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    Cyclopentadienylphosphazene complexes (CpPN Complexes) of metals of the third and fourth group and of the lanthanoids
    6.
    发明申请
    Cyclopentadienylphosphazene complexes (CpPN Complexes) of metals of the third and fourth group and of the lanthanoids 审中-公开
    第三和第四组金属和镧系元素的环戊二烯基磷腈络合物（CpPN络合物）

    公开(公告)号：US20110034715A1

    公开(公告)日：2011-02-10

    申请号：US12745037

    申请日：2008-11-25

    Applicant: Jörg Sundermeyer ,  Konstantin Rufanov ,  Alexander Petrov ,  Michael Elfferding ,  Manuel Winkenstette

    Inventor： Jörg Sundermeyer ,  Konstantin Rufanov ,  Alexander Petrov ,  Michael Elfferding ,  Manuel Winkenstette

    IPC: C07F15/00

    CPC classification number: C07F17/00 ,  C07F9/5352 ,  C07F9/5355 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F2420/01 ,  C08F4/6592 ,  C08F4/52

    Abstract: The present invention concerns cyclopentadienylphosphazene complexes (CpPN complexes) of the metals of the third and fourth group and of the lanthanoids with the exception of lutetium. The complexes according to the present invention are isolobal and isoelectronic to [(CpSiN)TiR2] complexes.Exactly one CpPN unit is present in the complexes according to the present invention. In all complexes according to the present invention, the cyclopentadienyl unit of CpPN represents a monodentate, anionic ligand of the metal atom. Furthermore, the metal atom is bound to further anionic ligands. In a preferred embodiment, both the cyclopentadienyl unit and the nitrogen atom are bound within CpPN to the metal atom, so that CpPN then represents a bidentate ligand. Complexes according to the present invention, in which CpN represents a bidentate ligand, are CpPN-constrained geometry complexes (CpPN-CGC). Furthermore, methods are provided for the in situ production of the complexes according to the present invention.The CpPN complexes can be electrically neutral or can be present as cationic complexes. Cationic complexes are formed by replacing one of the other anionic ligands of the metal atom by a neutral ligand; counterions of the cationic CpPN complexes are preferably fluoroborate, tetraphenyl borate, tetrakis-(3,5-trifluormethylphenyl)borate.The production is carried out in situ by reacting a metal halide with a protonated cyclopentadienylphosphazene CpPNH and an alkaline or alkaline earth salt of the desired other anionic ligand.The complexes according to the present invention are suitable for being used as catalysts for the hydroamination and polymerization of olefins.

    Abstract translation: 本发明涉及第三和第四组金属和镧系元素除了镥以外的环戊二烯基膦腈络合物（CpPN络合物）。 根据本发明的络合物是与[（CpSiN）TiR 2]络合物等离子体和等电子的。 根据本发明，复合物中存在完全一个CpPN单元。 在根据本发明的所有复合物中，CpPN的环戊二烯基单元代表金属原子的单齿阴离子配位体。 此外，金属原子与另外的阴离子配位体结合。 在优选的实施方案中，环戊二烯基单元和氮原子都与CpPN中的金属原子结合，使得CpPN表示双齿配位体。 CpN代表二齿配体的本发明配合物是CpPN约束几何配合物（CpPN-CGC）。 此外，提供了根据本发明的复合物的原位生产方法。 CpPN复合物可以是电中性的或可以作为阳离子络合物存在。 通过用中性配体代替金属原子的其它阴离子配体之一形成阳离子络合物; 阳离子CpPN络合物的抗衡离子优选为氟硼酸盐，四苯基硼酸盐，四（3,5-三氟甲基苯基）硼酸盐。 通过使金属卤化物与质子化的环戊二烯基膦腈CpPNH和所需的其它阴离子配体的碱金属或碱土金属盐反应来进行原位生产。 根据本发明的络合物适合用作烯烃的水解和聚合的催化剂。

    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    7.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100311932A1

    公开(公告)日：2010-12-09

    申请号：US12859337

    申请日：2010-08-19

    Applicant: Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    Inventor： Eric Johannes Maria DE BOER ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC: C08F4/22 ,  C07F9/08 ,  B01J31/12

    CPC classification number: C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    Abstract: The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    Abstract translation: 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Process for the preparation of a metal-organic compound comprising at least one imine ligand
    8.
    发明授权
    Process for the preparation of a metal-organic compound comprising at least one imine ligand 有权
    制备包含至少一种亚胺配体的金属 - 有机化合物的方法

    公开(公告)号：US07655592B2

    公开(公告)日：2010-02-02

    申请号：US10567098

    申请日：2004-08-03

    Applicant: Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    Inventor： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC: C08F4/6592 ,  B01J31/12 ,  C07F17/00

    CPC classification number: C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    Abstract: The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    Abstract translation: 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量的碱的存在下，其中HA表示酸，其中H表示其质子，A表示其共轭碱，YNH为式（1），Mv（L1）k（L2）1 （L3）m（L4）nX，其中Y是取代的磷原子，M表示第4族或第5族金属离子，V表示金属离子的化合价，为3,4或5 L1，L2，L3和L4表示M上的配体或17族卤素原子，并且可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand
    10.
    发明申请
    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand 有权
    用于制备包含至少一种亚胺配体的金属有机化合物的方法

    公开(公告)号：US20080045719A1

    公开(公告)日：2008-02-21

    申请号：US10567098

    申请日：2004-08-03

    Applicant: Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    Inventor： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC: C07D233/00 ,  C07F9/02

    CPC classification number: C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    Abstract: The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    Abstract translation: 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量碱的存在下，其中HA代表酸，其中H代表其质子，A代表其共轭碱，YNH如式（1）所示，M代表氢， （L 1/2）2（L 3）（L 1） （2），其中Y是取代的磷原子，M表示4或4位的基团（L 4） 5金属离子，V表示金属离子的化合价，为3,4或5个L 1，L 2，L 3 3和 L 4代表M上的配位体或17族卤素原子，可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

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