公开(公告)号：US20180066090A1

公开(公告)日：2018-03-08

申请号：US15550321

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Per M. Nelson ,  Jens C. Schrooten ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08F214/28 ,  C08F2/28 ,  C08K3/08 ,  C08J5/12

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, n is from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has up to 50 unstable end groups per 106 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US20180282493A1

公开(公告)日：2018-10-04

申请号：US15766254

申请日：2016-10-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Dae-Soon Park ,  Sung Wook Lim ,  Stephen E. Amos ,  Per M. Nelson

IPC: C08J3/22 ,  C08L9/00 ,  B29D35/12 ,  A43B13/04

Abstract: A masterbatch composition including glass bubbles and a toughening agent in a blend of syndiotactic 1,2-poly-butadiene and cis-1,4-polybutadiene is disclosed. The glass bubbles are present in an amount of at least 25 percent by weight, based on the total weight of the masterbatch composition. A method of making a rubber composition from the masterbatch composition is disclosed as well as a rubber composition and vulcanized rubber made from the masterbatch composition. A rubber composition that includes syndiotactic 1,2-polybutadiene, cis-1,4-polybutadiene, a toughening agent that includes at least one of a fluoroplastic or an organic or ceramic fiber, and glass bubbles in an amount up to 25 percent by weight, based on the total weight of the rubber composition, is also disclosed.

公开(公告)号：US20180030184A1

公开(公告)日：2018-02-01

申请号：US15550324

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Per M. Nelson ,  Jens C. Schrooten ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/28 ,  C08F8/22 ,  C08F214/26 ,  H01B3/44

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, z is 1 or 2, each n is independently from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has a combined number of unstable end groups and —CF2H end groups in a range from 25 per 106 carbon atoms up to 120 per 106 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US10766990B2

公开(公告)日：2020-09-08

申请号：US15550321

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Per M. Nelson ,  Jens C. Schrooten ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/26 ,  C08J5/12 ,  H01B3/44 ,  C08F214/28 ,  C08F2/28 ,  C08K3/08

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, n is from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has up to 50 unstable end groups per 106 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.

公开(公告)号：US20210108063A1

公开(公告)日：2021-04-15

申请号：US16464325

申请日：2017-11-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Michael C. Dadalas ,  Klaus Hintzer ,  Per M. Nelson

IPC: C08L27/18 ,  C08L23/08 ,  C08L27/20 ,  C08L27/16 ,  C08K5/06 ,  C08K5/09 ,  C08K5/42 ,  D06M15/256 ,  D06M15/227

Abstract: Described herein is an aqueous polymer dispersion comprising: (a) an ethylene-tetrafluoroethylene copolymer (b) 1-25 wt % of a non-ionic, branched, alkoxy alcohol surfactant versus the ethylene-tetrafluoroethylene copolymer, and (c) 0.05-5 wt % non-fluorinated anionic surfactant versus the ethylene-tetrafluoroethylene copolymer. Such aqueous polymer dispersion may be used to coat a fiber-containing substrate.

公开(公告)号：US10730980B2

公开(公告)日：2020-08-04

申请号：US15550324

申请日：2016-02-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Denis Duchesne ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Per M. Nelson ,  Jens C. Schrooten ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/28 ,  C08F8/22 ,  C08F214/26 ,  H01B3/44

Abstract: A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more —O— groups, z is 1 or 2, each n is independently from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has a combined number of unstable end groups and —CF2H end groups in a range from 25 per 106 carbon atoms up to 120 per 106 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed.