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公开(公告)号：US5147730A
公开(公告)日：1992-09-15
申请号：US790142
申请日：1991-11-07
申请人： Hideo Ogishi , Shigeru Umino , Kenji Takao , Hajime Kimura , Koji Yamato
发明人： Hideo Ogishi , Shigeru Umino , Kenji Takao , Hajime Kimura , Koji Yamato
CPC分类号： B05D7/16 , C09D163/00 , C23C22/83 , C23C2222/20 , Y10T428/12549 , Y10T428/12569 , Y10T428/12611 , Y10T428/12618 , Y10T428/12799
摘要： The improved corrosion-resistant steel plate with an organic coating comprises a steel plate having a zinc or zinc alloy plate layer which is overlaid with a chromate film which in turn is coated with an organic resin paint film. The organic resin coat comprises an epoxy resin having a dialkanolamine incorporated into its bisphenol A skeleton, an amino resin, and silica. The dialkanolamine combines with the amino resin to provide satisfactory curability at low temperatures; at the same time, it combines with the silica to provide a satisfactory film reinforcing effect. The organic coat formed of this composition can be effectively cured at low temperatures and yet it will neither dissolve nor soften upon swelling under the action of the alkali that is generated during cationic electrodeposition at the interface between the electrodeposited film and the organic coat. Thus, the organic coat has good paint adhesion, high corrosion resistance, as well as good workability and weldability and makes the steel plate suitable for use as an automotive part after painting. If the proportion of trivalent chromium in the chromate film and the amounts of zinc oxide and silica sol to be incorporated as additives are properly adjusted, the organic coating will exhibit satisfactory resistance to chromium dissolution and hence its paint adhesion and corrosion resistance are further improved to make the steel plate more suitable for use as an automotive part after painting.
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2.发明授权Steel plate with organic coating having improved corrosion resistance in as-worked state 失效具有有机涂层的钢板在工作状态下具有改善的耐腐蚀性
公开(公告)号：US5147729A
公开(公告)日：1992-09-15
申请号：US784130
申请日：1991-10-29
申请人： Hideo Ogishi , Kenji Takao , Shigeru Umino , Koji Yamato
发明人： Hideo Ogishi , Kenji Takao , Shigeru Umino , Koji Yamato
IPC分类号： B05D7/14 , B05D7/24 , B32B15/08 , B32B15/092 , B32B15/095 , C08G18/42 , C08G18/48 , C23C28/00
CPC分类号： C23C28/00 , Y10T428/12549 , Y10T428/12569 , Y10T428/12611 , Y10T428/12799
摘要： The improved corrosion-resistant steel plate with an organic coating comprises a steel plate having a zinc or zinc alloy plate layer which is overlaid with a chromate film which in turn is coated with an organic resin paint film. The organic resin coat comprises an epoxy resin which is prepared by reacting with an isocyanate compound and has a dialkanolamine incorporated into its bisphenol A skeleton, and silica. The dialkanolamine combines with a urethane-modified epoxy resin to provide satisfactory curability at low temperatures; at the same time, it combines with the silica to provide a satisfactory film reinforcing effect. The organic coat formed of this composition can be effectively cured at low temperatures and yet it will neither dissolve nor soften upon swelling under the action of the alkali that is generated during cationic electrodeposition at the interface between the electrodeposited film and the organic coat. Thus, the organic coat has good paint adhesion, high corrosion resistance, as well as good workability and as-worked corrosion resistance and makes the steel plate suitable for us an automotovie part after painting.
