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1.发明公开公开(公告)号：US20240204227A1
公开(公告)日：2024-06-20
申请号：US17909833
申请日：2021-03-05
IPC分类号： H01M8/1039 , C08F8/34 , C08F8/44 , C08F214/26 , C08G65/00 , C08G65/334 , H01M8/10 , H01M8/1027 , H01M8/103 , H01M8/1032
CPC分类号： H01M8/1039 , C08F8/34 , C08F8/44 , C08F214/262 , C08G65/007 , C08G65/3348 , H01M8/1027 , H01M8/103 , H01M8/1032 , C08G2650/48 , H01M2008/1095
摘要： A fluoropolymer is described comprising pendent groups having the formula: —(CF2)a—(OCbF2b)c—(OCeF2e)—SO2—[NX2—SO2(CF2)f—SO2]d—NX1—SO2—Rf wherein Rf is a perfluoroether and X1 and X2 are independently cationic counterions. Also described are various articles including catalyst ink, polymer electrolyte membranes, and membrane electrode assemblies comprising the fluoropolymer described herein; as well as a method of making a fluoropolymer.
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公开(公告)号：US11702486B2
公开(公告)日：2023-07-18
申请号：US16980312
申请日：2019-03-11
发明人： Carl A. Laskowski , Michael A. Yandrasits , Timothy M. Gillard , Zbyslaw R. Owczarczyk , Marina M. Kaplun
IPC分类号： C08F8/32 , C08F8/04 , C08F8/44 , C08F236/06 , C08F297/04 , C08K5/50 , C08L53/02 , H01M8/1004
CPC分类号： C08F8/32 , C08F8/04 , C08F8/44 , C08F236/06 , C08F297/04 , C08K5/50 , C08L53/025 , H01M8/1004
摘要： Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.
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公开(公告)号：US20230056130A1
公开(公告)日：2023-02-23
申请号：US17782193
申请日：2020-12-18
发明人： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Klaus Hintzer , Matthew J. Lindell , Sean M. Smith , Arne Thaler , Michael A. Yandrasits
IPC分类号： H01M8/1039 , H01M8/1004 , H01M4/90 , H01M4/88
摘要： The copolymer includes divalent units represented by formula —[CF2—CF2]—, at least one divalent unit represented by formula (I): and at least one divalent unit independently represented by formula (II): A is —N(RFa)2 or a is non-aromatic, 5- to 8-membered, perfluorinated ring comprising one or two nitrogen atoms in the ring and optionally comprising at least one oxygen atom in the ring, each RFa is independently linear or branched perfluoroalkyl having 1 to 8 carbon atoms and optionally interrupted by at least one catenated O or N atom, each Y is independently —H or —F, with the proviso that one Y may be —CF3, h is 0, 1, or 2, each i is independently 2 to 8, and j is 0, 1, or 2. A catalyst ink and polymer electrolyte membrane including the copolymer are also provided.
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公开(公告)号：US20210032378A1
公开(公告)日：2021-02-04
申请号：US16980320
申请日：2019-03-11
IPC分类号： C08F8/32 , C08F8/44 , C08F214/18 , C08F214/16 , C08F212/12 , C08F210/08 , C08J5/22 , H01M8/1004
摘要： Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.
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5.发明申请公开(公告)号：US20130216932A1
公开(公告)日：2013-08-22
申请号：US13848093
申请日：2013-03-21
IPC分类号： H01M8/10
CPC分类号： H01M8/1002 , H01M8/0267 , H01M8/0271 , H01M8/0284 , H01M8/0286 , H01M8/1007 , H01M8/2404 , H01M8/242 , H01M2008/1095 , Y02E60/50 , Y02E60/523 , Y02P70/56
摘要： A first transport system moves a web comprising a subgasketed CCM layer and an application system applies a crosslinkable resin to at least a subgasketed portion of the subgasketed CCM layer. The crosslinkable resin preferably comprises a photocurable cationic crosslinkable resin. A first curing apparatus subjects an exposed surface of the crosslinkable resin to a photo curing process to initiate curing of the crosslinkable resin. A second transport system moves a GDL into adhering contact with a partially cured exposed surface of the crosslinkable resin of the CCM layer so as to form an MEA layer. A second curing apparatus subjects the GDL, partially cured crosslinkable resin, and CCM layer structure to a thermal curing process to substantially complete curing of the crosslinkable resin. A converting system is configured to receive the MEA layer and produce a plurality of discrete MEAs from the MEA layer.
摘要翻译： 第一传送系统移动包括底层CCM层的网，并且应用系统将可交联树脂施加到所述被封闭的CCM层的至少一个下垫部分。 可交联树脂优选包含可光固化的阳离子可交联树脂。 第一固化装置将可交联树脂的暴露表面照射到光固化过程以引发可交联树脂的固化。 第二传输系统使GDL与CCM层的可交联树脂的部分固化的暴露表面粘合接触以形成MEA层。 第二固化装置使GDL部分固化的可交联树脂和CCM层结构经受热固化过程，以基本上完成可交联树脂的固化。 转换系统被配置为接收MEA层并且从MEA层产生多个离散MEA。
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公开(公告)号：US20210384523A1
公开(公告)日：2021-12-09
申请号：US17288021
申请日：2019-10-25
发明人： Andrew T. Haug , John E. Abulu , Matthew J. Lindell , Tyler S. Matthews , Andrew J.L. Steinbach , Fuxia Sun , Michael A. Yandrasits
IPC分类号： H01M4/92 , H01M4/86 , H01M4/88 , C09D127/18 , C09D141/00
摘要： Described herein is a coating composition comprising: (a) a metal catalyst, wherein the metal catalyst comprises at least one of platinum, ruthenium, iridium, and alloys and combinations thereof; (b) an at least highly fluorinated ionomer comprising a polymer backbone and a plurality of first side chains pendant therefrom, wherein the first side chain comprises at least one protogenic group, wherein the protogenic group is selected from a sulfonic acid, a bis(sulfonyl)imide, a sulfonamide, a sulfonyl methide, and salts and combinations thereof, and wherein the polymer backbone comprises an average of at least 14 carbon atoms between adjacent first side chains along the polymer backbone; and (c) a solvent. Such coating compositions may be used to make electrodes for electrochemical cells and have been shown to have reduced poisoning of the catalyst.
