公开(公告)号：US20230183570A1

公开(公告)日：2023-06-15

申请号：US18076511

申请日：2022-12-07

申请人： CORNING INCORPORATED

发明人： Xinyu Cao ,  Ling Chen ,  Wanghui Chen ,  Jiangwei Feng ,  Robert Randall Hancock, JR. ,  Yuhui Jin ,  Aize Li ,  Meng Shang

IPC分类号： C09K13/08 ,  C03C3/097 ,  C03C15/00

CPC分类号： C09K13/08 ,  C03C3/097 ,  C03C15/00

摘要： An etchant comprises: greater than or equal to 20 wt % and less than or equal to 45 wt % ammonium bifluoride; greater than or equal to 0.25 wt % and less than or equal to 10 wt % of a silicon compound; greater than or equal to 5 wt % and less than or equal to 30 wt % hydrochloric acid; greater than or equal to 25 wt % and less than or equal to 60 wt % water; and greater than or equal to 0.5 wt % and less than or equal to 20 wt % of polyhydric alcohol. The silicon compound comprises silica, silica gel, ammonium hexafluorosilicate, potassium hexafluorosilicate, sodium hexafluorosilicate, magnesium hexafluorosilicate, or a combination thereof.

公开(公告)号：US20220267195A1

公开(公告)日：2022-08-25

申请号：US17626223

申请日：2020-07-06

申请人： CORNING INCORPORATED

发明人： Haixing Chen ,  Ling Chen ,  Jiangwei Feng ,  Yuhui Jin ,  Jianqiang Zhu

IPC分类号： C03C15/00 ,  C03C23/00 ,  C03C21/00 ,  C09K13/06

摘要： The present disclosure includes a method of making an article including etching a surface of a substrate with an etching suspension comprising an etching cream and glycerin, such that the surface is an anti-glare surface and the article comprises a sparkle of no more than 1%. An article made by the method can include a substrate having a textured surface and comprises a sparkle of no more than 1%.

公开(公告)号：US10690818B2

公开(公告)日：2020-06-23

申请号：US15508307

申请日：2015-09-04

申请人： CORNING INCORPORATED

发明人： Haixing Chen ,  Ling Chen ,  Haofei Gong ,  Liping Hong ,  Cheng-Chung Li

IPC分类号： G02B5/02 ,  G02B1/12

摘要： Embodiments of an anti-glare article and methods for forming the same are disclosed. In one or more embodiments, the anti-glare article includes a substrate having a surface, and a plurality of features disposed on the surface, wherein about 50% or more of the plurality of features comprise a normalized area in the range from about 0.5 to about 1.5, and the normalized area is defined as the relationship (surface area of a feature/average surface area of all features). In some embodiments, about 90% or more of the features have a surface area of about 100 micrometers or less. The anti-glare article exhibits a PPDr of about 5% or less, a transmission haze of less than about 20% and a DOI of less than about 90%. Methods of forming the substrate are also disclosed and include etching a surface of a substrate with an etchant comprising a water soluble metal ion salt.

公开(公告)号：US10364180B2

公开(公告)日：2019-07-30

申请号：US15539472

申请日：2016-01-06

申请人： CORNING INCORPORATED

发明人： Baifeng Chen ,  Haixing Chen ,  Ling Chen ,  Haofei Gong ,  Jun Hou

IPC分类号： C03C15/00

摘要： An apparatus for producing anti-glare surfaces includes an etching cream dipping tank and a sub-tank arranged to receive a slurry of etching cream. A pumping unit is fluidly coupled to the etching cream dipping tank and the sub-tank such that the pumping unit is operable to selectively self-circulate the slurry of etching cream in the sub-tank to improve homogeneity of the etching cream and transfer a volume of the homogenized etching cream from the sub-tank to the etching cream dipping tank.

公开(公告)号：US20230192536A1

公开(公告)日：2023-06-22

申请号：US18083751

申请日：2022-12-19

申请人： CORNING INCORPORATED

发明人： Xinyu Cao ,  Ling Chen ,  Wanghui Chen ,  Jiangwei Feng ,  Meng Shang

IPC分类号： C03C15/00

CPC分类号： C03C15/00 ,  C03C2204/08

摘要： A method of forming a textured glass article comprises: submerging an aluminosilicate glass article in an etchant to an upper submerging depth from a surface of the etchant and at a tilting angle, wherein the aluminosilicate glass article comprises a first major surface and a second major surface opposite the first surface, wherein the tilting angle is a smallest angle between a normal to the first major surface and a vertical; holding the aluminosilicate glass article in the etchant for a holding time; and after the holding time, cycling the aluminosilicate glass article in the etchant between the upper submerging depth and a lower submerging depth deeper than the upper submerging depth for a cycling time.

