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公开(公告)号：KR100454672B1
公开(公告)日：2004-11-03
申请号：KR1020010042050
申请日：2001-07-12
Applicant: 주식회사 나노코 , 주식회사 서돌티앤씨
IPC: C08L61/06
Abstract: PURPOSE: A nonflammable construction material using a room temperature curable phenol resin and its preparation method are provided, which material is improved in the heat resistance and the ignition resistance, and is reduced in the amount of smoke and toxic gases generated in ignition. CONSTITUTION: The nonflammable construction material comprises 1-80 wt% of a room temperature curable phenol resin; 10-70 wt% of a filler; 1-15 wt% of a curing agent; and the balance of an additive comprising a plasticizer, an accelerator, a lubricant, a coloring agent, and a modifier. Preferably the filler is selected from the group consisting of cement, clay, silica, gypsum, carbon fiber, glass fiber, boron fiber, wood meal, cotton flock, asbestos, quartz powder and their mixtures. The method comprises the steps of mixing the phenol resin, a curing agent, and an additive; adding a filler and a releasing agent to the mixture; injecting the mixture into a mold and curing it at the B-stage before the C-stage at a room temperature; and demolding the composition and post-curing it at 20-90 deg.C.
Abstract translation: 目的：提供一种使用可室温固化的酚醛树脂的不易燃建筑材料及其制备方法，该材料的耐热性和耐点燃性得到改善，并且在点燃时产生的烟雾和有毒气体的量减少。 构成：不燃性建筑材料包含1-80重量％的室温可固化酚醛树脂; 10-70重量％的填料; 1-15重量％的固化剂; 和余量的包含增塑剂，促进剂，润滑剂，着色剂和改性剂的添加剂。 优选地，填料选自由水泥，粘土，二氧化硅，石膏，碳纤维，玻璃纤维，硼纤维，木粉，棉屑，石棉，石英粉及其混合物组成的组。 该方法包括混合酚醛树脂，固化剂和添加剂的步骤; 向混合物中加入填料和脱模剂; 将混合物注入模具并在C阶段之前的B阶段在室温下固化它; 并将组合物脱模并在20-90℃下后固化。
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公开(公告)号：KR1020030006337A
公开(公告)日：2003-01-23
申请号：KR1020010042050
申请日：2001-07-12
Applicant: 주식회사 나노코 , 주식회사 서돌티앤씨
IPC: C08L61/06
CPC classification number: C08J3/242 , C08K3/013 , C08L61/06 , C08L2201/02
Abstract: PURPOSE: A nonflammable construction material using a room temperature curable phenol resin and its preparation method are provided, which material is improved in the heat resistance and the ignition resistance, and is reduced in the amount of smoke and toxic gases generated in ignition. CONSTITUTION: The nonflammable construction material comprises 1-80 wt% of a room temperature curable phenol resin; 10-70 wt% of a filler; 1-15 wt% of a curing agent; and the balance of an additive comprising a plasticizer, an accelerator, a lubricant, a coloring agent, and a modifier. Preferably the filler is selected from the group consisting of cement, clay, silica, gypsum, carbon fiber, glass fiber, boron fiber, wood meal, cotton flock, asbestos, quartz powder and their mixtures. The method comprises the steps of mixing the phenol resin, a curing agent, and an additive; adding a filler and a releasing agent to the mixture; injecting the mixture into a mold and curing it at the B-stage before the C-stage at a room temperature; and demolding the composition and post-curing it at 20-90 deg.C.
Abstract translation: 目的：提供使用室温固化型酚醛树脂的不易燃结构材料及其制备方法，该材料的耐热性和耐点燃性得到改善，并且在点燃时产生的烟雾和有毒气体的量减少。 构成：不燃性建筑材料包含1-80重量％的室温固化酚醛树脂; 10-70重量％的填料; 1-15重量％的固化剂; 和包含增塑剂，促进剂，润滑剂，着色剂和改性剂的添加剂的余量。 优选地，填料选自水泥，粘土，二氧化硅，石膏，碳纤维，玻璃纤维，硼纤维，木粉，棉绒，石棉，石英粉及其混合物。 该方法包括混合酚醛树脂，固化剂和添加剂的步骤; 向混合物中加入填料和脱模剂; 将混合物注入模具中并在室温的C阶段之前的B阶段固化; 并将组合物脱模并在20-90℃下进行后固化。
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公开(公告)号：KR100793265B1
公开(公告)日：2008-01-17
申请号：KR1020060048520
申请日：2006-05-30
Applicant: 주식회사 나노코
Abstract: 본 발명은 비티 수지 조성물 및 그 제조방법에 관한 것으로서,
비스말레이미드 30 내지 45 중량 %와 시아네이트 에스테르 55 내지 70 중량 %의 혼합비를 가지며, 분자량이 3900 내지 5100 인 BT 수지 조성물을,
비스페놀-에이 시아네이트 에스테르와 4,4-다이페닐 메탄 비스말레이미드를 캐틀에 투입하는 단계와, 140~200 ℃로 승온하여 3~6 시간 동안 반응을 유도하는 단계와, 온도를 100 ℃ 이하로 조정하고 용제를 투입하는 단계를 포함하여 구성된 제조방법으로 제조함으로써,
난연성이 우수한 동시에 유해 원소를 포함하지 않는 친환경적인 기판용 수지 조성물을 얻을 수 있다.
반도체 기판, BT수지, 비스말레이미드, 시아네이트 에스테르.-
Patent Agency Ranking
公开(公告)号：KR1020070114895A
公开(公告)日：2007-12-05
申请号：KR1020060048520
申请日：2006-05-30
Applicant: 주식회사 나노코
Abstract: A bismaleimide-triazine resin composition is provided to obtain an eco-friendly material for fabricating wafers or composite materials having excellent flame resistance, heat resistance, thermal and electrical properties and dimensional stability. A bismaleimide-triazine resin composition comprises 30-45 wt% of bismaleimide and 70-55 wt% of cyanate ester, and has a molecular weight of 3900-5100. The bismaleimide-triazine resin composition is obtained by the method comprising the steps of: polymerizing a cyanate ester monomer with bismaleimide monomer to induce a reaction therebetween; and accelerating the intermolecular bond to provide a macromolecule having a three-dimensional network structure.
Abstract translation: 提供双马来酰亚胺 - 三嗪树脂组合物以获得具有优异的阻燃性，耐热性，热和电性能和尺寸稳定性的晶片或复合材料制造的环保材料。 双马来酰亚胺 - 三嗪树脂组合物包含30-45重量％的双马来酰亚胺和70-55重量％的氰酸酯，分子量为3900-5100。 通过包括以下步骤的方法获得双马来酰亚胺 - 三嗪树脂组合物：将氰酸酯单体与双马来酰亚胺单体聚合以在其间引起反应; 并加速分子间键，提供具有三维网络结构的大分子。
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公开(公告)号：KR1020040022984A
公开(公告)日：2004-03-18
申请号：KR1020020054594
申请日：2002-09-10
Applicant: 주식회사 나노코
CPC classification number: C09K21/10 , C08K5/0066 , C08K5/21 , C08K5/3492 , C08K5/34922
Abstract: PURPOSE: Provided are a fire retardant containing non-halogen nitrogen compounds and layered silicate, and a preparation method thereof. The fire retardant reserves stable mechanical properties of a resin without using toxic halogen compounds, can be applied to electronic and industrial materials where fire retardants are needed. CONSTITUTION: The fire retardant comprises 80-90wt.% of a nitrogen compound containing no halogen component and 1-20wt.% of a layered silicate with nanometer size which has reduced polarity by treating with an organic compound. The layered silicate is selected from the group of montmorillonite, hectorite, vermiculite and saponite. The organic transformer is alkyl ammonium with the carbon chain number of 10 to 18. One or more of the nitrogen compounds are selected from the group of melamine derivatives consisting melamine, melamine phosphate and melamine cyanurate, the isocyanurate compounds consisting urea, urea derivatives, tris(2-hydroxyethyl)isocyanurate and triazine derivatives. The preparation method comprises the steps of: (a) treating with organic agent to reduce the polarity of the silicate layer; (b) mixing the 80-99wt.% of the nitrogen compound containing no halogen with 1-20wt.% of the layered silicate with less polarity from the step (a); and (c) conducting intercalation or delamination with the mixture from the step (b) at 180deg.C and under atmospheric pressure.
Abstract translation: 目的：提供含有无卤素氮化合物和层状硅酸盐的阻燃剂及其制备方法。 阻燃剂在不使用有毒卤素化合物的情况下保持树脂的机械性能稳定，可应用于需要阻燃剂的电子和工业材料。 构成：阻燃剂包含80-90重量％的不含卤素组分的氮化合物和1-20重量％的具有纳米尺寸的层状硅酸盐，其通过用有机化合物处理而极性降低。 层状硅酸盐选自蒙脱石，锂蒙脱石，蛭石和皂石。 有机变压器是碳链数为10至18的烷基铵。一种或多种氮化合物选自三聚氰胺，磷酸三聚氰胺和氰尿酸三聚氰胺三聚氰胺衍生物，由脲，脲衍生物，三 （2-羟乙基）异氰脲酸酯和三嗪衍生物。 制备方法包括以下步骤：（a）用有机试剂处理以降低硅酸盐层的极性; （b）从步骤（a）将80-99重量％的不含卤素的氮化合物与1-20重量％的极性较小的层状硅酸盐混合; 和（c）在180℃和大气压下，用步骤（b）的混合物进行插层或分层。
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公开(公告)号：KR1020120126883A
公开(公告)日：2012-11-21
申请号：KR1020110044988
申请日：2011-05-13
Applicant: 주식회사 나노코
Abstract: PURPOSE: A highly flame-retardant benzoxazine resin composition is provided to maximize flame retardance because char generation is remarkably high than existing benzoxazine compounds. CONSTITUTION: A highly flame-retardant benzoxazine resin composition is a thermosetting resin with a benzoxazine structure indicated in chemical formula 1 and comprises bisphenol-F in backbone. In chemical formula 1, each of R is an aryl group, a substituted or unsubstituted phenyl group, or substituted or unsubstituted C1-C8 alkyl group. The benzoxazine resin composition consists of 35-40 weight% of a phenol compound, 25-30 weight% of an aldehyde compound, and 30-40 weight% of amine per 100.0 weight% of the benzoxazine resin composition.
Abstract translation: 目的：提供高度阻燃的苯并恶嗪树脂组合物，以使阻燃性最大化，因为炭的产生显着高于现有的苯并恶嗪化合物。 构成：高阻燃苯并恶嗪树脂组合物是具有化学式1所示的苯并恶嗪结构的热固性树脂，并且包含骨架中的双酚F。 在化学式1中，R为芳基，取代或未取代的苯基或取代或未取代的C1〜C8烷基。 苯并恶嗪树脂组合物由35-40重量％的酚化合物，25-30重量％的醛化合物和30-40重量％的胺/ 100.0重量％的苯并恶嗪树脂组合物组成。
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公开(公告)号：KR1020020027701A
公开(公告)日：2002-04-15
申请号：KR1020000058276
申请日：2000-10-04
Applicant: 주식회사 나노코
Abstract: PURPOSE: Provided are a composition which impart fire retardancy to a final resin while retaining stable physical property of the resin without using harmful halogen, and a method for producing the same. CONSTITUTION: The composition comprises 80-99 parts by weight of phosphorus compound which does not contain halogen, 1-20 parts by weight of layered silicate having a reduced polarity by treatment with modifying agent. The composition is produced by the steps of (i) treating layered silicate with modifying agent to reduce its polarity; (ii) mixing 80-99 parts by weight of phosphorus compound(which does not contain halogen) with 1-20 parts by weight of the treated layered silicate; and (iii) intercalating the mixture at the temperature of 120-180 deg.C under atmospheric pressure and vacuum.
Abstract translation: 目的：提供对最终树脂赋予阻燃性同时保持树脂的物理性能而不使用有害的卤素的组合物及其制造方法。 构成：组合物包含80-99重量份不含卤素的磷化合物，1-20重量份通过用改性剂处理而具有极性降低的层状硅酸盐。 通过以下步骤制备组合物：（i）用改性剂处理层状硅酸盐以降低其极性; （ii）将80-99重量份磷化合物（其不含卤素）与1-20重量份处理过的层状硅酸盐混合; 和（iii）在大气压和真空下在120-180℃的温度下嵌入该混合物。
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公开(公告)号：KR100374258B1
公开(公告)日：2003-03-04
申请号：KR1020000058276
申请日：2000-10-04
Applicant: 주식회사 나노코
Abstract: PURPOSE: Provided are a composition which impart fire retardancy to a final resin while retaining stable physical property of the resin without using harmful halogen, and a method for producing the same. CONSTITUTION: The composition comprises 80-99 parts by weight of phosphorus compound which does not contain halogen, 1-20 parts by weight of layered silicate having a reduced polarity by treatment with modifying agent. The composition is produced by the steps of (i) treating layered silicate with modifying agent to reduce its polarity; (ii) mixing 80-99 parts by weight of phosphorus compound(which does not contain halogen) with 1-20 parts by weight of the treated layered silicate; and (iii) intercalating the mixture at the temperature of 120-180 deg.C under atmospheric pressure and vacuum.
Abstract translation: 目的：提供一种组合物，其在不使用有害卤素的情况下保持树脂的稳定物理性能的同时赋予最终树脂阻燃性的组合物及其制备方法。 构成：该组合物包含80-99重量份不含卤素的磷化合物，1-20重量份通过用改性剂处理而具有降低的极性的层状硅酸盐。 该组合物通过以下步骤制备：（i）用改性剂处理层状硅酸盐以降低其极性; （ii）将80-99重量份的磷化合物（其不含卤素）与1-20重量份的经处理的层状硅酸盐混合; 和（iii）在大气压和真空下，在120-180℃的温度下嵌入混合物。
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