公开(公告)号：US3412102A

公开(公告)日：1968-11-19

申请号：US55952166

申请日：1966-06-22

Applicant: BASF AG

Inventor： GERHARD SCHULZ ,  RUDOLF POLSTER

IPC: C09B47/067

CPC classification number: C09B47/067

公开(公告)号：US3370065A

公开(公告)日：1968-02-20

申请号：US58090966

申请日：1966-09-21

Applicant: BASF AG

Inventor： EBERHARD NOLD ,  RUDOLF POLSTER

IPC: C09B67/16

CPC classification number: C09B67/0019

公开(公告)号：US3098088A

公开(公告)日：1963-07-16

申请号：US14251761

申请日：1961-10-03

Applicant: BASF AG

Inventor： RUDOLF POLSTER

IPC: C07F7/22

CPC classification number: C07F7/2208 ,  C07F7/2212

Abstract: A 3, 3-dialkylpentylene-1, 5 aluminium compound, prepared by reacting a diolefine of formula: in which R1 is a C1-4 alkyl radical, with an organo aluminium compound of formula: in which y is c2-4 alkyl and y1 is c2-4 alkyl or hydrogen, is reacted with tin tetrabromide or tin tetrachloride to give a compound of formula: Specification 933,364 is referred to.

公开(公告)号：US3353977A

公开(公告)日：1967-11-21

申请号：US47057365

申请日：1965-07-08

Applicant: BASF AG

Inventor： JOACHIM KRANZ ,  RUDOLF POLSTER

IPC: C09B67/12

CPC classification number: C09B67/0016

公开(公告)号：US3190901A

公开(公告)日：1965-06-22

申请号：US19845062

申请日：1962-05-29

Applicant: BASF AG

Inventor： RUDOLF POLSTER

IPC: C07F7/22 ,  C08G18/24 ,  C08G71/00 ,  C08G79/12 ,  C08K5/57 ,  C08L27/06 ,  C08L85/00

CPC classification number: C08G71/00 ,  C07F7/2216 ,  C08G18/242 ,  C08G79/12 ,  C08K5/57 ,  C08L27/06 ,  C08L85/00 ,  C08L2666/14

Abstract: Linear polymers the chains of which contain two to sixty units of the formula: in which R1 and R2 are H, methyl or ethyl are prepared by reacting at 20-250 DEG C., 1 mol. of tin tetrachloride with a compound of the formula: Reaction may be performed in a liquid hydrocarbon to facilitate removal of heat. The cyclic monomeric starting materials may be produced according to Specification 933,365. Suitable ones are 3,3,9,9-tetramethyl-6-stanna-spiro-[5,5]-undecan and 3,9-dimethyl-3,9-diethyl-6-stanna-spiro-[5,5]-undecane.ALSO:Linear polymers the chains of which contain two to sixty units of the formula: in which R1 and R2 are H, methyl or ethyl are prepared by reacting, at 20 DEG to 250 DEG C., 1 mol of tin tetrachloride with 1 to 2 mols of a 6-stanna spiro-[5,5]-undecane of the formula: Reaction may be performed in a liquid hydrocarbon to facilitate removal of heat. Examples describe the production of polymers from 3, 3, 9, 9-tetramethyl -6- stanna-spiro-[5,5]-undecane. 3,9-dimethyl-3,9-diethyl -6- stanna-spiro- [5,5]-undecane is also mentioned as a suitable starting material. The cyclic monomeric tin compound can be made as described in Specification 933,365.