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    Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers
    1.
    发明申请
    Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers 失效
    用于烯烃单体催化低聚的催化剂体系

    公开(公告)号：US20110319579A1

    公开(公告)日：2011-12-29

    申请号：US13204020

    申请日：2011-08-05

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/78 ,  B01J31/00 ,  C07F9/6574

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    2.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20090062493A1

    公开(公告)日：2009-03-05

    申请号：US11961638

    申请日：2007-12-20

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/22 ,  C07F9/535 ,  B01J31/02

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3)  (I) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R4）-P（R1）（R2）-N（R3）（I）<？in-line-formula description =“In-line-formula”end =“lead” =“在线式”末端=“尾”→其中：R1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    3.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100317814A1

    公开(公告)日：2010-12-16

    申请号：US12859327

    申请日：2010-08-19

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/78 ,  C07F9/06 ,  B01J31/18

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (II); P(R1)(R2)—P(R4)═N(R3)  (II) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及配体及其在烯烃单体低聚催化剂中的用途，具有通式（II）的配体; P（R 1）（R 2）-P（R 4）= N（R 3）（II）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。