公开(公告)号：JPH1077270A

公开(公告)日：1998-03-24

申请号：JP25229096

申请日：1996-09-03

申请人： NIPPON SODA CO

发明人： HAGIWARA KENJI ,  SASO HARUO

IPC分类号： C07D213/26 ,  C07D213/61 ,  C07D213/64

摘要： PROBLEM TO BE SOLVED: To provide a pyridine derivative useful as a raw material for agricultural chemicals, medicines, polymers, etc. SOLUTION: This pyridine derivative is represented by formula I [X is H, a halogen, a 1-6C alkyl, a 1-6C haloalkyl, a 1-6C alkoxy; (n) is 0-4], e.g. 2-(1- chlorovinyl) pyridine. The compound of formula I is obtained by treating a compound of formula II or its mineral acid salt with a base (e.g. sodium bicarbonate) in an aprotic solvent (e.g. acetonitrile) at 0-150 deg.C. The compound of formula I is especially useful as an intermediate for synthesizing a pyridylpyrrole derivative microbicide used for agriculture and horticulture and described in PCT/JP95/02479.

公开(公告)号：JPH09309885A

公开(公告)日：1997-12-02

申请号：JP15011696

申请日：1996-05-21

申请人： NIPPON SODA CO

发明人： HAGIWARA KENJI ,  SASO HARUO ,  ICHINOSE KOSUKE ,  YOKOTA YORI ,  SANO CHIKAAKI

IPC分类号： C07D401/04 ,  A01N43/40

摘要： PROBLEM TO BE SOLVED: To obtain a pyridylpyrrole compound useful for prevention of every kind of plant disease as a germicide for an agriculture and a horticulture. SOLUTION: This pyridylpyrrole compound is represented by formula I [R is cyano, carbamoyl, formyl, hydroxyiminomethyl, etc.; R is H, an alkylcarbonyloxymethyl, benzoyloxymethyl, alkoxycarbonyl, etc.; X is H, a halogen, an alkyl, an alkoxy, etc.; Y is H, a halogen, an alkyl, an alkoxy, etc.; Z is H, a halogen or an alkyl; (m) is 0 to 5; (n) is 0 to 4], e.g. 2-(3- chlorophenyl)-3-(2-pyridyl)-5-formylpyrrole. The compound of formula I is obtained by reacting phenylglycines of formula II with an acid anhydride of the formula (R 'CO)2 O [R ' is H, a 2-4C alkenyl (substituted by a halogen) or a 2-4C alkynyl] and ethynylpyridines of formula III (Z' is H or a 1-6C alkyl) in the presence of a tri-valent phosphorous compound and a dehydrating agent. The pyridylpyrrole compound is effective for preventing downy mildews of a cucumber and a grape and an epidemic of a potato.

公开(公告)号：JPH05310650A

公开(公告)日：1993-11-22

申请号：JP24134492

申请日：1992-08-18

申请人： NIPPON SODA CO

发明人： KISHIMOTO TAKASHI ,  SASO HARUO ,  YAMADA YASUO ,  MATSUDA MICHIHIKO ,  TAKAKUSA NOBUO ,  YAMAMOTO ATSUSHI

IPC分类号： A01N47/44 ,  A01N51/00 ,  A01N55/00 ,  C07C209/08 ,  C07C209/16 ,  C07C209/22 ,  C07C211/24 ,  C07C255/30 ,  C07C257/14 ,  C07C261/04 ,  C07C279/28 ,  C07C279/36 ,  C07C317/42 ,  C07C323/27 ,  C07C323/44 ,  C07C327/42 ,  C07C327/48 ,  C07C333/20 ,  C07D207/22 ,  C07D211/72 ,  C07D233/20 ,  C07D233/48 ,  C07D233/52 ,  C07D239/18 ,  C07D243/04 ,  C07D263/28 ,  C07D265/08 ,  C07D277/18 ,  C07D279/06 ,  C07F7/08 ,  C07F7/10

摘要： PURPOSE:To obtain a new compound, having remarkable insecticidal characteristics, safely usable and useful as an insecticide effective against especially Aphis gossypii Glover or Nephotettix cincticeps. CONSTITUTION:The compound of formula I [R1 is alkyl or alkenyl; R2 is H, aJky1 or COR3 (R3 is H or alkyl); X is NR4 (R4 is H or alkyl); l is 0 or 1; n is 0-7; Y is CH or N; Q is CN or NO2; Z is alkyl, alkenyl, alkynyl or OR5 (R5 is H, alkyl, aryl, etc.), etc.], e.g. N-(4-hydroxybutyl)-N'-methyl-N''- nitroguanidine. This compound of formula I is obtained by reacting a compound of formula II (A is O or S; R13 is lower alkyl) with a compound of the formula R2NH-(CH2)nZ in an organic solvent (e.g. DMF), as necessary, in the presence of a base (e.g. triethylamine) at 0 deg.C to the boiling point temperature of the solvent.

