Process For The Preparation Of Nitriles Containing Amino Groups
    5.
    发明授权
    Process For The Preparation Of Nitriles Containing Amino Groups 失效
    含有氨基的腈的制备方法

    公开(公告)号:US3864382A

    公开(公告)日:1975-02-04

    申请号:US1102070

    申请日:1970-02-12

    CPC classification number: C07C255/00 C09K15/18

    Abstract: Production of amino nitriles of the formula:

    WHEREIN R is -CH2-CHR3- by catalytic amination hydrogenation of a compound of the formula:

    WHEREIN R is -CH CR3- or -CH2-CHR3-; R1 and R2 are the same or different and each are an alkyl group of 1 to 4 carbon atoms; R3 is hydrogen or an alkyl group of 1 to 4 carbon atoms; and R4 is hydrogen, an alkyl group of 1 to 4 carbon atoms or an aryl group and wherein R3 and R4 together with the carbon atoms to which they are connected may form a 5 or 6 carbon atom containing ring IN THE PRESENCE OF AT LEAST STOICHIOMETRIC QUANTITIES OF AMMONIA, HYDROGEN PRESSURE OF AT LEAST 50 ATMOSPHERES, TEMPERATURE OF ABOUT 60* TO 180*C, preferably 100* to 140*C wherein the catalyst is platinum or palladium instead of the known nickel, cobalt or rhodium.

    Abstract translation: 生产氨基腈的配方:

    Method for the production of substituted cyanobutyric acids
    10.
    发明授权
    Method for the production of substituted cyanobutyric acids 失效
    生产取代的氰尿酸的方法

    公开(公告)号:US3654339A

    公开(公告)日:1972-04-04

    申请号:US3654339D

    申请日:1969-08-28

    CPC classification number: C07C255/00

    Abstract: METHOD FOR THE PRODUCTION OF SUBSTITUTED 4-CYANOBUTYRIC ACIDS OF THE GENERAL FORMULA:

    HOOC-C(-R1)(-R2)-CH2-CH2-CN

    IN WHICH R1, AND R2 EITHER SIGNIFY ALKYL GROUPS WITH 1-4 C-ATOMS, OR IN WHICH R1 AND R2 TOGETHER WITH THE CARBON ATOM TO WHICH THEY ARE ATTACHED FORM A CARBOCYCLIC RING, BY OXIDATION OF CORRESPONDING SUBSTITUTED 4-CYANOBUTYRIC ALDEHYDES OF THE GENERAL FORMULA:

    HCO-C(-R1)(-R2)-CH2-CH2-CN

    IN WHICH R1 AND R2 HAVE THE MEANING INDICATED ABOVE, IN WHICH THE OXIDATION IS CARRIED OUT WITH HALOGEN IN THE PRESENCE OF WATER.

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