Silyl phosphine compound, process for producing silyl phosphine compound and process for producing InP quantum dots

    公开(公告)号:US11578266B2

    公开(公告)日:2023-02-14

    申请号:US16979340

    申请日:2019-03-20

    摘要: The silyl phosphine compound of the present invention is represented by the formula (1) and has an arsenic content of not more than 1 ppm. The process for producing a silyl phosphine compound of the present invention is a process comprising mixing a basic compound, a silylating agent and phosphine to obtain a solution containing a silyl phosphine compound, removing a solvent from the solution to obtain a concentrated solution of a silyl phosphine compound, and distilling the concentrated solution, wherein an arsenic content in the phosphine is adjusted to not more than 1 ppm by volume in terms of arsine. The process for producing InP quantum dots of the present invention uses, as a phosphorus source, a silyl phosphine compound represented by the formula (1) and having an arsenic content of not more than 1 ppm by mass. (For definition of R, see the specification.)

    Positive electrode active substance for lithium secondary battery and lithium secondary battery

    公开(公告)号:US11554968B2

    公开(公告)日:2023-01-17

    申请号:US17635521

    申请日:2020-08-27

    发明人: Masahiro Kikuchi

    IPC分类号: C01G51/00

    摘要: An object of the present invention is to provide a positive electrode active substance for a lithium secondary battery, the positive electrode active substance, when being used as a positive electrode active substance for a lithium secondary battery, being little in deterioration of cycle characteristics and being high in the energy density retention rate, even in repetition of charge and discharge at high voltages, and a lithium secondary battery little in deterioration of cycle characteristics and high in the energy density retention rate, even in repetition of charge and discharge at high voltages. The positive electrode active substance for a lithium secondary battery comprises a lithium cobalt-based composite oxide particle having a Ti-containing compound and an Mg-containing compound adhered on at least part of the particle surface.

    Production method of biarylphosphine

    公开(公告)号:US11453687B2

    公开(公告)日:2022-09-27

    申请号:US17600251

    申请日:2020-03-30

    IPC分类号: C07F9/50

    摘要: A production method by which a biarylphosphine useful as a Buchwald phosphine ligand can be obtained in high purity is provided through an industrially advantageous process. The production method of a biarylphosphine comprises a step A of reacting a lithiated product obtained through lithiation of a halogenated benzene derivative with a benzene derivative to obtain a biphenyl derivative, and a step B of the reacting the biphenyl derivative with a halogenated phosphine. In the step A, the charge molar ratio of the halogenated benzene derivative to the benzene derivative is preferably 1.0 to 5.0.

    POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR LITHIUM SECONDARY BATTERY AND LITHIUM SECONDARY BATTERY

    公开(公告)号:US20220298025A1

    公开(公告)日:2022-09-22

    申请号:US17635521

    申请日:2020-08-27

    发明人: Masahiro Kikuchi

    IPC分类号: C01G51/00

    摘要: An object of the present invention is to provide a positive electrode active substance for a lithium secondary battery, the positive electrode active substance, when being used as a positive electrode active substance for a lithium secondary battery, being little in deterioration of cycle characteristics and being high in the energy density retention rate, even in repetition of charge and discharge at high voltages, and a lithium secondary battery little in deterioration of cycle characteristics and high in the energy density retention rate, even in repetition of charge and discharge at high voltages. The positive electrode active substance for a lithium secondary battery comprises a lithium cobalt-based composite oxide particle having a Ti-containing compound and an Mg-containing compound adhered on at least part of the particle surface.

    PRODUCTION METHOD OF BIARYLPHOSPHINE

    公开(公告)号:US20220169667A1

    公开(公告)日:2022-06-02

    申请号:US17600251

    申请日:2020-03-30

    IPC分类号: C07F9/50

    摘要: A production method by which a biarylphosphine useful as a Buchwald phosphine ligand can be obtained in high purity is provided through an industrially advantageous process. The production method of a biarylphosphine comprises a step A of reacting a lithiated product obtained through lithiation of a halogenated benzene derivative with a benzene derivative to obtain a biphenyl derivative, and a step B of the reacting the biphenyl derivative with a halogenated phosphine. In the step A, the charge molar ratio of the halogenated benzene derivative to the benzene derivative is preferably 1.0 to 5.0.

    Modified zirconium phosphate tungstate, negative thermal expansion filler and polymer composition

    公开(公告)号:US11332599B2

    公开(公告)日:2022-05-17

    申请号:US17435139

    申请日:2020-02-28

    摘要: There is provided a modified zirconium phosphate tungstate which effectively suppresses the elution of phosphorus ions even when it contacts with water, can develop the performance excellent as a negative thermal expansion material, and can be dispersed in a polymer compound such as a resin, and use of which enables a low-thermal expansive material containing a negative thermal expansion filler to be well produced. The surface of a zirconium phosphate tungstate particle is coated with an inorganic compound containing one or two or more elements (M) selected from Zn, Si, Al, Ba, Ca, Mg, Ti, V, Sn, Co, Fe and Zr. The BET specific surface area of the zirconium phosphate tungstate particle is preferably 0.1 m2/g to 50 m2/g.