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公开(公告)号：US10934374B2
公开(公告)日：2021-03-02
申请号：US16977294
申请日：2019-03-11
IPC分类号： C08F210/02 , C08F220/06 , C08J5/22 , B01J39/07 , B01J39/20 , B01J47/12 , H01M8/10 , H01M8/1072 , H01M8/1051 , H01M8/103 , H01M8/1018
摘要： Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.
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公开(公告)号：US20180229186A1
公开(公告)日：2018-08-16
申请号：US15737955
申请日：2016-07-01
发明人： Michael A. Yandrasits , David S. Seitz , Eric F. Funkenbusch , Ryan C. Shirk , Jinsheng Zhou , Eric J. Hanson , Moses M. David , Kazuhiko Mizuno
CPC分类号： B01D61/362 , B01D63/10 , B01D67/0088 , B01D67/0093 , B01D69/10 , B01D69/12 , B01D71/32 , B01D71/46 , B01D2323/30 , B01D2323/345 , B01D2323/46 , B01D2325/42 , F02D19/0671 , F02M37/22 , Y02T10/36
摘要： A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorinated backbone and recurring pendant groups according to the following formula (Formula I): —O—Rf—[—SO2—N−(Z′)—SO2—R—]m—[SO2]n-Q wherein: Rf is a perfluorinated organic linking group; R is an organic linking group; Z+ is H+, a monovalent cation, or a multivalent cation; Q is H, F, —NH2, —NH2, —O−Y+, or —CxF2x+1; Y+ is H+, a monovalent cation, or a multivalent cation; x=1 to 4; m=0 to 6; and n=0 or 1; with the proviso that at least one of morn must be non-zero
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公开(公告)号：US20180006315A1
公开(公告)日：2018-01-04
申请号：US15536401
申请日：2015-12-15
IPC分类号： H01M8/0297 , H01M8/18 , C25B1/10 , C25B11/03 , C25B9/10 , C25B15/08 , H01M8/1004 , H01M8/1018
CPC分类号： H01M8/0297 , C25B1/08 , C25B1/10 , C25B9/08 , C25B9/10 , C25B11/035 , C25B15/08 , H01M8/0234 , H01M8/0245 , H01M8/1004 , H01M8/188 , H01M12/08 , H01M2008/1095 , Y02E60/128 , Y02E60/366
摘要： An article comprising a first gas distribution layer (100), a first gas dispersion layer (200), or a first electrode layer, having first and second opposed major surfaces and a first adhesive layer having first and second opposed major surfaces, wherein the second major surface (102) of the first gas distribution layer (100), the second major surface (202) of the first gas dispersion layer (200), or the first major surface of the first electrode layer, as applicable, has a central area, wherein the first major surface of the first adhesive layer contacts at least the central area of the second major surface of the first gas distribution layer, the second major surface of the first gas dispersion layer, or the first major surface of the first electrode layer, as applicable, and wherein the first adhesive layer comprises a porous network of first adhesive including a continuous pore network extending between the first and second major surfaces of the first adhesive layer. The articles described herein are useful, for example, in membrane electrode assemblies, unitized electrode assemblies, and electrochemical devices (e.g., fuel cells, redox flow batteries, and electrolyzers).
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公开(公告)号：US20160141642A1
公开(公告)日：2016-05-19
申请号：US15005571
申请日：2016-01-25
发明人： Eric J. Iverson , Daniel M. Pierpont , Michael A. Yandrasits , Steven J. Hamrock , Stephan J. Obradovich , Donald G. Peterson
IPC分类号： H01M8/0286 , H01M8/242 , H01M8/0273
CPC分类号： H01M8/2418 , H01M8/0273 , H01M8/0276 , H01M8/0286 , H01M8/1004 , H01M8/1016 , H01M8/242 , H01M2008/1095 , Y02P70/56
摘要： An automated roll to roll method of making a fuel cell roll good subassembly is described wherein an elongated first subgasket web having a plurality of apertures is moved relative to a plurality of individual electrolyte membranes, each individual electrolyte membrane having a center region. The individual electrolyte membranes are aligned with the first subgasket web so that a center region of each electrolyte membrane is aligned with an aperture of the first subgasket web and the individual electrolyte membranes are attached to the first subgasket web.
摘要翻译： 描述了制造燃料电池辊良好组件的自动化滚动滚动方法，其中具有多个孔的细长的第一子网腹板相对于多个单独的电解质膜移动，每个单独的电解质膜具有中心区域。 单个电解质膜与第一子网网对齐，使得每个电解质膜的中心区域与第一子网幅材的孔对准，并且单个电解质膜附接到第一子网幅材。
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