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公开(公告)号:US20130245289A1
公开(公告)日:2013-09-19
申请号:US13885867
申请日:2011-11-17
Applicant: Vito Tortelli , Marco Galimberti
Inventor: Vito Tortelli , Marco Galimberti
IPC: C07C67/287 , C07C51/58 , C07D317/42
CPC classification number: C07C67/287 , C07C51/58 , C07C51/60 , C07C67/14 , C07C2601/14 , C07D317/14 , C07D317/34 , C07D317/42 , C07C69/63 , C07C53/50
Abstract: A process for producing a perfluorinated functional compound comprises the steps of: A) converting an at least partially hydrogenated alcohol into an at least partially hydrogenated ester compound; and B) reacting said at least partially hydrogenated ester compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated ester compound.
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公开(公告)号:US20120095243A1
公开(公告)日:2012-04-19
申请号:US13378887
申请日:2010-07-06
Applicant: Vito Tortelli , Marco Galimberti , Giuseppe Marchionni
Inventor: Vito Tortelli , Marco Galimberti , Giuseppe Marchionni
IPC: C07D317/42
CPC classification number: C07D317/42
Abstract: A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.
Abstract translation: 公开了一种制备全氟化官能化合物的方法,其包括:A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的(全)卤代烯烃存在下,使所述至少部分氢化的氟甲酸酯化合物与氟反应,并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子 双键,得到全氟化氟甲酸酯化合物。
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公开(公告)号:US07544752B2
公开(公告)日:2009-06-09
申请号:US11191031
申请日:2005-07-28
Applicant: Francesco Triulzi , Marco Apostolo , Vito Tortelli , Marco Galimberti
Inventor: Francesco Triulzi , Marco Apostolo , Vito Tortelli , Marco Galimberti
IPC: C08F116/12 , C07C43/17
CPC classification number: C08F214/262
Abstract: TFE-based thermoprocessable copolymers having the following composition, expressed in percentage by moles on the total of the monomers: A) from 0.01 to 15% of the monomer of formula: CF2═CFOCF2OCF3 (a); A1) tetrafluoroethylene from 99.99 to 85%; optionally B) one or more (per)fluorinated comonomers having at least one unsaturation of ethylene type, different from TFE; the sum of the molar percentages A)+B) being such as to give polymers showing at least one melting peak at the thermogravimetric analysis (DSC).
Abstract translation: 具有以下组成的基于TFE的热可加工共聚物,以单体总量的百分比表示:A)0.01至15%的式的单体:<?在线公式描述=“在线式” end =“lead”?> CF2-CFOCF2OCF3(a); <?in-line-formula description =“In-line formula”end =“tail”?> A1)从99.99到85%的四氟乙烯; 任选地B)一种或多种具有不同于TFE的乙烯类型的至少一个不饱和键的(全)氟化共聚单体; 摩尔百分比A)+ B)的总和使得在热重分析(DSC)下显示出至少一个熔融峰的聚合物。
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公开(公告)号:US07514512B2
公开(公告)日:2009-04-07
申请号:US11190893
申请日:2005-07-28
Applicant: Marco Apostolo , Francesco Triulzi , Vito Tortelli , Marco Galimberti
Inventor: Marco Apostolo , Francesco Triulzi , Vito Tortelli , Marco Galimberti
IPC: C08F214/26
CPC classification number: C07C68/00 , C07C41/48 , C07C41/54 , C07C43/313 , C08F14/18 , C07C69/96 , C08F2/02
Abstract: VDF-based curable fluoroelastomers having glass transition temperature lower than −35° C. and an amount of —COF end groups in the polymer lower than the sensitivity limit of the method using the FT-IR spectroscopy described in the present application.
Abstract translation: 玻璃化转变温度低于-35℃的VDF类固化性含氟弹性体,聚合物中-COF端基的量低于使用本申请所述的FT-IR光谱法的灵敏度极限。
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公开(公告)号:US06998506B2
公开(公告)日:2006-02-14
申请号:US11002463
申请日:2004-12-03
Applicant: Marco Galimberti , Walter Navarrini
Inventor: Marco Galimberti , Walter Navarrini
CPC classification number: C07C51/58 , C07C53/50 , C07C59/135
Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2 (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1–C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.
Abstract translation: 通过使羰基氟化物COF 2与通常形式的化合物反应来制备酰氟的方法
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公开(公告)号:US06852884B2
公开(公告)日:2005-02-08
申请号:US10461349
申请日:2003-06-16
Applicant: Marco Galimberti , Walter Navarrini
Inventor: Marco Galimberti , Walter Navarrini
CPC classification number: C07C51/58 , C07C53/50 , C07C59/135
Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2 (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1-C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.
