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    Conductive polymer aqueous suspension manufacturing method, conductive organic material, and electrolytic capacitor and manufacturing method thereof
    2.
    发明专利
    Conductive polymer aqueous suspension manufacturing method, conductive organic material, and electrolytic capacitor and manufacturing method thereof 有权
    导电聚合物水性悬浮液制造方法，导电有机材料和电解电容器及其制造方法

    公开(公告)号：JP2012138616A

    公开(公告)日：2012-07-19

    申请号：JP2012066041

    申请日：2012-03-22

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： SUGAWARA YASUHISA ,  SHINODA TOMOKI ,  TAKAHASHI NAOKI ,  YOSHIDA YUJI ,  SUZUKI SATOSHI ,  TOMIOKA YASUHIRO

    IPC分类号： H01G9/028 ,  C08G63/12 ,  C08L67/00 ,  C08L101/12 ,  H01B1/20 ,  H01B13/00

    摘要： PROBLEM TO BE SOLVED: To provide a conductive polymer aqueous suspension used for providing an organic material which excels in adhesion to a base material and in water resistance and has high conductivity, and a manufacturing method therefor.SOLUTION: A conductive polymer aqueous suspension according to an embodiment of the invention contains a conductive polymer, at least one kind of water soluble polyhydric alcohol, and at least one kind of water soluble organic substance having two or more functional groups which can be condensation polymerized with the water soluble polyhydric alcohol. The conductive polymer aqueous suspension can be manufactured by: recovering a conductive polymer obtained by chemically oxidizing and polymerizing a monomer for providing a conductive polymer using an oxidant in a solvent containing as dopant an organic acid or a salt thereof; letting an oxidant act upon the conductive polymer in an aqueous solvent containing polyacid; and further mixing at least one kind of water soluble polyhydric alcohol and at least one kind of water soluble organic substance having two or more functional groups which can be condensation polymerized with the water soluble polyhydric alcohol.

    摘要翻译： 要解决的问题：提供一种用于提供优异的与基材的粘附性和耐水性并且具有高导电性的有机材料的导电聚合物水性悬浮体及其制造方法。 解决方案：根据本发明的一个实施方案的导电聚合物水性悬浮液含有导电聚合物，至少一种水溶性多元醇和至少一种具有两个或更多个官能团的水溶性有机物质，其可以 与水溶性多元醇缩合。 导电聚合物水性悬浮液可以通过以下方法制造：回收通过在含有有机酸或其盐作为掺杂剂的溶剂中使用氧化剂化学氧化和聚合用于提供导电聚合物的单体而获得的导电聚合物; 使氧化剂在含有多酸的含水溶剂中作用于导电聚合物; 进一步混合至少一种水溶性多元醇和至少一种具有两个或更多个可与水溶性多元醇缩聚的官能团的水溶性有机物质。 版权所有（C）2012，JPO＆INPIT

    Solid electrolytic capacitor, and method of manufacturing the same
    3.
    发明专利
    Solid electrolytic capacitor, and method of manufacturing the same 有权
    固体电解电容器及其制造方法

    公开(公告)号：JP2011233739A

    公开(公告)日：2011-11-17

    申请号：JP2010103257

    申请日：2010-04-28

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： SUGAWARA YASUHISA ,  SHINODA TOMOKI ,  YOSHIDA YUJI ,  SUZUKI SATOSHI ,  TOMIOKA YASUHIRO

    IPC分类号： H01G9/028 ,  H01G9/00

    摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a solid electrolytic capacitor having low ESR and low LC, in which a conductive polymer layer can be easily formed.SOLUTION: This method of manufacturing the solid electrolytic capacitor includes a process to form a dielectric oxide film layer 2 on the surface of a valve action metal porous body 1, a process to form a conductive polymer layer 3 on the dielectric oxide film layer by immersing it in conductive polymer suspension, and a process to form a cathode layer on the conductive polymer layer. A process to make organic material powder which does not dissolve in the conductive polymer suspension adhere to the surface of the conductive polymer suspension before the conductive polymer suspension adhering onto the dielectric oxide film layer is completely dried and cured, and a process to form the conductive polymer layer by drying and curing the conductive polymer suspension, and a process to remove the organic material powder remained on the surface of the conductive polymer layer using a solvent in which only the organic material powder is dissolved are included in this method.

