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    HYDROGEN CYANIDE PROCESS AND APPARATUS THEREFOR
    5.
    发明申请
    HYDROGEN CYANIDE PROCESS AND APPARATUS THEREFOR 失效
    氢化氰化物工艺及其设备

    公开(公告)号：US20020039553A1

    公开(公告)日：2002-04-04

    申请号：US09029536

    申请日：1998-12-21

    发明人： CHRISTOPHER COWELL ,  RALPH DOY

    IPC分类号： C01C003/02 ,  B32B027/42

    CPC分类号： C01C3/0225 ,  B01J8/0285 ,  B01J19/002 ,  B01J19/2425 ,  B01J2219/00081 ,  B01J2219/00159 ,  C01C3/0212

    摘要： A catalytic process and apparatus therefor for the manufacture of hydrogen cyanide. In the process an oxygen rich oxidant stream and at least one oxidant-free feed stream containing methane and ammonia are separately preheated and rapidly mixed to form a detonable mixed stream at a temperature which is at least 50null C. below the autoignition temperature of the mixed stream. The mixed stream is then conveyed to a catalyst capable of catalysing the formation of hydrogen cyanide at such a velocity that detonation is avoided. The process is more energy efficient and gives rise to an effluent stream containing more hydrogen than the conventional Andrussow process.

    摘要翻译： 用于制造氰化氢的催化方法及其设备。 在此过程中，含氧气体氧化剂流和至少一种不含氧化剂的进料流分别被预热并快速混合，形成可爆炸的混合流，温度低于低于自燃温度 混合流。 然后将混合物流以能够催化形成氰化氢的催化剂以避免爆炸的速度被输送。 该方法更节能，并且产生比常规安德鲁斯方法含有更多氢的流出物流。

    Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions
    7.
    发明授权
    Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions 失效
    进行催化放热和吸热高压气体反应的方法

    公开(公告)号：US4423022A

    公开(公告)日：1983-12-27

    申请号：US487173

    申请日：1983-04-21

    申请人： John V. Albano ,  George Friedman

    发明人： John V. Albano ,  George Friedman

    IPC分类号： B01J8/00 ,  B01J8/04 ,  C01C1/04 ,  C01C3/02 ,  C07C29/151 ,  C07C29/152

    CPC分类号： B01J8/0415 ,  B01J8/0005 ,  C01C1/0417 ,  C01C3/0225 ,  C07C29/1516 ,  C07C29/152 ,  B01J2208/0007 ,  B01J2208/00088 ,  B01J2208/00132 ,  B01J2208/00168 ,  B01J2208/00194 ,  B01J2208/00256 ,  Y02P20/52

    摘要： Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions with a single-walled pressure vessel or shell containing cross-flow (e.g., radial flow) heat transfer exchangers, a continuous catalytic bed having at least two stages, and means for effecting "cross-over" material flows from "outside" to "inside" (for exothermic reactions) and vice versa (for endothermic reactions), whereby conditions of: maximum gas temperature always being in the core of said vessel or shell, minimal pressure drop, and minimal compression of catalyst particles are achieved, along with significant economic savings in cost of the pressure vessel or shell and catalyst (through extension of catalyst life).

    摘要翻译： 用单壁压力容器或含有交叉流动的壳体（例如，径流）传热交换器，具有至少两个阶段的连续催化床进行催化放热和吸热高压气体反应的方法以及用于实现 “交叉”材料从“外部”流向“内部”（用于放热反应），反之亦然（对于吸热反应），其条件是：最大气体温度始终位于所述容器或壳体的核心中，最小压降 ，并且实现了催化剂颗粒的最小压缩，同时显着节省了压力容器或壳和催化剂的成本（通过延长催化剂寿命）。