Thermostable, substantially aromatic high molecular weight compounds and their production from homopolymers and copolymers of unsaturated ketones
    1.
    发明授权
    Thermostable, substantially aromatic high molecular weight compounds and their production from homopolymers and copolymers of unsaturated ketones 失效
    热稳定的,基本上芳族的高分子量化合物及其由不饱和酮的均聚物和共聚物的生产

    公开(公告)号:US3280075A

    公开(公告)日:1966-10-18

    申请号:US40417164

    申请日:1964-10-15

    Applicant: BASF AG

    Abstract: Polymers of vinyl methyl ketone or isopropenyl ketone or the cyclization products of such polymers are heated to a temperature of from 30 DEG C. to 800 DEG C. in the presence of a metal halide of a metal of Groups IIIA, IVB, VB, VIB, or VIIB of the Periodic Table (defined) or of iron or zinc in the presence of a dehydrogenating agent, to produce aromatized high-molecular weight compounds. Copolymers of the above ketones containing at least 50% by weight of ketone may also be used. The cyclization products are formed by intramolecular condensation by the action of acid or alkali. The treatment of copolymers with styrene, vinyl chloride, butadiene, isoprene, acrylonitrile, and methacrylonitrile are exemplified.

    Abstract translation: 乙烯基甲基酮或异丙烯基酮的聚合物或这些聚合物的环化产物在IIIA,IVB,VB,VIB族金属的金属卤化物存在下加热到30℃至800℃的温度 ,或VIIB,或在脱氢剂存在下使用铁或锌,以产生芳构化的高分子量化合物。 也可以使用含有至少50重量%酮的上述酮的共聚物。 环化产物通过酸或碱的作用通过分子内缩合而形成。 与苯乙烯,氯乙烯,丁二烯,异戊二烯,丙烯腈和甲基丙烯腈的共聚物的处理被列举。

    Self-extinguishing plastics compositions
    9.
    发明授权
    Self-extinguishing plastics compositions 失效
    自熄性塑料组合物

    公开(公告)号:US3326832A

    公开(公告)日:1967-06-20

    申请号:US33911364

    申请日:1964-01-21

    Applicant: BASF AG

    Abstract: A self-extinguishing composition comprises (a) a styrene polymer, (b) an organic chlorine or bromine compound used in such amount that the chlorine content of the composition is 3-10% or the bromine content is 1-5%, and (c) 0.05-5% of a metal chelate compound of a metal of Groups Ib, IIb, IVb, Va, VIb, VIIb or VIII of the Periodic Table. The polymer may be polystyrene or a styrene copolymer containing at least 50 mol. per cent styrene and acrylonitrile, an ester of acrylic or methacrylic acid with a C1- 8 alcohol, vinyl carbazole, butadiene or 0.01-0.5% divinylbenzene. The chelate compound may be an acetylacetonate of copper, zinc, mercury, titanium, chromium, molybdenum, manganese, iron or cobalt, ethyl acetoacetate and copper, nickel salicylaldehyde, chromium anthranilate, or may be one of the said metals and a b-diketone, a b-ketocarboxylic ester, a hydroxyaldehyde or an aminocarboxylic acid. The organic chlorine compound may be a chlorinated diphenyl. The composition may also contain 2-20% of an expanding agent, e.g. a gaseous or liquid hydrocarbon or chlorofluorohydrocarbon. In an example, styrene is bead polymerized in water with polyvinylpyrrolidone, a chlorinated paraffin, pentane and a chelate compound, to produce a foam; styrene is polymerized in petroleum ether with hexabromocyclododecane and the chelate compound; films are prepared from a solution of the composition in methylene chloride and are then expanded.

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