公开(公告)号：US06336956B1

公开(公告)日：2002-01-08

申请号：US08718696

申请日：1996-09-27

申请人： Serge Moreau ,  Bernard Sardan

发明人： Serge Moreau ,  Bernard Sardan

IPC分类号： B01D53047

CPC分类号： B01D53/047 ,  B01D2253/108 ,  B01D2253/30 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2257/102

摘要： Process for separating nitrogen from a gas mixture containing nitrogen and at least one gas which is less polar than nitrogen, and employing a differential gas adsorption technique, called PSA process, using an adsorbent of zeolite type, according to which the PSA process is used at a temperature of at least 40° C. by employing as adsorbent a zeolite whose nitrogen adsorption isotherm at 20° C. exhibits a curvature characterized by a parameter C defined by the formula: C = P 1 ⁢ q ⁡ ( P 2 ) P 2 ⁢ q ⁡ ( P 1 ) where q(P1) denotes the quantity of nitrogen adsorbed at pressure P1 and q(P2) that adsorbed at pressure P2, and the pressures P1 and P2 are defined respectively from the high and low pressures of the PSA cycle in question, C being equal to at least 2.5.

摘要翻译： 从含有氮气的气体混合物和至少一种比氮极性低的气体中分离氮气的方法，使用PSA法，使用沸石型吸附剂，采用差示气体吸附技术，称为PSA法 通过使用氮吸附等温线在20℃下的吸附等温线的沸石表现出由下式定义的曲线，其曲线由式（q）表示在压力下氮吸附量的曲线，其温度为40℃以上 在压力P2处吸附的P1和q（P2），压力P1和P2分别来自所讨论的PSA循环的高压和低压，C等于至少2.5。

公开(公告)号：US5658370A

公开(公告)日：1997-08-19

申请号：US501319

申请日：1995-07-12

申请人： Xavier Vigor ,  Pierre Petit ,  Serge Moreau ,  Bernard Sardan

发明人： Xavier Vigor ,  Pierre Petit ,  Serge Moreau ,  Bernard Sardan

IPC分类号： B01D53/06 ,  B01J20/18 ,  C01B21/04 ,  B01D53/047

CPC分类号： B01D53/047 ,  B01D53/06 ,  B01D2251/40 ,  B01D2253/1085 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/4006 ,  B01D53/02 ,  Y10S95/902

摘要： PSA process for the separation of nitrogen from a gaseous mixture containing nitrogen by selective adsorption of nitrogen from the gaseous mixture in an adsorbent mass with cyclic pressure variations. At least one nitrogen adsorption phase is carried out at high pressure and at least one nitrogen desorption phase is carried out at low pressure. The adsorbent mass is arranged in a rotating adsorber and at least 50% of the adsorbent mass is constituted by a zeolite exchanged with lithium by more than 50%.

摘要翻译： PSA方法，用于通过在具有循环压力变化的吸附剂块中从气态混合物中选择性吸附氮气，从含氮气体混合物中分离氮气。 在高压下进行至少一个氮吸附阶段，并且在低压下进行至少一个氮解吸附阶段。 吸附剂质量被布置在旋转的吸附器中，并且至少50％的吸附剂质量由与锂交换的沸石构成超过50％。

公开(公告)号：US5411577A

公开(公告)日：1995-05-02

申请号：US171423

申请日：1993-12-22

申请人： Serge Moreau ,  Bernard Sardan ,  Pierre Ehrburger

发明人： Serge Moreau ,  Bernard Sardan ,  Pierre Ehrburger

IPC分类号： B01D53/02 ,  B01D53/04 ,  B01J20/20 ,  B01D53/047

CPC分类号： B01J20/20 ,  Y10S95/903

摘要： A method for separating gases wherein the gases to be separated are contacted with a particulate composite material with a carbon matrix to selectively adsorb gases. The material contains a microporous phase which is essentially carbon with a microporous volume between 0.1 cm.sup.2 /g and 1 cm.sup.2 /g, which is associated with an amorphous mineral dispersed phase containing an oxide of silicon, aluminum, titanium or magnesium disposed on the carbon phase at a thickness of less than 10 nm.

摘要翻译： 一种用于分离气体的方法，其中待分离的气体与具有碳基质的颗粒状复合材料接触以选择性地吸附气体。 该材料含有微孔相，其基本上为碳，微孔体积为0.1cm 2 / g至1cm 2 / g，其与含有设置在碳相上的硅，铝，钛或镁的氧化物的无定形矿物分散相相关联 厚度小于10nm。

公开(公告)号：US5294585A

公开(公告)日：1994-03-15

申请号：US725469

申请日：1991-07-03

申请人： Serge Moreau ,  Bernard Sardan ,  Pierre Ehrburger

发明人： Serge Moreau ,  Bernard Sardan ,  Pierre Ehrburger

IPC分类号： B01D53/02 ,  B01D53/04 ,  B01J20/20 ,  B01J20/10 ,  B01J20/04 ,  B01J20/08

CPC分类号： B01J20/20 ,  Y10S95/903

摘要： The present invention concerns a polyphase particulate composite material containing a microporous phase which is essentially carbon whose microporous volume is between 0.1 cm.sup.3 /g and 1 cm.sup.3 /g, which is associated with an amorphous mineral dispersed phase essentially consisting of an oxide of silicon, aluminum, titanium or magnesium disposed on the carbon phase, at a thickness of less than 10 nm. The invention is also concerned with a process for the preparation of these composite materials, and the use thereof as a molecular sieve.

摘要翻译： 本发明涉及一种多相微粒复合材料，其包含微孔相，其微孔体积为0.1cm 3 / g至1cm 3 / g，其基本上为碳，其与无定形矿物分散相相关，所述无定形矿物分散相主要由硅氧化物，铝 ，设置在碳相上的钛或镁，厚度小于10nm。 本发明还涉及制备这些复合材料的方法及其作为分子筛的用途。