公开(公告)号：US20160289392A1

公开(公告)日：2016-10-06

申请号：US15065291

申请日：2016-03-09

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Robert H. GRUBBS ,  Christopher M. BATES ,  Alice CHANG ,  Brendon MCNICHOLAS ,  Simon C. JONES

IPC: C08G81/00

CPC classification number: H01M10/0565 ,  C08G61/02 ,  C08G61/08 ,  C08G81/00 ,  C08G2261/126 ,  C08G2261/1426 ,  C08G2261/143 ,  C08G2261/148 ,  C08G2261/149 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/516 ,  C08G2261/792 ,  C08L65/00 ,  C08L87/005 ,  H01M10/0525 ,  H01M14/005 ,  H01M2008/1095 ,  H01M2300/0082

Abstract: Provided herein is a class of copolymers, including triblock brush copolymers having specific block configurations, for example, ABC triblock brush copolymers and ABA triblock brush copolymers. In an embodiment, for example, copolymers of the invention incorporate various polymer side chain groups which contribute beneficial physical, chemical, or electronic properties such as increased mechanical or elastic strength, improved ionic or electric conductivity. In some embodiments, the provided copolymers exhibit advantageous steric properties allowing for rapid self-assembly into a variety of morphologies that are substantially different than non-brush, block copolymers.

Abstract translation: 本文提供了一类共聚物，包括具有特定嵌段构型的三嵌段共聚物，例如ABC三嵌段共聚物和ABA三嵌段共聚物。 在一个实施方案中，例如，本发明的共聚物包含各种有助于物理，化学或电子性质的聚合物侧链基团，例如增加的机械或弹性强度，改进的离子或导电性。 在一些实施方案中，所提供的共聚物表现出有利的空间特性，允许快速自组装成与非刷嵌段共聚物基本上不同的各种形态。

公开(公告)号：US20170018801A1

公开(公告)日：2017-01-19

申请号：US15065317

申请日：2016-03-09

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Robert H. GRUBBS ,  Christopher M. BATES ,  Alice CHANG ,  Brendon MCNICHOLAS ,  Simon C. JONES

IPC: H01M10/0565 ,  H01M14/00 ,  H01M10/0525 ,  C08G61/02

CPC classification number: H01M10/0565 ,  C08G61/02 ,  C08G61/08 ,  C08G81/00 ,  C08G2261/126 ,  C08G2261/1426 ,  C08G2261/143 ,  C08G2261/148 ,  C08G2261/149 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/516 ,  C08G2261/792 ,  C08L65/00 ,  C08L87/005 ,  H01M10/0525 ,  H01M14/005 ,  H01M2008/1095 ,  H01M2300/0082

Abstract: Provided herein are copolymer electrolytes and electrocatalyst platforms, including brush block copolymers, triblock brush copolymers and pentablock brush copolymers. The copolymers described have beneficial chemical, physical and electrical properties including high ionic conductivity and mechanical strength. In embodiments, for example, the provided copolymer electrolytes and electrocatalyst platforms are doped with lithium salts or mixed with ionic liquids to form ion gels. In some embodiments, the copolymers provided herein self-assemble into physically cross-linked polymer networks with additional useful properties. The provided copolymers have low dispersity in the polymer side chains and do not require post-polymerization modifications.

Abstract translation: 本文提供了共聚物电解质和电催化剂平台，包括刷嵌段共聚物，三嵌段刷共聚物和五嵌段刷共聚物。 所述的共聚物具有有益的化学，物理和电学性能，包括高离子导电性和机械强度。 在实施方案中，例如，所提供的共聚物电解质和电催化剂平台掺杂有锂盐或与离子液体混合以形成离子凝胶。 在一些实施方案中，本文提供的共聚物自组装成具有额外有用性质的物理交联的聚合物网络。 所提供的共聚物在聚合物侧链中具有低分散性，并且不需要后聚合修饰。