公开(公告)号：US20230141260A1

公开(公告)日：2023-05-11

申请号：US17918239

申请日：2021-04-13

申请人： Corning Incorporated

发明人： Haixing Chen ,  Ling Chen ,  Jiangwei Feng ,  Meng Qin ,  Jianqiang Zhu

IPC分类号： C09D5/00 ,  C03C3/064

CPC分类号： C09D5/006 ,  C03C3/064 ,  C03C2217/285 ,  C03C2218/111 ,  C03C2217/213

摘要： A glass article is provided (and methods of making the same) that includes: a glass substrate comprising a thickness and a first primary surface; and a porosity-graded layer that extends from the first primary surface of the substrate to a first depth within the substrate. The first depth is from about 250 nm to about 3000 nm. The porosity-graded layer comprises a plurality of pores having an average pore size from about 5 nm to 100 nm. The article comprises a single-side average reflectance of less than 9% at an incident angle of 60 degrees across a spectrum from 350 nm to 2000 nm. Further, the porosity-graded layer comprises a surface porosity at the first primary surface and a bulk porosity at the first depth, the surface porosity greater than the bulk porosity.

公开(公告)号：US11104604B2

公开(公告)日：2021-08-31

申请号：US16485337

申请日：2018-02-09

申请人： CORNING INCORPORATED

发明人： Haixing Chen ,  Ling Chen ,  Chenglong Dai ,  Liming Wang ,  Li Yao ,  Jianqiang Zhu

IPC分类号： B32B3/30 ,  C03C15/00 ,  B32B7/12 ,  B32B17/06 ,  C03C21/00 ,  G02B1/12 ,  G02B5/02

摘要： Anti-glare glass-based articles and methods of processing a glass based article to reduce warp are disclosed. A method for processing a glass-based article includes etching a first surface of the glass article to create a first anti-glare surface having a plurality of first anti-glare features and etching a second surface of the glass-based article to create a second anti-glare surface having a plurality of second anti-glare features. At least one of a length, a width, and a diagonal of the glass-based article is greater than or equal to 500 mm. A difference of warp between a first warp value before etching the first surface and the second surface and a second warp value after etching the first surface and the second surface is less than or equal to 0.15 mm across each of one or more 500 mm intervals of length, width, or diagonal of the glass-based article.

公开(公告)号：US20170369362A1

公开(公告)日：2017-12-28

申请号：US15539472

申请日：2016-01-06

申请人： CORNING INCORPORATED

发明人： Baifeng Chen ,  Haixing Chen ,  Ling Chen ,  Haofei Gong ,  Jun Hou

IPC分类号： C03C15/00

CPC分类号： C03C15/00

摘要： An apparatus for producing anti-glare surfaces includes an etching cream dipping tank and a sub-tank arranged to receive a slurry of etching cream. A pumping unit is fluidly coupled to the etching cream dipping tank and the sub-tank such that the pumping unit is operable to selectively self-circulate the slurry of etching cream in the sub-tank to improve homogeneity of the etching cream and transfer a volume of the homogenized etching cream from the sub-tank to the etching cream dipping tank.

公开(公告)号：US20170285227A1

公开(公告)日：2017-10-05

申请号：US15508307

申请日：2015-09-04

申请人： CORNING INCORPORATED

发明人： Haixing Chen ,  Ling Chen ,  Haofei Gong ,  Liping Hong ,  Cheng-Chung Li

IPC分类号： G02B5/02

摘要： Embodiments of an anti-glare article and methods for forming the same are disclosed. In one or more embodiments, the anti-glare article includes a substrate having a surface, and a plurality of features disposed on the surface, wherein about 50% or more of the plurality of features comprise a normalized area in the range from about 0.5 to about 1.5, and the normalized area is defined as the relationship (surface area of a feature/average surface area of all features). In some embodiments, about 90% or more of the features have a surface area of about 100 micrometers or less. The anti-glare article exhibits a PPDr of about 5% or less, a transmission haze of less than about 20% and a DOI of less than about 90%. Methods of forming the substrate are also disclosed and include etching a surface of a substrate with an etchant comprising a water soluble metal ion salt.

公开(公告)号：US20220073418A1

公开(公告)日：2022-03-10

申请号：US17462848

申请日：2021-08-31

申请人： Corning Incorporated

发明人： Xinyu Cao ,  Christine Cecala ,  Ling Chen ,  Wanghui Chen ,  Yuhui Jin ,  Cameron Robert Nelson ,  Jayantha Senawiratne ,  David Lee Weidman

IPC分类号： C03C15/00 ,  C03C23/00 ,  C03C3/097 ,  C03C3/091 ,  C03C3/085 ,  C09K13/08

摘要： A textured glass article includes: a body comprising an aluminosilicate glass comprising greater than or equal to 16 wt % Al2O3, the body having at least a first surface; and a plurality of polyhedral surface features extending from the first surface, each of the plurality of polyhedral surface features comprising a base on the first surface, a plurality of facets extending from the first surface, and a surface feature size at the base greater than or equal to 10 μm and less than or equal to 350 μm, wherein the plurality of facets of each polyhedral surface feature converge toward one another.