Abstract translation: 通过使碳氟化物COF 2与具有以下通式的化合物反应来制备酰基氟的方法:其中:T是O或CF 2 R 1,R 2等同或不同,是F或R(O)t基团,其中R =直链或支链C1- 任选地含有一个或多个氧原子的C 7(全)氟代烷基,t是等于零或1的整数;其中使用负载在多孔化合物上的催化剂,所述催化剂选自:CsF,RbF,KF,AgF, 与其中一个或多个混合。
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公开(公告)号:US08742142B2
公开(公告)日:2014-06-03
申请号:US13378887
申请日:2010-07-06
Applicant: Vito Tortelli , Marco Galimberti , Guiseppe Marchionni
Inventor: Vito Tortelli , Marco Galimberti , Guiseppe Marchionni
IPC: C07D317/42
CPC classification number: C07D317/42
Abstract: A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.
Abstract translation: 公开了一种制备全氟化官能化合物的方法,其包括:A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的(全)卤代烯烃存在下,使所述至少部分氢化的氟甲酸酯化合物与氟反应,并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子 双键,得到全氟化氟甲酸酯化合物。
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公开(公告)号:US20130256588A1
公开(公告)日:2013-10-03
申请号:US13993154
申请日:2011-12-16
Applicant: Vito Tortelli , Marco Galimberti , Cristiano Monzani , Piero Gavezotti
Inventor: Vito Tortelli , Marco Galimberti , Cristiano Monzani , Piero Gavezotti
CPC classification number: C07C41/22 , C07C41/48 , C08G65/007 , C08G65/3236 , C09K5/00 , C07C43/126 , C07C43/315
Abstract: A process for fluorinating hydrocarbon compounds, which comprises: A. providing a compound selected from the group consisting of straight-chain, branched-chain and cyclic alkanes, straight-chain, branched-chain and cyclic ethers, said compound comprising at least one carbon-hydrogen bond and being free from C(O)— functional groups; B. reacting said compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a compound wherein at least one carbon-hydrogen bond has been replaced by a carbon-fluorine bond. Compositions of partially fluorinated compounds obtained with the process are also disclosed.
Abstract translation: 一种氟化烃化合物的方法,其包括:A.提供选自直链,支链和环烷烃,直链,支链和环醚的化合物,所述化合物包含至少一个碳 - 氢键并且不含C(O) - 官能团; 在至少一种包含至少一个碳 - 碳双键并且在所述双键的碳原子上具有至少一个氟或氯原子的(全)卤代烯烃存在下,使所述化合物与氟反应,得到 其中至少一个碳 - 氢键已被碳 - 氟键取代的化合物。 还公开了通过该方法获得的部分氟化化合物的组合物。
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公开(公告)号:US20130116483A1
公开(公告)日:2013-05-09
申请号:US13809486
申请日:2011-07-05
Applicant: Vito Tortelli , Marco Galimberti
Inventor: Vito Tortelli , Marco Galimberti
IPC: C07C17/04
CPC classification number: C07C17/04 , C07C41/22 , C07C19/12 , C07C43/123
Abstract: A process for the fluorination of haloolefins with elemental fluorine in the presence of anhydrous HF proceeds with high yield and selectivity in the product deriving from the addition of fluorine to the carbon-carbon double bond.
Abstract translation: 在无水HF存在下用元素氟氟化氟代烯烃的方法在从碳 - 碳双键中加入氟的产物中产生高产率和选择性。
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公开(公告)号:US20050080291A1
公开(公告)日:2005-04-14
申请号:US11002463
申请日:2004-12-03
Applicant: Marco Galimberti , Walter navarrini
Inventor: Marco Galimberti , Walter navarrini
CPC classification number: C07C51/58 , C07C53/50 , C07C59/135
Abstract: A process for preparing acylfluorides by reaction of carbonyl fluoride COF2 with compounds having general formula: T=CR1R2 (I) wherein: T is O or CF2 R1 and R2, equal or different, are F or a R(O)t radical, wherein R=linear or branched C1-C7 (per)fluoroalkyl, optionally containing one or more oxygen atoms, t is an integer equal to zero or 1; wherein a catalyst supported on porous compound is used, the catalyst being selected from: CsF, RbF, KF, AgF, each optionally in admixture with one or more of the others.
Abstract translation: 通过羰基氟化物COF 2与通式为T = CR 1 R 2(I)的化合物反应来制备酰氟的方法其中:T为O或CF 2 R 1和R 2等同或不同,为F或R(O)t基团,其中 R =任选含有一个或多个氧原子的直链或支链C 1 -C 7(全)氟代烷基,t是等于0或1的整数; 其中使用负载在多孔化合物上的催化剂,所述催化剂选自:CsF,RbF,KF,AgF,各自任选地与一种或多种其它物质混合。
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