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公开(公告)号:JPH1129641A
公开(公告)日:1999-02-02
申请号:JP16191798
申请日:1998-06-10
申请人: WACKER CHEMIE GMBH
IPC分类号: G02C7/04 , C08F299/08 , C08G77/20 , C08G77/388 , C08G77/392 , C08G77/46 , D06M13/02 , D06M13/148 , D06M13/184 , D06M13/203 , D06M13/51 , D06M13/513 , D06M15/643 , G02B1/04
摘要: PROBLEM TO BE SOLVED: To obtain a new compound useful for modifying polymers, coating papers, sheets and fiber surface-forming bodies, and processing woven fabrics, mesh products, nonwoven fabrics and cloths, and useful in industries of cosmetics, maintenance materials and coating materials and a printing industry. SOLUTION: An organosilicon compound having an acrylate (methacrylate) group which contains a unit of formula I R is a 1-22C (substituted) SiC-bonded hydrocarbon residue; X is OR [R is H, a 1-8C (substituted) alkyl] or a group of formula II [R is a 2-60C (substituted) SiC-bonded hydrocarbon residue; (y)=2, 3; R is H or a 1-20C (substituted) hydrocarbon residue; (e), (f), (g) are each 0-200, and (e)+(f)+(g)>=1]; A is a group of formula III [R is a 2-60C hydrocarbon residue; (x)=2, 3; Z is 0 or NR ; R is H or methyl]; A' is a group of formula IV [R is a 2-60C (substituted) hydrocarbon residue; R is a 2-20C (substituted) hydrocarbon residue]; (a), (u) are each 0-2; (b), (c) are each 0-3; (a)+(b)+(c)+(u)
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公开(公告)号:JPH115948A
公开(公告)日:1999-01-12
申请号:JP15317998
申请日:1998-06-02
申请人: WACKER CHEMIE GMBH
发明人: DAUTH JOCHEN DIPL CHEM DR , DEUBZER BERNWARD DIPL CHEM DR , WOLFERSEDER JOSEF , SCHNITZER KLAUS
IPC分类号: C07C49/794 , C07C49/835 , C08K5/07 , C08L83/04 , C08L83/05 , C08L83/07 , C09D183/04 , C09D183/05 , C09D183/07 , C09J183/05 , C09J183/07
摘要: PROBLEM TO BE SOLVED: To obtain a crosslinkable compsn. that has a volatility and heat stability and is capable of sufficiently retarding the crosslinking reaction and assuring the closslinking reaction by compounding an organosilicon compd. having an aliph. carbon- carbon multiple bond and an organosilicon compd. having an Si-bonded hydrogen atom, or an organosilicon compd. having both a carbon-carbon multiple bond and an Si-bonded hydrogen atom, and a catalyst accelerating the addition of the Si-bonded hydrogen atom to the aliph. multiple bond and a retarder, which retards the addition and has a good thermal stability and volatility. SOLUTION: The organosilicon compd. having an aliph. carbon-carbon multiple bond is pref. one represented by formula I (wherein R is a hydrocarbon group having no multiple bond; and R is a hydrocarbon group, etc., having a multiple bond). The organosilicon compd. having an Si-bonded hydrogen atom is pref. one represented by formula II (wherein R is the same as in formula I). The organosilicon compd. (C) having both a multiple bond and an Si-bonded hydrogen atom is used. An example of the catalyst is fine platinum particles. The retarder is represented by formula III (wherein R is H, a 1-12C hydrocarbon group, etc.; R is H or a 1-12C hydrocarbon group; and X is OH, etc.).
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