公开(公告)号：JPS6174304A

公开(公告)日：1986-04-16

申请号：JP19484084

申请日：1984-09-19

Applicant: Showa Denko Kk

Inventor： KUSHIBIKI NOBUO ,  KAI TAKASHI ,  MATSUYAMA HISATOKU

IPC: H01F1/12 ,  C10M125/00 ,  C10M161/00 ,  C10N10/04 ,  C10N10/16 ,  C10N20/06 ,  C10N30/02 ,  C10N40/02 ,  C10N40/14 ,  H01F1/44

CPC classification number: H01F1/44

Abstract: PURPOSE:To increase dispersibility by dispersing in an organic solvent the spherical particles of a highmolecular composite material which is composed of ferromagnetic powder and thermoplastic resin having functional groups. CONSTITUTION:A styrene-n-butyl acrylate copolymer 50wt. part and Fe3O4 50wt. part are mixed, and a composite thus formed is melted and kneaded at a temperature of 150 deg.C in a laboplastomill and then cooled down to be cured. Thereafter it is roughly crushed. A crushed material thus obtained, 30wt. part, and polyethylene glycol which is incompatible substantially with the copolymer are agitated in flask and then cooled down. A coagulated material thus obtained is dried after the polyethylene glycol is removed therefrom.

Abstract translation: 目的：通过在有机溶剂中分散由铁磁粉末和具有官能团的热塑性树脂组成的高分子复合材料的球形颗粒来提高分散性。 构成：苯乙烯 - 丙烯酸正丁酯共聚物50wt。 部分和Fe3O4 50wt。 部分混合，将这样形成的复合体在实验室模具中在150℃的温度下熔化和捏合，然后冷却以固化。 此后，它大致被压碎。 由此得到的粉碎物，30wt。 部分和与共聚物基本上不相容的聚乙二醇在烧瓶中搅拌，然后冷却。 从其中除去聚乙二醇后，将得到的凝固物干燥。

公开(公告)号：JPS60195128A

公开(公告)日：1985-10-03

申请号：JP5102684

申请日：1984-03-19

Applicant: Showa Denko Kk

Inventor： KAI TAKASHI ,  KUSHIBIKI NOBUO ,  SAEDA SHIGERU

IPC: C08J3/16

Abstract: PURPOSE: To obtain the titled very fine size-controlled particles of virtually shperical form, by incorporating a polybasic acid in a mixture of resin and an incompatible medium, stirring the system at temperatures above a specified level to disperse the resin followed by separation of said resin (particles) from the medium.
CONSTITUTION: A polybasic acid is incorporated in a mixture of a thermoplastic resin and a medium virtually incompatible with said resin, the resultant system being stirred at temperatures above the melting or softening point of the medium to fully disperse the resin (particles) followed by separation of said resin (particles) from the medium, thus obtaining the objective fine particles. The thermoplastic resin is e.g. polyethylene, polyamide. The medium is e.g. polyethylene glycol. The polybasic acid is e.g. sulfuric acid, sulfurous acid sulfonic acid, fuming sulfuric acid, phosphoric acid. The size of the particles finally obtained is ≤50μm.
COPYRIGHT: (C)1985,JPO&Japio

Abstract translation: 目的：通过将多元酸在树脂和不相容介质的混合物中混合，获得标准非常精细尺寸控制的实际形状的颗粒，在高于规定水平的温度下搅拌该系统以分散树脂，然后分离所述 树脂（颗粒）。 构成：将多元酸加入到与所述树脂实际上不相容的热塑性树脂和介质的混合物中，所得体系在高于介质的熔点或软化点的温度下搅拌以完全分散树脂（颗粒），然后分离 的所述树脂（颗粒），从而获得目标细颗粒。 热塑性树脂是例如。 聚乙烯，聚酰胺。 介质是例如 聚乙二醇。 多元酸是例如。 硫酸，亚硫酸磺酸，发烟硫酸，磷酸。 最终获得的粒子的大小为<50μm。

公开(公告)号：JPS581382B2

公开(公告)日：1983-01-11

申请号：JP16942179

申请日：1979-12-27

Applicant: SHOWA DENKO KK

Inventor： KUSHIBIKI NOBUO ,  YOSHIDA HARUO ,  YAMAGUCHI KANEYA

IPC: B01J20/281 ,  B01D15/08 ,  C07K1/16 ,  C07K14/76 ,  G01N30/88

公开(公告)号：JPS61152751A

公开(公告)日：1986-07-11

申请号：JP27390584

申请日：1984-12-27

Applicant: SHOWA DENKO KK

Inventor： KUSHIBIKI NOBUO

IPC: C08L23/00 ,  C08K3/00 ,  C08L23/08 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00

