PROCESS FOR INHIBITING THE UNDESIRED FREE-RADICAL POLYMERIZATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P

    公开(公告)号:US20230132285A1

    公开(公告)日:2023-04-27

    申请号:US17913447

    申请日:2021-03-18

    Applicant: BASF SE

    Abstract: Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with protoanemonine in an amount that results in a protoanemonine content in the range from 0.5 to 100 ppmw based on the weight of the acrylic acid present in P, and a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 0.5 to 100 ppmw of protoanemonine, in each case based on the weight of the acrylic acid present in P.

    METHOD FOR INHIBITING UNWANTED RADICAL POLYMERISATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P

    公开(公告)号:US20210309598A1

    公开(公告)日:2021-10-07

    申请号:US17263415

    申请日:2019-07-16

    Applicant: BASF SE

    Abstract: Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.

    METHOD FOR OBTAINING PURE CYCLOHEXYL(METH)ACRYLATE BY DISTILLATION

    公开(公告)号:US20210292270A1

    公开(公告)日:2021-09-23

    申请号:US16468823

    申请日:2017-12-13

    Applicant: BASF SE

    Abstract: Process for isolating pure cyclohexyl (meth)acrylate from a mixture comprising cyclohexyl (meth)acrylate, cyclohexanol and entrainer, by feeding or introducing the mixture is fed as side feed stream into a rectification column having a bottom vaporizer, separation-active internals and a stripping section and an enrichment section, where the column has from 4 to 50 theoretical plates, the side feed stream is introduced in the region commencing at least one theoretical plate above the bottommost theoretical plate and ending at least one theoretical plate below the uppermost theoretical plate, the pressure at the top of the column is in the range from 10 mbar to 5 bar and the reflux ratio is from 1:0.2 to 1:10, and the bottom output is fed to a further distillation unit in which the cyclohexyl (meth)acrylate is separated off at the top or at a side offtake.

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