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公开(公告)号:US08178068B2
公开(公告)日:2012-05-15
申请号:US10554982
申请日:2004-04-27
申请人: Sean Alexander Axon , Duncan Roy Coupland , Brian Thomas Horner , John Ridland , Ian Carmichael Wishart
发明人: Sean Alexander Axon , Duncan Roy Coupland , Brian Thomas Horner , John Ridland , Ian Carmichael Wishart
IPC分类号: C01B21/26
CPC分类号: C01B21/265 , B01J23/40 , B01J23/464 , B01J23/63 , B01J23/83 , B01J35/0006 , C01C3/0216
摘要: A catalyst charge for ammonia oxidation, including the Andrussow process, comprises a first stage ammonia oxidation catalyst capable of oxidizing 20 to 99% of designed ammonia throughput, to produce a first stage product gas comprising unreacted ammonia, oxygen and nitrogen oxides, and a second stage ammonia oxidation catalyst capable of completing the oxidation of unreacted ammonia. Low levels of nitrous oxide are produced an extended campaign lengths may be seen.
摘要翻译: 包括Andrussow工艺的氨氧化催化剂装料包括能够氧化20至99%设计的氨生产量的第一级氨氧化催化剂,以产生包含未反应的氨,氧和氮氧化物的第一级产物气体, 能够完成未反应氨的氧化的阶段氨氧化催化剂。 产生低水平的一氧化二氮可以看出延长的活动长度。
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公开(公告)号:US07427580B2
公开(公告)日:2008-09-23
申请号:US10489016
申请日:2002-08-22
IPC分类号: B01J23/00 , B01J23/70 , B01J23/74 , B01J23/745 , B01J23/80 , B01J23/84 , B01J23/85 , B01J23/86 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/12
CPC分类号: B01J23/862 , B01J23/005 , B01J23/8892 , B01J37/03 , C01B3/16 , C01B2203/0283 , C01B2203/1017 , C01B2203/1041 , C01B2203/1047 , Y02P20/52 , Y10S502/506 , Y10S502/508 , Y10S502/509 , Y10S502/524
摘要: A method is described for producing a high temperature shift catalyst, not requiring a reduction step prior to use, by precipitating a composition containing divalent and trivalent iron compounds and a modifier metal selected from trivalent chromium and/or manganese compounds from an aqueous solution containing iron and modifier metal salts with a base, and forming the resultant precipitate into shaped catalyst units, without exposing said precipitate to an oxidizing atmosphere at temperatures above 200° C.
摘要翻译: 描述了一种用于生产高温变换催化剂的方法,其不需要使用前的还原步骤,通过从含铁的水溶液中沉淀含有二价和三价铁化合物的组合物和选自三价铬和/或锰化合物的改性金属, 和与碱形成的改性金属盐,并将所得沉淀物形成成型催化剂单元,而在高于200℃的温度下不将所述沉淀物暴露于氧化气氛。
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公开(公告)号:US07323152B2
公开(公告)日:2008-01-29
申请号:US10485049
申请日:2002-07-03
CPC分类号: C10G49/002 , B01D53/0423 , B01D2257/2045 , B01D2257/30 , B01D2257/55 , B01D2257/602 , B01D2259/414 , B01J8/008 , B01J8/025 , B01J2208/0084 , B01J2208/00884 , B01J2208/025 , B01J2219/1923 , C01B3/386 , C01B21/265 , C01B2203/0261 , C01B2203/1011 , C01B2203/1258 , C01B2203/127 , C01C3/0216 , C01C3/0225 , C07C45/38 , C10G25/00 , Y02P20/52 , C07C47/04
摘要: A fixed bed containing a particulate catalyst or sorbent material (10) subject to operation at high temperature having a shaped boundary member (16) inclined to the direction of fluid flow through the bed that maintains the depth of said catalyst or sorbent at the boundary of the bed through a series of thermal expansion-thermal contraction cycles is described. By maintaining bed depth, the shaped boundary member (16) can prevent bypass of, e.g. ammonia through a bed of particulate ammonia oxidation catalyst.
摘要翻译: 含有在高温下操作的颗粒状催化剂或吸附剂材料(10)的固定床具有成形的边界部件(16),所述成形边界部件(16)倾斜于流过所述床的流体流动方向,所述方法将所述催化剂或吸附剂的深度保持在 描述了通过一系列热膨胀 - 热收缩循环的床。 通过保持床深度,成形的边界构件(16)可以防止例如过滤器的旁路。 氨通过颗粒氨氧化催化剂床。
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公开(公告)号:US06204411B1
公开(公告)日:2001-03-20
申请号:US09137974
申请日:1998-08-21
IPC分类号: C07C20900
CPC分类号: C07C209/02
摘要: Process for the production of an aromatic amine by reacting an aromatic hydrocarbon with ammonia at a temperature of less than 500° C. and a pressure of less than 10 bara in the presence of a catalyst comprising at least one metal selected from the group consisting of the transition elements, lanthanides and actinides, preferably in the presence of an oxidant.
摘要翻译: 在包含至少一种选自以下的金属的催化剂存在下,在低于500℃的温度和小于10巴的温度下使芳族烃与氨反应生产芳族胺的方法。 过渡元素,镧系元素和锕系元素,优选在氧化剂的存在下。
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