Process for producing perfluorinated organic compounds
    2.
    发明申请
    Process for producing perfluorinated organic compounds 有权
    生产全氟化有机化合物的方法

    公开(公告)号:US20120095243A1

    公开(公告)日:2012-04-19

    申请号:US13378887

    申请日:2010-07-06

    CPC classification number: C07D317/42

    Abstract: A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.

    Abstract translation: 公开了一种制备全氟化官能化合物的方法,其包括:A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的(全)卤代烯烃存在下,使所述至少部分氢化的氟甲酸酯化合物与氟反应,并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子 双键,得到全氟化氟甲酸酯化合物。

    TFE-based thermoprocessable copolymers
    3.
    发明授权
    TFE-based thermoprocessable copolymers 失效
    基于TFE的热可加工共聚物

    公开(公告)号:US07544752B2

    公开(公告)日:2009-06-09

    申请号:US11191031

    申请日:2005-07-28

    CPC classification number: C08F214/262

    Abstract: TFE-based thermoprocessable copolymers having the following composition, expressed in percentage by moles on the total of the monomers: A) from 0.01 to 15% of the monomer of formula: CF2═CFOCF2OCF3  (a); A1) tetrafluoroethylene from 99.99 to 85%; optionally B) one or more (per)fluorinated comonomers having at least one unsaturation of ethylene type, different from TFE; the sum of the molar percentages A)+B) being such as to give polymers showing at least one melting peak at the thermogravimetric analysis (DSC).

    Abstract translation: 具有以下组成的基于TFE的热可加工共聚物,以单体总量的百分比表示:A)0.01至15%的式的单体:<?在线公式描述=“在线式” end =“lead”?> CF2-CFOCF2OCF3(a); <?in-line-formula description =“In-line formula”end =“tail”?> A1)从99.99到85%的四氟乙烯; 任选地B)一种或多种具有不同于TFE的乙烯类型的至少一个不饱和键的(全)氟化共聚单体; 摩尔百分比A)+ B)的总和使得在热重分析(DSC)下显示出至少一个熔融峰的聚合物。

    Process for preparing acylfluorides
    5.
    发明授权
    Process for preparing acylfluorides 有权
    制备酰氟的方法

    公开(公告)号:US06998506B2

    公开(公告)日:2006-02-14

    申请号:US11002463

    申请日:2004-12-03

    CPC classification number: C07C51/58 C07C53/50 C07C59/135

    Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2  (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1–C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.

    Abstract translation: 通过使羰基氟化物COF 2与通常形式的化合物反应来制备酰氟的方法

    Process for preparing acylfluorides
    6.
    发明授权
    Process for preparing acylfluorides 有权
    制备酰氟的方法

    公开(公告)号:US06852884B2

    公开(公告)日:2005-02-08

    申请号:US10461349

    申请日:2003-06-16

    CPC classification number: C07C51/58 C07C53/50 C07C59/135

    Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2  (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1-C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.

    Abstract translation: 通过使碳氟化物COF 2与具有以下通式的化合物反应来制备酰基氟的方法:其中:T是O或CF 2 R 1,R 2等同或不同,是F或R(O)t基团,其中R =直链或支链C1- 任选地含有一个或多个氧原子的C 7(全)氟代烷基,t是等于零或1的整数;其中使用负载在多孔化合物上的催化剂,所述催化剂选自:CsF,RbF,KF,AgF, 与其中一个或多个混合。

    Process for producing perfluorinated organic compounds
    7.
    发明授权
    Process for producing perfluorinated organic compounds 有权
    生产全氟化有机化合物的方法

    公开(公告)号:US08742142B2

    公开(公告)日:2014-06-03

    申请号:US13378887

    申请日:2010-07-06

    CPC classification number: C07D317/42

    Abstract: A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.

    Abstract translation: 公开了一种制备全氟化官能化合物的方法,其包括:A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的(全)卤代烯烃存在下,使所述至少部分氢化的氟甲酸酯化合物与氟反应,并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子 双键,得到全氟化氟甲酸酯化合物。

    Process for producing fluorinated organic compounds
    8.
    发明申请
    Process for producing fluorinated organic compounds 有权
    氟化有机化合物的制备方法

    公开(公告)号:US20130256588A1

    公开(公告)日:2013-10-03

    申请号:US13993154

    申请日:2011-12-16

    Abstract: A process for fluorinating hydrocarbon compounds, which comprises: A. providing a compound selected from the group consisting of straight-chain, branched-chain and cyclic alkanes, straight-chain, branched-chain and cyclic ethers, said compound comprising at least one carbon-hydrogen bond and being free from C(O)— functional groups; B. reacting said compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a compound wherein at least one carbon-hydrogen bond has been replaced by a carbon-fluorine bond. Compositions of partially fluorinated compounds obtained with the process are also disclosed.

    Abstract translation: 一种氟化烃化合物的方法,其包括:A.提供选自直链,支链和环烷烃,直链,支链和环醚的化合物,所述化合物包含至少一个碳 - 氢键并且不含C(O) - 官能团; 在至少一种包含至少一个碳 - 碳双键并且在所述双键的碳原子上具有至少一个氟或氯原子的(全)卤代烯烃存在下,使所述化合物与氟反应,得到 其中至少一个碳 - 氢键已被碳 - 氟键取代的化合物。 还公开了通过该方法获得的部分氟化化合物的组合物。

    Process for preparing acylfluorides
    10.
    发明申请
    Process for preparing acylfluorides 有权
    制备酰氟的方法

    公开(公告)号:US20050080291A1

    公开(公告)日:2005-04-14

    申请号:US11002463

    申请日:2004-12-03

    CPC classification number: C07C51/58 C07C53/50 C07C59/135

    Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2  (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1-C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.

    Abstract translation: 通过羰基氟化物COF 2与通式为T = CR 1 R 2(I)的化合物反应来制备酰氟的方法其中:T为O或CF 2 R 1和R 2等同或不同,为F或R(O)t基团,其中 R =任选含有一个或多个氧原子的直链或支链C 1 -C 7(全)氟代烷基,t是等于0或1的整数; 其中使用负载在多孔化合物上的催化剂,所述催化剂选自:CsF,RbF,KF,AgF,各自任选地与一种或多种其它物质混合。

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