sheet with insulating film
    7.
    发明专利
    Insulating film treating liquid for magnetic steel sheet, and magnetic steel sheet with insulating film 有权
    绝缘膜绝缘膜处理液及绝缘膜磁性片

    公开(公告)号:JP2012177180A

    公开(公告)日:2012-09-13

    申请号:JP2011041477

    申请日:2011-02-28

    Abstract: PROBLEM TO BE SOLVED: To provide an insulating film treating liquid for magnetic steel sheets capable of forming an insulating film of a magnetic steel sheet with the insulating film which is excellent in both corrosion resistance and chalking resistance, and to provide a magnetic steel sheet with the insulating film formed using the same.SOLUTION: The insulating film treating liquid for magnetic steel sheets for forming the insulating film of the magnetic steel sheet contains, in an aqueous solvent, a Zr compound, a resin, and a nitrogen-containing compound having two or more N atoms and 10 or less carbon atoms. The content of the resin is 20 to 60 pts.mass based on 100 pts.mass of the Zr compound (in terms of ZrO). The content of the nitrogen-containing compound is such an amount that the molar ratio (N/Zr) of the N atoms in the nitrogen-containing compound to the Zr atoms in the Zr compound is in the range of 0.01 to 10.

    Abstract translation: 要解决的问题:为了提供能够形成具有优异的耐腐蚀性和耐粉化性的绝缘膜的电磁钢板的绝缘膜的电磁钢板的绝缘膜处理液,并且提供磁性 使用其形成绝缘膜的钢板。 解决方案:用于形成电磁钢板绝缘膜的电磁钢板用绝缘膜处理液在含水溶剂中含有Zr化合物,树脂和具有两个以上N原子的含氮化合物 和10个或更少的碳原子。 基于100重量份的Zr化合物(以ZrO 2 )计,树脂的含量为20〜60质量度。 含氮化合物的含量为含氮化合物中的N原子与Zr化合物中的Zr原子的摩尔比(N / Zr)在0.01〜10的范围内。 >版权所有(C)2012,JPO&INPIT

    Electrical steel sheet with inorganic insulating film
    8.
    发明专利
    Electrical steel sheet with inorganic insulating film 有权
    无电绝缘膜电工钢板

    公开(公告)号:JP2012132050A

    公开(公告)日:2012-07-12

    申请号:JP2010283576

    申请日:2010-12-20

    Abstract: PROBLEM TO BE SOLVED: To provide an electrical steel sheet with an inorganic insulating film which contains no chromium compound, and prevents degradation of corrosion resistance and water resistance without any degradation of the environment, and is excellent in powdering resistance, flaw resistance, sticking resistance, Tig weldability, and blanking property, and also excellent in uniformity of the film appearance after the stress relieving annealing.SOLUTION: The inorganic film containing, by a ratio to a total solid content mass of the inorganic film, 15-75% by mass of a Zr compound in terms of ZrO, and 25-85% by mass of a Si compound including sheet silica in terms of SiO, is formed on the surface of an electrical steel sheet.

    Abstract translation: 要解决的问题:提供一种不含铬化合物的无机绝缘膜的电工钢板,并且防止耐腐蚀性和耐水性降低而不会降低环境,并且耐粉化性,耐瑕疵性优异 耐粘着性,Tig焊接性,冲切性,以及应力消除退火后的膜外观均匀性优异。 < P>解决方案:以ZrO 2 15%〜75质量%的Zr化合物,以无机膜的总固体成分质量比计含有的无机膜 >,并且在电工钢板的表面上形成以SiO 2 为25〜85质量%的含有二氧化硅的Si化合物。 版权所有(C)2012,JPO&INPIT

    Electromagnetic steel plate with semiorganic insulating coating
    9.
    发明专利
    Electromagnetic steel plate with semiorganic insulating coating 有权
    具有绝缘绝缘涂层的电磁钢板

    公开(公告)号:JP2012028538A

    公开(公告)日:2012-02-09

    申请号:JP2010165389

    申请日:2010-07-22

    Abstract: PROBLEM TO BE SOLVED: To provide an electromagnetic steel plate with a semiorganic insulating coating which exhibits excellent sticking properties, TIG weldability, punching properties and also exhibits excellent appearance of coating, and in which corrosion resistance and water resistance do not deteriorate even if a chromium compound is not contained.SOLUTION: In the semiorganic insulating coating composed of an inorganic component and an organic resin, a B compound and an Si compound containing planar silica are contained as the inorganic component. In the dry coating, 0.1-10 mass% of the B compound (in terms of BO) and 30-80 mass% of the Si compound (in terms of SiO) containing planar silica are contained, and the remainder is organic resin.

    Abstract translation: 要解决的问题:为了提供一种具有优良粘附性能,TIG焊接性,冲压性能以及优异的涂层外观的半成品绝缘涂层的电磁钢板,其中耐腐蚀性和耐水性也不会劣化甚至 如果不含有铬化合物。 解决方案:在由无机组分和有机树脂组成的半成品绝缘涂层中,含有B化合物和含有平面二氧化硅的Si化合物作为无机组分。 在干涂层中,B化合物的0.1〜10质量%(以B 2 O 3 )和30- 含有80质量%的含有平面状二氧化硅的Si化合物(以SiO 2

    Electrogalvanized steel sheet
    10.
    发明专利
    Electrogalvanized steel sheet 审中-公开
    电化钢板

    公开(公告)号:JP2011042826A

    公开(公告)日:2011-03-03

    申请号:JP2009191181

    申请日:2009-08-20

    Abstract: PROBLEM TO BE SOLVED: To provide an electrogalvanized steel sheet having high corrosion resistance even when the deposition of a zinc-containing plated layer is reduced.
    SOLUTION: The electrogalvanized steel sheet has a metal layer having ≥0.02 g/m
    2 deposition per one surface and comprising Ti, Zr, Al, Nb or Ta with at least on one surface of steel sheet and the electrogalvanized layer having 0.5-8 g/m
    2 deposition per one surface on the metal layer.
    COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 要解决的问题:即使当含锌镀层的沉积减少时,也提供具有高耐腐蚀性的电镀锌钢板。 解决方案:电镀锌钢板具有至少在钢的一个表面上每个表面具有≥0.02g/ m 2 SP / 2沉积的金属层,并且包括Ti,Zr,Al,Nb或Ta 片和电镀锌层在金属层上每一个表面具有0.5-8g / m 2 SP / 2的沉积。 版权所有(C)2011,JPO&INPIT

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