公开(公告)号：US20200368690A1

公开(公告)日：2020-11-26

申请号：US16638171

申请日：2018-08-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Michael A. Yandrasits ,  David Scott Seitz ,  Eric F. Funkenbusch ,  Ryan C. Shirk ,  Jinsheng Zhou ,  Eric J. Hanson ,  Moses M. David ,  Kazuhiko Mizuno

IPC: B01D61/36 ,  B01D71/32 ,  B01D69/12 ,  B01D71/46 ,  B01D67/00 ,  B01D69/02

Abstract: A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorinated backbone and recurring pendant groups according to the following formula (Formula I): —O—Rf—[—SO2—N−(Z+)—SO2—R—]m—[SO2]n-Q wherein: Rf is a perfluorinated organic linking group; R is an organic linking group; Z+ is H+, a monovalent cation, or a multivalent cation; Q is H, F, —NH, —O-2 Y+, or —CxF2x+1; Y+ is H+, a monovalent cation, or a multivalent cation; x=1 to 4; m=0 to 6; and n=0 or 1; with the proviso that at least one of m or n must be non-zero.

公开(公告)号：US20180154311A1

公开(公告)日：2018-06-07

申请号：US15737945

申请日：2016-07-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz ,  Moses M. David

IPC: B01D61/36 ,  B01D67/00 ,  B01D69/10 ,  B01D69/12 ,  B01D71/40 ,  B01D71/48 ,  B01D71/52 ,  B01D71/70

CPC classification number: B01D61/362 ,  B01D67/0006 ,  B01D67/0088 ,  B01D67/0093 ,  B01D69/10 ,  B01D69/12 ,  B01D69/125 ,  B01D71/40 ,  B01D71/48 ,  B01D71/52 ,  B01D71/70 ,  B01D2323/286 ,  B01D2323/30 ,  B01D2323/345 ,  B01D2323/40 ,  B01D2323/46 ,  F02D19/0671 ,  Y02T10/36

Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

公开(公告)号：US20160325229A1

公开(公告)日：2016-11-10

申请号：US15108892

申请日：2014-12-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz

IPC: B01D61/36 ,  B01D69/12 ,  B01D71/44 ,  B01D71/42 ,  B01D71/48 ,  B01D71/70 ,  B01D67/00 ,  B01D71/40

Abstract: A composite membrane for selectively pervaporating a first liquid from a mixture comprising the first liquid and a second liquid. The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The polymer is more permeable to the first liquid than the second liquid but not soluble in the first liquid or the second liquid. The composite membrane may be asymmetric or symmetric with respect to the amount of pore-filling polymer throughout the thickness of the porous substrate.

Abstract translation: 一种复合膜，用于从包含第一液体和第二液体的混合物中选择性地蒸发第一液体。 复合膜包括包括相对的第一和第二主表面以及多个孔的多孔基底。 孔隙填充聚合物设置在至少一些孔中，以形成在多孔基材内具有厚度的层。 聚合物比第二液体比第一液体更可渗透，但不溶于第一液体或第二液体。 复合膜相对于孔隙填充聚合物在多孔基材整个厚度上的量可以是不对称的或对称的。

公开(公告)号：US20200030748A1

公开(公告)日：2020-01-30

申请号：US16594502

申请日：2019-10-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz ,  Moses M. David

IPC: B01D61/36 ,  B01D69/12 ,  B01D67/00 ,  B01D69/10 ,  B01D71/40 ,  B01D71/48 ,  B01D71/52 ,  B01D71/70

Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

公开(公告)号：US10478778B2

公开(公告)日：2019-11-19

申请号：US15737945

申请日：2016-07-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz ,  Moses M. David

IPC: B01D61/36 ,  B01D67/00 ,  B01D69/10 ,  B01D69/12 ,  B01D71/40 ,  B01D71/48 ,  B01D71/52 ,  B01D71/70 ,  F02D19/06

Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.

公开(公告)号：US10766004B2

公开(公告)日：2020-09-08

申请号：US15108892

申请日：2014-12-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz

IPC: B01D61/36 ,  B01D71/52 ,  B01D69/10 ,  B01D69/12 ,  B01D67/00 ,  B01D71/42 ,  B01D71/44 ,  B01D71/40 ,  B01D71/48 ,  B01D71/70

Abstract: A composite membrane for selectively pervaporating a first liquid from a mixture comprising the first liquid and a second liquid. The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The polymer is more permeable to the first liquid than the second liquid but not soluble in the first liquid or the second liquid. The composite membrane may be asymmetric or symmetric with respect to the amount of pore-filling polymer throughout the thickness of the porous substrate.

公开(公告)号：US20200164319A1

公开(公告)日：2020-05-28

申请号：US16638167

申请日：2018-08-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jinsheng Zhou ,  Ryan C. Shirk ,  David Scott Seitz ,  Moses M. David

IPC: B01D69/12 ,  B01D69/10 ,  B01D61/36

Abstract: A composite membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., first liquid such as a high octane compound) from a mixture comprising the first fluid (e.g., first liquid such as a high octane compound) and a second fluid (e.g., second liquid such as gasoline). The composite membrane includes a porous substrate comprising opposite first and second major surfaces, and a plurality of pores. A pore-filling polymer is disposed in at least some of the pores so as to form a layer having a thickness within the porous substrate. The composite membrane further includes at least one of: (a) an ionic liquid mixed with the pore-filling polymer; or (b) an amorphous fluorochemical film disposed on the composite membrane.