Abstract: PURPOSE:A resin composition that is composed of a copolymer from ethylene and a vinyl compound having a polar group and a magnetic material, thus having high flexibility, applicability of a variety of molding techniques and high effect of reflecting infrared light. CONSTITUTION:A resin composition which reflects infrared light is obtained by combining (A) a consisting of 95-50wt%, preferably 85-60wt% of ethylene and 5-50wt%, preferably 15-40wt% of a vinyl compound bearing a polar group such as vinyl acetate or acrylic acid and having a melt index of, preferably 100-400g/min at 190C with a ferrite with an average particle size of 0.01-10, preferably 0.01-3 micrometers, preferably represented by formula I and formula II, more preferably being a mixture of at least two kinds of particles different in their average size with particle size distribution expanded in an amount of 50-95wt% based on A.

公开(公告)号：JPS619264B2

公开(公告)日：1986-03-20

申请号：JP16942279

申请日：1979-12-27

Applicant: Showa Denko Kk

Inventor： KUSHIBIKI NOBUO ,  YAMAGUCHI KANEYA

IPC: C04B41/84 ,  A61L31/00 ,  B01J20/283 ,  C01B33/00 ,  C03C17/28 ,  C03C17/30 ,  C08K9/00 ,  C08K9/04 ,  G01N30/88

CPC classification number: C03C17/28

公开(公告)号：JPS6013818A

公开(公告)日：1985-01-24

申请号：JP12149883

申请日：1983-07-06

Applicant: SHOWA DENKO KK

Inventor： KUSHIBIKI NOBUO ,  KAI TAKASHI ,  SAEDA SHIGERU

IPC: C08J3/20

Abstract: PURPOSE:To obtain the titled spherical particles useful as a coating compound for baking, and a coating compound for electrostatic coating, by dispersing a thermoplastic resin and an inorganic filler into a specific medium atter heating while stirring, and separating the medium from it. CONSTITUTION:100pts.wt. thermoplastic resin (e.g., polyethylene, etc.) is blended with 0.5-50pts.wt. inorganic filler (e.g., carbon black, etc.) to give a composition. 1-70wt% composition is sufficiently dispersed into 99-30wt% medium (e.g., polyethylene glycol, etc.) having substantially no compatibility with the resin at a temperature >= the melting point or the softening point of the resin and the medium while stirring, and the medium is dissolved or washed and removed by the use of water or a low-boiling liquid organic compound.

公开(公告)号：JPS6131435A

公开(公告)日：1986-02-13

申请号：JP15048384

申请日：1984-07-21

Applicant: Showa Denko Kk

Inventor： KUSHIBIKI NOBUO ,  KAI TAKASHI ,  SAEDA SHIGERU

IPC: C08J3/16

Abstract: PURPOSE: To control the particle diameter and viscosity distribution and obtain dense spherical fine particles, by mixing a specific medium compound with a thermoplastic resin, adding an EO-PO block copolymer thereto, dispersing the copolymer in the melt state, and the cooling and solidifying the dispersion, and separating the particles.
CONSTITUTION: A compound expressed by the formula R-(OCH
2 XH
2 )-OR' (R and R' and H or 1W12C branched chain alkyl; n is ≥20) is used as a medium compound, and a thermoplastic resin is mixed therewith. A kind of block copolymer consisting of ethylene oxide and propylene oxide is added thereto, and the mixture is mixed and agitated at the melting point or the softening point or above of the respective components to form a dispersion system of the respective components in the melt state. The resultant dispersion system is then cooled to the solidifying point of the thermoplastic resin or below, solidified and separated. An EO-Po block copolymer having 50:50W97:3 weight ratio between the ethylene oxide and propylene oxide is used as the EO-PO block copolymer.
COPYRIGHT: (C)1986,JPO&Japio

