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公开(公告)号：US20050176874A1
公开(公告)日：2005-08-11
申请号：US10515442
申请日：2002-05-31
申请人： Carme Panades , Jordi Albalat Perez
发明人： Carme Panades , Jordi Albalat Perez
IPC分类号： B05D3/02 , C08F265/04 , C08F283/00 , C08F290/06 , C08K3/00 , C08L33/04 , C08L57/00 , C09D4/06 , C09D133/04 , C09D157/00
CPC分类号： C08F290/06 , C08F283/00
摘要： The invention concerns an aqueous polymer dispersion composition comprising for 100 parts by weight of (A)+(B):(A) from 30 to 99 parts by weight of at least one dispersed polymer containing acetoacetoxy-type functional moieties, the said polymer having a glass transition temperature from 0 to 100° C.; and (B) from 1 to 70 parts by weight of a multifunctional acrylate, said aqueous composition further containing a volatile base in an amount sufficient to convert the acetoacetoxy functionalities of (A) to enamine ones. The invention does also concern a process of preparation, a coating composition comprising the said composition as a binder, its uses in industrial coatings and a dual cure process of coating.
摘要翻译： 本发明涉及一种含水聚合物分散体组合物，其包含100重量份的（A）+（B）：（A）：30至99重量份的至少一种含有乙酰乙酰氧基型功能部分的分散聚合物，所述聚合物具有 玻璃化转变温度为0至100℃; 和（B）1至70重量份的多官能丙烯酸酯，所述水性组合物还含有足以将（A）的乙酰乙酰氧基官能团转化成烯胺的挥发性碱。 本发明还涉及一种制备方法，一种包含所述组合物作为粘合剂的涂料组合物，其在工业涂料中的用途和涂覆的双重固化方法。
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公开(公告)号：US07985789B2
公开(公告)日：2011-07-26
申请号：US12280861
申请日：2007-02-22
CPC分类号： C08F2/22 , C08F2/44 , C08F220/06 , C08F220/18
摘要： The invention concerns an aqueous specific silica-based nanocomposite polymer dispersion, a method for preparing same, a coating composition, in particular protective, containing said dispersion, for applications requiring high anti-corrosive, anti-abrasive and chemical resistance performances. It concerns an aqueous nanocomposite polymer dispersion obtainable by an emulsion polymerization process of at least one monomer composition in the presence of at least one aqueous silica nanoparticle dispersion, said monomer composition being added at least in one step into the reactor already containing the aqueous silica nanoparticle dispersion, said aqueous silica nanoparticle dispersion having an anionic character and being stable in a pH range between 2 to 10, and said emulsion polymerization being performed in the presence of at least one organic initiator free of any ionic group and in the absence of any monomer or cationic dispersant.
摘要翻译： 本发明涉及一种水性特异性二氧化硅基纳米复合材料聚合物分散体，其制备方法，包含所述分散体的涂料组合物，特别是保护性的，用于需要高抗腐蚀性，耐磨性和耐化学性能的应用。 它涉及通过至少一种单体组合物的乳液聚合方法在至少一种含水二氧化硅纳米颗粒分散体存在下可获得的水性纳米复合聚合物分散体，所述单体组合物至少在一个步骤中加入已经含有二氧化硅水溶液纳米颗粒的反应器 分散体，所述含水二氧化硅纳米颗粒分散体具有阴离子特征并且在2-10的pH范围内是稳定的，并且所述乳液聚合在至少一种不含任何离子基团的有机引发剂存在下和在不存在任何单体的情况下进行 或阳离子分散剂。
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3.发明授权High-washability aqueous polymer dispersion, preparation and use thereof as binder in coating compositions 失效高可洗性水性聚合物分散体，其作为涂料组合物中的粘合剂的制备和用途公开(公告)号：US07214737B2
公开(公告)日：2007-05-08
申请号：US10488817
申请日：2002-09-06
IPC分类号： C08F2/16
CPC分类号： C08F220/12
摘要： The invention concerns an aqueous polymer dispersion, prepared from a monomer composition comprising: (A) 50 to 99.99 parts by weight of at least an acrylic or methacrylic ester derived from acrylic or methacrylic acid and an alcohol having 1 to 12 carbon atoms; (B) 0 to 40 parts by weight of at least a vinylaromatic monomer; (C) 0 to 5 parts by weight of at least a short-chain α,β-unsaturated mono- or polycarboxylic acid; (D) 0.01 to 5 parts by weight of at least an ethylenically unsaturated alpha-beta monomer compound (D), comprising at least a carbonyl group having at least a hydrogen atom borne in position alpha of said carbonyl (diacetone acrylamide), for 100 parts by weight of monomers (A)+(B)+(C)+(D), 80 to 98 wt. % of monomer components having been added to a reaction medium already containing a totally or partly polymerized pre-emulsion representing 2 to 20 wt. % of the final global proportion of monomer components in the dispersion finally obtained.
摘要翻译： 本发明涉及由单体组合物制备的含水聚合物分散体，其包含：（A）50至99.99重量份的至少一种衍生自丙烯酸或甲基丙烯酸的丙烯酸或甲基丙烯酸酯和具有1至12个碳原子的醇; （B）0〜40重量份的至少一种乙烯基芳族单体; （C）0至5重量份的至少一种短链α，β-不饱和单羧酸或多元羧酸; （D）0.01至5重量份的至少一种烯属不饱和的α-β单体化合物（D），至少包含至少一个在所述羰基（双丙酮丙烯酰胺）的α位置具有至少一个氢原子的羰基，用于100 单体重量份（A）+（B）+（C）+（D），80-98％ 已经添加到已经含有表示2至20重量％的全部或部分聚合的预乳液的反应介质中的单体组分的％ 最终得到最终全部比例的单体成分在分散体中的百分比。
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公开(公告)号：US20090318598A1
公开(公告)日：2009-12-24
申请号：US12280861
申请日：2007-02-22
CPC分类号： C08F2/22 , C08F2/44 , C08F220/06 , C08F220/18
摘要： The invention concerns an aqueous specific silica-based nanocomposite polymer dispersion, a method for preparing same, a coating composition, in particular protective, containing said dispersion, for applications requiring high anti-corrosive, anti-abrasive and chemical resistance performances. It concerns an aqueous nanocomposite polymer dispersion obtainable by an emulsion polymerization process of at least one monomer composition in the presence of at least one aqueous silica nanoparticle dispersion, said monomer composition being added at least in one step into the reactor already containing the aqueous silica nanoparticle dispersion, said aqueous silica nanoparticle dispersion having an anionic character and being stable in a pH range between 2 to 10, and said emulsion polymerization being performed in the presence of at least one organic initiator free of any ionic group and in the absence of any monomer or cationic dispersant.
摘要翻译： 本发明涉及一种水性特异性二氧化硅基纳米复合材料聚合物分散体，其制备方法，包含所述分散体的涂料组合物，特别是保护性的，用于需要高抗腐蚀性，耐磨性和耐化学性能的应用。 它涉及通过至少一种单体组合物的乳液聚合方法在至少一种含水二氧化硅纳米颗粒分散体存在下可获得的水性纳米复合聚合物分散体，所述单体组合物至少在一个步骤中加入已经含有二氧化硅水溶液纳米颗粒的反应器 分散体，所述含水二氧化硅纳米颗粒分散体具有阴离子特征并且在2-10的pH范围内是稳定的，并且所述乳液聚合在至少一种不含任何离子基团的有机引发剂存在下和在不存在任何单体的情况下进行 或阳离子分散剂。
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