    摘要翻译： 解决的问题：提供一种制造具有低ESR和低LC的固体电解电容器的方法，其中可以容易地形成导电聚合物层。 解决方案：这种制造固体电解电容器的方法包括在阀作用金属多孔体1的表面上形成电介质氧化物膜层2的工艺，在电介质氧化物膜上形成导电聚合物层3的工艺 将其浸渍在导电聚合物悬浮液中的方法，以及在导电聚合物层上形成阴极层的工艺。 在导电聚合物悬浮液附着到电介质氧化膜层上之前，使导电聚合物悬浮液中不溶解的有机材料粉末粘附到导电聚合物悬浮液的表面上的方法被完全干燥和固化，并且形成导电 通过干燥和固化导电聚合物悬浮液的聚合物层，以及使用其中仅溶解有机材料粉末的溶剂除去导电聚合物层表面上残留的有机材料粉末的方法。 版权所有（C）2012，JPO＆INPIT

    Conductive polymer composition and solid electrolytic capacitor using the same
    6.
    发明专利
    Conductive polymer composition and solid electrolytic capacitor using the same 有权
    导电聚合物组合物和使用其的固体电解电容器

    公开(公告)号：JP2010095580A

    公开(公告)日：2010-04-30

    申请号：JP2008265867

    申请日：2008-10-15

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： SUGAWARA YASUHISA ,  SHINODA TOMOKI ,  TAKAHASHI NAOKI ,  KOBAYAKAWA RYUTA ,  SUZUKI SATOSHI

    IPC分类号： C08L101/02 ,  C08K5/1515 ,  C08L25/04 ,  C08L65/00 ,  C08L101/12 ,  H01B1/12 ,  H01G9/028

    CPC分类号： H01G9/028 ,  C08K5/06 ,  C08L25/18 ,  C08L65/00 ,  H01B1/122 ,  H01G11/48 ,  H01G11/56 ,  H01L51/0021 ,  H01L51/0037 ,  Y02E60/13 ,  C08L2666/22 ,  C08L2666/06

    摘要： PROBLEM TO BE SOLVED: To provide a conductive polymer composition with excellent water resistance and a solid electrolytic capacitor with low ESR, excellent reliability, and especially moisture resistance. SOLUTION: The conductive polymer composition with excellent water resistance is obtained by bringing a conductive polymer suspension containing a conductive polymer with a polyanion as a dopant and a compound with one epoxy group into a reaction by heating or ultraviolet-ray irradiation, and drying the suspension. The solid electrolytic capacitor with low ESR and excellent moisture resistance is obtained by using a conductive polymer layer 3 comprising the conductive polymer composition in a solid electrolyte layer. COPYRIGHT: (C)2010,JPO&INPIT

    摘要翻译： 要解决的问题：提供具有优异耐水性的导电聚合物组合物和具有低ESR，优异的可靠性，特别是耐湿性的固体电解电容器。 解决方案：具有优异耐水性的导电聚合物组合物通过将含有聚阴离子作为掺杂剂的导电聚合物的导电聚合物悬浮液和具有一个环氧基的化合物通过加热或紫外线照射而进行反应而获得， 干燥悬浮液。 通过在固体电解质层中使用包含导电性高分子组合物的导电性聚合物层3，可获得ESR低，耐湿性优异的固体电解电容器。 版权所有（C）2010，JPO＆INPIT

    Electroconductive polymer and solid electrolytic capacitor using it
    7.
    发明专利
    Electroconductive polymer and solid electrolytic capacitor using it 审中-公开
    使用它的电极聚合物和固体电解电容器

    公开(公告)号：JP2009209259A

    公开(公告)日：2009-09-17

    申请号：JP2008053391

    申请日：2008-03-04

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： TAKAHASHI NAOKI ,  KOBAYAKAWA RYUTA ,  SHINODA TOMOKI ,  SUGAWARA YASUHISA ,  SUZUKI SATOSHI

    IPC分类号： C08G61/12 ,  H01G9/028 ,  H01G9/04

    CPC分类号： H01G9/028 ,  C08G61/124 ,  C08G61/125 ,  C08G61/126 ,  H01G9/0036 ,  H01G11/48 ,  H01G11/52 ,  H01G11/56 ,  Y02E60/13 ,  Y10T29/41 ,  Y10T29/417

    摘要： PROBLEM TO BE SOLVED: To provide an electroconductive polymer of high electroconductivity as well as a solid electrolytic capacitor of low ESR. SOLUTION: The electroconductive polymer is polymerized on the surface of a dielectric layer by means of the chemically oxidative polymerization of a compound as a monomer, a dimer to a decamer in which alkyl groups are sterically head-tail regulated and 3-alkyl five-membered heterocyclic compounds are bonded at 2- and 5-position thereof, in a solution containing an aromatic dopant having at least one sulfonic acid group; and the solid electrolytic capacitor uses the electroconductive polymer as a solid electrolyte. COPYRIGHT: (C)2009,JPO&INPIT

    摘要翻译： 要解决的问题：提供高导电性的导电聚合物以及低ESR的固体电解电容器。 解决方案：导电聚合物通过化合物作为单体的化学氧化聚合，二聚体与其中烷基在空间头尾调节的十聚体和3-烷基 在含有具有至少一个磺酸基团的芳族掺杂剂的溶液中，五元杂环化合物的2-位和5-位键合; 并且固体电解电容器使用导电聚合物作为固体电解质。 版权所有（C）2009，JPO＆INPIT