公开(公告)号：JP2006178274A

公开(公告)日：2006-07-06

申请号：JP2004372988

申请日：2004-12-24

申请人： Nippon Soda Co Ltd ,  日本曹達株式会社

发明人： SASO HARUO

IPC分类号： G03F7/004

摘要： PROBLEM TO BE SOLVED: To provide a method for converting the surface physical properties of an organic thin film with high efficiency, by photoirradiating the organic thin film containing a photosensitive compound formed on a substrate. SOLUTION: The method for converting surface physical properties of an organic thin film is characterized, by (A) photoirradiating the organic thin film containing a photosensitive compound, formed on a substrate via an organic solvent or (B) photoirradiating the organic thin film while being heated to 50-250°C, with the photosensitive compound having a protective group which is released by photoirradiation. COPYRIGHT: (C)2006,JPO&NCIPI

摘要翻译： 要解决的问题：为了提供通过光电化含有形成在基板上的感光性化合物的有机薄膜，高效率地转换有机薄膜的表面物理性质的方法。 转换有机薄膜的表面物理性质的方法的特征在于：（A）通过有机溶剂在基材上形成的含有感光性化合物的有机薄膜进行光照射，或（B）光电化有机薄膜 同时加热至50-250℃，光敏化合物具有通过光照射释放的保护基。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006122748A

公开(公告)日：2006-05-18

申请号：JP2004311046

申请日：2004-10-26

申请人： Nippon Soda Co Ltd ,  日本曹達株式会社

发明人： TAKAHASHI TOSHIAKI ,  SASO HARUO

IPC分类号： B05D7/24 ,  B01J19/00 ,  C03C17/28 ,  G03F7/004

摘要： PROBLEM TO BE SOLVED: To provide a method of forming a reactive organic thin film easily causing photoreaction using a general exposing apparatus in which a dense monomolecular film having small impurities is rapidly formed and a solution for forming the organic thin film using the forming method. SOLUTION: The method of forming the organic thin film comprises a process for bringing the solution for forming the organic thin film into contact with the surface of a base material, and the solution for forming the organic thin film is obtained by treating a photosensitive compound having a functional group containing a hetero atom with at least one kind selected from a metal, a metal oxide, a metallic salt, a metallic hydroxide, metallic alkoxides, a chelated or coordinated metallic compound, a hydrolyzed product obtained by treating the metallic alkoxides with water and an acid and water in an organic solvent. COPYRIGHT: (C)2006,JPO&NCIPI

摘要翻译： 要解决的问题：提供一种使用其中快速形成具有小杂质的致密单分子膜的一般曝光装置形成易反应的有机薄膜的方法，以及使用该方法形成有机薄膜的溶液 成型方法。 解决方案：形成有机薄膜的方法包括使用于形成有机薄膜的溶液与基材的表面接触的方法，并且用于形成有机薄膜的溶液是通过将 具有含有选自金属，金属氧化物，金属盐，金属氢氧化物，金属醇盐，螯合或配位金属化合物中的至少一种的杂原子的官能团的光敏化合物，通过处理金属 醇与水和酸和水在有机溶剂中反应。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2006110476A

公开(公告)日：2006-04-27

申请号：JP2004301024

申请日：2004-10-15

申请人： Nippon Soda Co Ltd ,  日本曹達株式会社

发明人： TAKAHASHI TOSHIAKI ,  FUJITA YOSHITAKA ,  HIDAKA TOMOYA ,  SASO HARUO

IPC分类号： B05D1/18

摘要： PROBLEM TO BE SOLVED: To provide a method for stably forming a fine organic thin film with reduced impurities which can rapidly form the film, and to provide a solution for forming the organic thin film used for the method. SOLUTION: The organic thin film forming method has a process of making the solution for forming the organic thin film into contact with the surface of a substrate. The organic thin film forming method is characterized in that the solution for forming the organic thin film is prepared by treating a metal based surfactant having a hydroxy group or a hydrolyzable group in a solvent with at least one kind selected from a metal, a metal oxide, a metal hydroxide, a metal carried on a carrier, a metal salt carried on a carrier, a metal oxide carried on a carrier, a chelated or coordinated metal compound and a metal nano particle, and water. The solution for forming the organic thin film is also disclosed. COPYRIGHT: (C)2006,JPO&NCIPI

摘要翻译： 要解决的问题：提供一种稳定地形成可以快速形成膜的杂质减少的有机微细薄膜的方法，并提供用于形成用于该方法的有机薄膜的溶液。 解决方案：有机薄膜形成方法具有使用于形成有机薄膜的溶液与基板的表面接触的方法。 有机薄膜形成方法的特征在于用于形成有机薄膜的溶液是通过在选自金属，金属氧化物中的至少一种的溶剂中处理具有羟基或可水解基团的金属基表面活性剂 载体上的金属氢氧化物，载体上的金属，载体上承载的金属盐，承载在载体上的金属氧化物，螯合或配位的金属化合物和金属纳米颗粒以及水。 还公开了用于形成有机薄膜的溶液。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2002356470A