Abstract translation: 目的：为了控制粒径和粘度分布，并获得致密的球形细颗粒，通过将特定介质化合物与热塑性树脂混合，向其中加入EO-PO嵌段共聚物，将共聚物分散在熔融状态，并冷却和固化 分散体，分离颗粒。 构成：将式R-（OCH 2 XH 2）-OR'（R和R'，H或1-12C支链烷基; n = 20）表示的化合物用作介质化合物，并将热塑性树脂混合 随之而来。 向其中加入一种由环氧乙烷和环氧丙烷组成的嵌段共聚物，并将混合物在各组分的熔点或软化点或以上混合并搅拌形成熔融状态的各组分的分散体系 。 然后将得到的分散体系冷却至热塑性树脂的凝固点以下，固化分离。 使用环氧乙烷与环氧丙烷之间的重量比为50:50-97:3的EO-Po嵌段共聚物作为EO-PO嵌段共聚物。

公开(公告)号：JPS60197734A

公开(公告)日：1985-10-07

申请号：JP5235684

申请日：1984-03-21

Applicant: SHOWA DENKO KK

Inventor： KAI TAKASHI ,  KUSHIBIKI NOBUO ,  SAEDA SHIGERU

IPC: C08J3/16

Abstract: PURPOSE:To provide the titled resin particles in a perfectly spherical form, having a narrow particle size distribution, by dispersing a polyamide resin in a particular medium contg. an anionic surfactant by heating, followed by separating. CONSTITUTION:A polyamide resin (A) (e.g., nylon 6), a medium (B) of the formula (wherein R, R' are H, 1-12C straight-chain or branched alkyl; R'' is H, CH3, C2H5; n is 20 or more) having a MW of 900-1,000,000 (e.g., polyoxyethylene), and 0.1-40% one or more anionic surfactants (C) based on said polyamide resin are mixed with stirring at a temp. of at least the m.p. or softening point of components A and B to disperse well, and then cooled to a temp. of at most the m.p. of the component A and at least the m.p. or softening point of the component B. Then, the component A is separated from the component B, etc. by procedures such as filtering and, if necessary, the component B is completely removed by washing with water or low-boiling org. compds., yielding the titled resin particles.

公开(公告)号：JPS5693043A

公开(公告)日：1981-07-28

申请号：JP16942179

申请日：1979-12-27

Applicant: SHOWA DENKO KK

Inventor： KUSHIBIKI NOBUO ,  YOSHIDA HARUO ,  YAMAGUCHI KANEYA

IPC: B01J20/281 ,  B01D15/08 ,  C07K1/16 ,  C07K14/76 ,  G01N30/88

Abstract: PURPOSE:To make a carrier ideal for the separation of water soluble high polymer, especially substance related to organisms by chemically connecting sugars onto the surface of porous inorganic particles through an organic silane compound containing gamma-glycidoxypropyl group. CONSTITUTION:Sugars selected from among monosaccharide, disaccharide and trisaccharide can be fixed easily on the surface of an inorganic particles if an organic silane compound as given in the formula I (X is Cl, OCH3 or OCH2CH3) is provided on the surface of a porous inorganic particles such as silica, alumina, zeorite or the like as spacer molecule. A carrir thus obtained is charged into a column of a fast gell precipitating chromatograph method (fast GPC method). If so, being a rigid construction, the carrier is usable under a high pressure/high velocity flow and hence ideal for separation of water soluble high polymer, especially protin, enzime or the like.

公开(公告)号：JPS54136592A

公开(公告)日：1979-10-23

申请号：JP4379578

申请日：1978-04-15

Applicant: SHOWA DENKO KK

Inventor： KUSHIBIKI NOBUO ,  MATSUMURA YUKIHIRO ,  YOKOTA MASAHISA ,  YAMAGUCHI KANEYA

IPC: C08F4/00 ,  C01G23/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

Abstract: PURPOSE:To provide an olefin polymn. catalyst component with remarkably enhanced polymn. activity by plasma treating a TiCl3-based olefin polymn. catalyst component at a low temp. CONSTITUTION:gamma-TiCl3 powder obtd. by reducing TiCl4 with metallic Al or the like is charged into a discharge device previously replaced with N2. The system is then evacuated to remove N2, H2 or the like is introduced to a press. of 0.005-5 Torr, and plasma is produced at an output of 0.001-200 W to plasma treat the gamma-TiCl3 powder. The treating time is above 1 sec and the treating temp. room temp.-200 deg.C. The resulting polymn. catalyst component, the plasma treated TiCl3 is used in polymn. of olefins in combination with an organo-metallic cpd., usually an org. Al cpd. such as Al(C2H5)3 or the cpd. and an electron donative cpd. The olefins may be 15 or less C olefins such as ethylene and propylene.