-
公开(公告)号:US20230235103A1
公开(公告)日:2023-07-27
申请号:US18013369
申请日:2021-06-29
Applicant: ADEKA CORPORATION
Inventor: Tomofumi YOKOMIZO , Hirokatsu SHINANO , Hiromi TAKENOUCHI , Kensaku AKIMOTO , Yohei AOYAMA
IPC: C08F20/44 , C08F8/34 , H01M4/60 , H01M10/0525 , H01M4/04
CPC classification number: C08F20/44 , C08F8/34 , H01M4/604 , H01M10/0525 , H01M4/04 , H01M2004/027
Abstract: The present invention provides a sulfur-modified polyacrylonitrile having a total content of sulfur of from 30 mass % to 55 mass % and having a content of free sulfur of from 0.05 ppm by mass to 4 mass % determined by a solvent extraction method, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.
-
公开(公告)号:US20180226683A1
公开(公告)日:2018-08-09
申请号:US15749513
申请日:2016-09-14
Applicant: ADEKA CORPORATION
Inventor: Yuta NOHARA , Kenji KAKIAGE , Tomofumi YOKOMIZO , Hiroaki WATANABE , Yohei AOYAMA , Toru YANO
IPC: H01M10/0567 , H01M10/0525 , H01M10/42 , H01M4/505 , H01M4/525 , C07F7/18
Abstract: Disclosed is a nonaqueous secondary battery having a nonaqueous electrolyte containing a lithium salt dissolved in an organic solvent, in which the positive electrode active material is preferably a manganese-containing, lithium transition metal oxide salt. The nonaqueous electrolyte contains at least one compound of general formula (1), preferably at least one compound of general formula (1′). The content of the compound of formula (1) or (1′) in the nonaqueous electrolyte is preferably 0.001 to 10 mass %. The symbols in formulae (1) and (1′) are as defined in the description.
-
公开(公告)号:US20200350587A1
公开(公告)日:2020-11-05
申请号:US16960782
申请日:2019-02-25
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Tomofumi YOKOMIZO , Hirokatsu SHINANO , Kenji KAKIAGE , Yuta NOHARA , Yohei AOYAMA
Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.
-
公开(公告)号:US20180026304A1
公开(公告)日:2018-01-25
申请号:US15549441
申请日:2016-03-02
Applicant: ADEKA CORPORATION
Inventor: Tomofumi YOKOMIZO , Yuta NOHARA
IPC: H01M10/0567 , H01M10/0525
CPC classification number: H01M10/0567 , H01M10/0525 , H01M2300/0025 , Y02T10/7011
Abstract: A nonaqueous electrolyte having a lithium salt dissolved in an organic solvent and a nonaqueous secondary battery using the same are disclosed. The nonaqueous electrolyte is characterized by containing (A) at least one compound represented by general formula (1) (wherein symbols are as defined in the description) and (B) at least one compound having two or more groups selected from a vinyl group, an allyl group, and a propargyl group per molecule. Component (B) is preferably a compound having an ethylenically and acetylenically unsaturated bond equivalent of 150 or smaller.
-
公开(公告)号:US20230261193A1
公开(公告)日:2023-08-17
申请号:US18013378
申请日:2021-06-29
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Tomofumi YOKOMIZO
IPC: H01M4/60 , C08F220/44 , C08F8/36
CPC classification number: H01M4/604 , C08F220/44 , C08F8/36 , H01M2004/028
Abstract: The present invention provides a sulfur-modified polyacrylonitrile, which has a total content of sulfur of from 30 mass % to 55 mass %, and has a value for the calculation formula (1) defined in Description of less than 0.08, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.
-
公开(公告)号:US20220340693A1
公开(公告)日:2022-10-27
申请号:US17763839
申请日:2020-09-14
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Kensaku AKIMOTO , Kenji KAKIAGE , Hirokatsu SHINANO , Tomofumi YOKOMIZO
Abstract: The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).
-
7.
公开(公告)号:US20160336621A1
公开(公告)日:2016-11-17
申请号:US15109902
申请日:2015-03-06
Applicant: ADEKA CORPORATION
Inventor: Tomofumi YOKOMIZO , Toru YANO , Hiroaki WATANABE , Yohei AOYAMA , Tomomi SERI , Yuta NOHARA
IPC: H01M10/0567 , H01M10/0525
CPC classification number: H01M10/0567 , H01M10/0525 , H01M2300/0025
Abstract: Provided are a nonaqueous electrolyte excellent in the prevention of overcharge and capable of retaining a small internal resistance and a high electrical capacity even after charge/discharge cycles and a nonaqueous secondary battery using the same. Specifically, the nonaqueous electrolyte is a lithium salt solution in an organic solvent and contains at least one compound having general formula (1), and the nonaqueous secondary battery includes a negative electrode capable of intercalating and deintercalating lithium, a positive electrode containing a transition metal and lithium, and the nonaqueous electrolyte. The details of formula (1) are also provided.
Abstract translation: 本发明提供一种防止过充电且即使在充放电循环后也能够保持小的内电阻和高电容的非水电解质和使用其的非水二次电池。 具体而言,非水电解液是有机溶剂中的锂盐溶液,含有至少一种具有通式(1)的化合物,非水系二次电池具有可插入和脱嵌锂的负极,含有过渡金属的正极 和锂,以及非水电解质。 还提供了公式(1)的细节。
-
-
-
-
-
-