-
公开(公告)号:KR1020000010907A
公开(公告)日:2000-02-25
申请号:KR1019980709054
申请日:1998-03-05
申请人: 주식회사 다이셀
IPC分类号: C07C69/757 , C07C35/37 , C07C205/18 , C07C233/23
CPC分类号: C07C29/50 , C07C35/37 , C07C62/06 , C07C62/24 , C07C67/05 , C07C67/08 , C07C67/29 , C07C67/31 , C07C68/02 , C07C69/757 , C07C69/96 , C07C205/18 , C07C205/41 , C07C205/55 , C07C219/24 , C07C233/23 , C07C233/32 , C07C233/74 , C07C235/40 , C07C265/10 , C07C271/34 , C07C2603/74 , C07C69/753 , C07C69/157
摘要: PURPOSE: An aerobic oxidation method of a substrate using imide compounds as a catalyst is disclosed in prior patent. Adamantanol can be obtained by applying the method to substrates such as adamantane. CONSTITUTION: To achieve the purpose, adamantane derivatives are formed effectively by using specific adamantane derivatives to aerobic oxidation in the presence of oxidation catalysts comprising imide compound or the imide compound and cocatalyst. The new adamantane derivatives are designated as formula 1. In formula 1, X1 is hydroxyl group, and X2 is nitro group, amino group, hydroxyl group, carboxyl group, hydroxymethyl group, or isocyanato group. X3 and X4 differ dependent on the groups of X1 and X2.
摘要翻译: 目的:在现有专利中公开了使用酰亚胺化合物作为催化剂的底物的好氧氧化方法。 金刚烷可通过将该方法应用于诸如金刚烷等底物而获得。 构成:为了达到目的,金刚烷衍生物通过在含有酰亚胺化合物或酰亚胺化合物和助催化剂的氧化催化剂存在下,使用特定的金刚烷衍生物进行有氧氧化而有效形成。 新的金刚烷衍生物被称为式1.在式1中,X 1是羟基,X 2是硝基,氨基,羟基,羧基,羟甲基或异氰酸酯基。 X3和X4根据X1和X2的不同而不同。