公开(公告)日：2002-12-13

申请号：JP2001161107

申请日：2001-05-29

申请人： NIPPON SODA CO

发明人： SASO HARUO ,  SATOU KIYOSHI

IPC分类号： H01L51/50 ,  C07C321/28 ,  C07C321/30 ,  C07C391/02 ,  C07C395/00 ,  C09K11/06 ,  H05B33/14

摘要： PROBLEM TO BE SOLVED: To provide a material for organic luminescent element having a high efficiency of light emission using an aromatic compound including chalcogen as a constituting compound. SOLUTION: This organic luminescent element using the aromatic compound including chalcogen as the constituting compound is expressed by formula (I). [In the formula (I), Y is an atom belonging to an elements of 16th group in the long-form periodic table, Each R is independently H, CN group, a 1-6C (substituted)alkyl group, a 2-6C (substituted)alkenyl group, a T (C=O) group, a (substituted) amino group, a (substituted)aryl group, a (substituted)aralkyl group, Cl or Br atom, m is an integer of 0 to 2, T is a 1-6C alkyl group, a 1-6C alkoxy group, an amino group, mono- or di-substituted alkyl amino group.].

公开(公告)号：JP2006188487A

公开(公告)日：2006-07-20

申请号：JP2005292786

申请日：2005-10-05

申请人： Nippon Soda Co Ltd ,  日本曹達株式会社

发明人： SASO HARUO

IPC分类号： C07F7/18 ,  H01L51/50

摘要： PROBLEM TO BE SOLVED: To provide a compound which has excellent water repellency, can change the physical properties of surfaces with wavelength light of relative low energy, excellently changes water contact angles before and after irradiated with the light, and can form a high performance organic thin film, when an immersion time into substrates is short.
SOLUTION: The compound represented by formula (I) [X is a functional group containing a heterogeneous atom; R
1 is a 4 to 11C alkyl which may have a substituent; R
2 is a 1 to 4C alkyl which may have a substituent; (m) is an integer of 0 to 4; (n) is an integer of 6 to 30; G
1 is a divalent 1 to 3C saturated or unsaturated hydrocarbon group; Ar is an aromatic group which may have one or more substituents; G
2 is O or the like], and the organic thin film formed body on which an organic thin film is formed by coating the surface of a substrate with a solution containing the compound represented by formula (I).
COPYRIGHT: (C)2006,JPO&NCIPI

摘要翻译： 要解决的问题为了提供具有优异的防水性的化合物，可以用相对低的能量的波长的光改变表面的物理性能，在用光照射之前和之后都会改变水接触角，并且可以形成 高性能的有机薄膜，当浸入到底层的时间短。 解决方案：由式（I）表示的化合物[X是含有异质原子的官能团; R SB 1是可以具有取代基的4至11C烷基; R SB 2是可以具有取代基的1-4C烷基; （m）为0〜4的整数。 （n）为6〜30的整数， G 1 是二价1〜3饱和或不饱和烃基; Ar是可以具有一个或多个取代基的芳族基团; 通过用含有式（I）表示的化合物的溶液涂布基材的表面，形成有机薄膜的有机薄膜形成体，其中，G 2 为O等] 。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2004189674A

公开(公告)日：2004-07-08

申请号：JP2002359918

申请日：2002-12-11

申请人： Nippon Soda Co Ltd ,  日本曹達株式会社

发明人： SASO HARUO ,  TAKAHASHI TOSHIAKI

IPC分类号： C07D339/06 ,  C07D279/20 ,  C07D487/04 ,  C07D519/00 ,  H01L51/00 ,  H01L51/05 ,  H01L51/30

摘要： PROBLEM TO BE SOLVED: To provide a molecular aggregate composed of an electron-accepting compound having a wider flat structure part, having a molecular structure having an electron-accepting ability and having a molecular structure suitable for diversification and an electron-donating compound. SOLUTION: The molecular aggregate is composed of a compound represented by formula (1) (wherein n is an integer of 1-4) or its dihydro substance and a low molecular weight electron-donating compound. COPYRIGHT: (C)2004,JPO&NCIPI

公开(公告)号：JP2003192625A

公开(公告)日：2003-07-09

申请号：JP2001394662

申请日：2001-12-26

申请人： NIPPON SODA CO

发明人： AMANOKURA NATSUKI ,  SASO HARUO

IPC分类号： C07C41/16 ,  C07B61/00 ,  C07C43/205 ,  C07C46/00 ,  C07C50/10 ,  C08G65/32 ,  C08G65/321

摘要： PROBLEM TO BE SOLVED: To carry out an organic reaction in an aqueous medium using a unimolecular micelle (a star polymer) having little dependences on surfactant concentration or temperature or pH, and an excellent molecule uptake ability. SOLUTION: This aqueous reaction comprises carrying out the organic reaction in the presence of the star polymer having a hydrophobic structure as a core and hydrophilic structures as arms in the organic reaction using water or an aqueous solution of water and an inorganic substance and/or an organic substance as a solvent. COPYRIGHT: (C)2003,JPO