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公开(公告)号：US08962153B2
公开(公告)日：2015-02-24
申请号：US12441604
申请日：2007-11-08
申请人： Hideo Koumura , Akihiko Furuta , Yoshito Furuya , Hideo Ogishi , Susumu Sato , Rie Umebayashi , Satoru Ando , Shigeru Takano
发明人： Hideo Koumura , Akihiko Furuta , Yoshito Furuya , Hideo Ogishi , Susumu Sato , Rie Umebayashi , Satoru Ando , Shigeru Takano
CPC分类号： C23C2/06 , Y10T428/12799
摘要： A hot-dip Zn—Al alloy coated steel sheet exhibiting a beautiful coating appearance with metallic luster, in which no spangle or very fine spangles are formed, and having excellent blackening resistance and a method for manufacturing the hot-dip Zn—Al alloy coated steel sheet are provided. The hot-dip Zn—Al alloy coated steel sheet includes a hot-dip Zn—Al alloy coating layer containing 1.0 to 10 percent by mass of Al, 0.2 to 1.0 percent by mass of Mg, 0.005 to 0.1 percent by mass of Ni, and the balance being Zn and incidental impurities on at least one surface of a steel sheet. The manufacturing method includes the steps of dipping the steel sheet into a hot-dip Zn—Al alloy coating bath and pulling up and cooling the steel sheet, wherein the steel sheet pulled up from the coating bath is cooled to 250° C. at a cooling rate of 1° C. to 15° C./sec.
摘要翻译： 具有金属光泽的美观涂层外观的热浸Zn-Al合金涂层钢板，其中没有形成条纹或非常细的波纹，并且具有优异的耐黑变性，以及涂覆的热浸Zn-Al合金的制造方法 提供钢板。 热浸镀Zn-Al合金涂层钢板包括含有1.0〜10质量％的Al，0.2〜1.0质量％的Mg，0.005〜0.1质量％的Ni的热浸Zn-Al合金被膜， 余量为钢板的至少一个表面上的Zn和附带的杂质。 该制造方法包括以下步骤：将钢板浸入热浸Zn-Al合金涂层中并拉起和冷却钢板，其中从涂浴中拉出的钢板在 冷却速度为1℃至15℃/秒。
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4.发明申请公开(公告)号：US20100086806A1
公开(公告)日：2010-04-08
申请号：US12441604
申请日：2007-11-08
申请人： Hideo Koumura , Akihiko Furuta , Yoshito Furuya , Hideo Ogishi , Susumu Sato , Rie Umebayashi , Satoru Ando , Shigeru Takano
发明人： Hideo Koumura , Akihiko Furuta , Yoshito Furuya , Hideo Ogishi , Susumu Sato , Rie Umebayashi , Satoru Ando , Shigeru Takano
CPC分类号： C23C2/06 , Y10T428/12799
摘要： A hot-dip Zn—Al alloy coated steel sheet exhibiting a beautiful coating appearance with metallic luster, in which no spangle or very fine spangles are formed, and having excellent blackening resistance and a method for manufacturing the hot-dip Zn—Al alloy coated steel sheet are provided. The hot-dip Zn—Al alloy coated steel sheet includes a hot-dip Zn—Al alloy coating layer containing 1.0 to 10 percent by mass of Al, 0.2 to 1.0 percent by mass of Mg, 0.005 to 0.1 percent by mass of Ni, and the balance being Zn and incidental impurities on at least one surface of a steel sheet. The manufacturing method includes the steps of dipping the steel sheet into a hot-dip Zn—Al alloy coating bath and pulling up and cooling the steel sheet, wherein the steel sheet pulled up from the coating bath is cooled to 250° C. at a cooling rate of 1° C. to 15° C./sec.
摘要翻译： 具有金属光泽的美观涂层外观的热浸Zn-Al合金涂层钢板，其中没有形成条纹或非常细的波纹，并且具有优异的耐黑变性，以及涂覆的热浸Zn-Al合金的制造方法 提供钢板。 热浸镀Zn-Al合金涂层钢板包括含有1.0〜10质量％的Al，0.2〜1.0质量％的Mg，0.005〜0.1质量％的Ni的热浸Zn-Al合金被膜， 余量为钢板的至少一个表面上的Zn和附带的杂质。 该制造方法包括以下步骤：将钢板浸入热浸Zn-Al合金涂层中并拉起和冷却钢板，其中从涂浴中拉出的钢板在 冷却速度为1℃至15℃/秒。
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