    Conductive polymer, conductive polymer aqueous solution, conductive polymer film, solid electrolytic capacitor and method for producing the same
    8.
    发明专利
    Conductive polymer, conductive polymer aqueous solution, conductive polymer film, solid electrolytic capacitor and method for producing the same 审中-公开
    导电聚合物，导电聚合物水溶液，导电聚合物膜，固体电解电容器及其制造方法

    公开(公告)号：JP2012246427A

    公开(公告)日：2012-12-13

    申请号：JP2011120479

    申请日：2011-05-30

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： SUGAWARA YASUHISA ,  SHINODA TOMOKI ,  YOSHIDA YUJI ,  SUZUKI SATOSHI ,  TOMIOKA YASUHIRO

    IPC分类号： C08G61/12 ,  C08G73/00 ,  C08G85/00 ,  H01G9/00 ,  H01G9/028

    CPC分类号： H01G9/025 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08K5/42 ,  H01G9/0029 ,  H01G9/028 ,  Y10T29/417 ,  C08L65/00 ,  C08L101/12

    摘要： PROBLEM TO BE SOLVED: To provide a conductive polymer with high conductivity, a conductive polymer aqueous solution, a conductive polymer film, and furthermore a solid electrolytic capacitor compatible with a reduction in ESR and a method for producing the same.SOLUTION: The conductive polymer includes a monomeric organic acid having one anion group and one or more hydrophilic groups. The method for producing the solid electrolytic capacitor comprises the steps of forming a dielectric layer 2 on the surface of an anode conductor 1 made of a metal for valve action, forming a first conductive polymer compound layer 3A on the surface of the dielectric layer 2 through chemical oxidation and polymerization, or through electropolymerization of monomers to give the first conductive polymer compound layer 3A, and forming a second conductive polymer compound layer 3B through impregnation of the surface of the first conductive polymer compound layer 3A with a conductive polymer aqueous solution.

    摘要翻译： 要解决的问题：为了提供具有高导电性的导电聚合物，导电聚合物水溶液，导电聚合物膜，以及与减少ESR相容的固体电解电容器及其制造方法。 导电聚合物包括具有一个阴离子基团和一个或多个亲水基团的单体有机酸。 固体电解电容器的制造方法包括以下步骤：在由金属制成的阳极导体1的表面上形成电介质层2，在电介质层2的表面上形成第一导电高分子化合物层3A， 化学氧化和聚合，或通过单体的电聚合得到第一导电聚合物化合物层3A，以及通过用导电聚合物水溶液浸渍第一导电聚合物层3A的表面形成第二导电聚合物化合物层3B。 版权所有（C）2013，JPO＆INPIT

    Conductive polymer suspension and method of manufacturing the same, conductive polymer material, electrolytic capacitor, and solid electrolytic capacitor and method of manufacturing the same
    10.
    发明专利
    Conductive polymer suspension and method of manufacturing the same, conductive polymer material, electrolytic capacitor, and solid electrolytic capacitor and method of manufacturing the same 有权
    导电聚合物悬浮液及其制造方法，导电聚合物材料，电解电容器和固体电解电容器及其制造方法

    公开(公告)号：JP2012104851A

    公开(公告)日：2012-05-31

    申请号：JP2012000541

    申请日：2012-01-05

    申请人： Nec Tokin Corp ,  Necトーキン株式会社

    发明人： KOBAYAKAWA RYUTA ,  SHINODA TOMOKI ,  TAKAHASHI NAOKI ,  SUGAWARA YASUHISA ,  SUZUKI SATOSHI ,  NISHIYAMA TOSHIHIKO

    IPC分类号： H01G9/028 ,  C08G61/12 ,  H01G9/04

    摘要： PROBLEM TO BE SOLVED: To provide a conductive polymer suspension for providing a conductive polymer material with high conductivity and a method of manufacturing the same, and to provide a solid electrolytic capacitor with low ESR in particular and a method of manufacturing the same.SOLUTION: A monomer for providing a conductive polymer is chemically oxidized and polymerized by using an oxidizer in a solvent containing a dopant comprising a low-molecular organic acid or its salt to synthesize the conductive polymer, the conductive polymer is purified, and the purified conductive polymer and the oxidizer are mixed in an aqueous solvent containing a polyacid component to manufacture the conductive polymer suspension.

    摘要翻译： 要解决的问题：提供一种用于提供具有高导电性的导电聚合物材料的导电聚合物悬浮液及其制造方法，并且特别提供具有低ESR的固体电解电容器及其制造方法 。 解决方案：用于提供导电聚合物的单体通过在包含低分子有机酸或其盐的掺杂剂的溶剂中使用氧化剂进行化学氧化和聚合，以合成导电聚合物，纯化导电聚合物，和 将纯化的导电聚合物和氧化剂在含有多酸组分的水性溶剂中混合以制造导电聚合物悬浮液。 版权所有（C）2012，JPO＆INPIT