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    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS
    2.
    发明申请
    LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 有权
    烯烃单体催化低级化合物的配体和催化剂体系

    公开(公告)号：US20100317814A1

    公开(公告)日：2010-12-16

    申请号：US12859327

    申请日：2010-08-19

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/78 ,  C07F9/06 ,  B01J31/18

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (II); P(R1)(R2)—P(R4)═N(R3)  (II) wherein: the R1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R2 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及配体及其在烯烃单体低聚催化剂中的用途，具有通式（II）的配体; P（R 1）（R 2）-P（R 4）= N（R 3）（II）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
    3.
    发明授权
    Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers 有权
    用于催化低聚烯烃单体的配体及其催化剂体系

    公开(公告)号：US07803886B2

    公开(公告)日：2010-09-28

    申请号：US11961638

    申请日：2007-12-20

    申请人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C08F4/22 ,  C07F9/535 ,  B01J31/02

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (I); P(R4)—P(R1)(R2)═N(R3)  (I) wherein: the R1 group and R2 group are independently selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（I）的配体; P（R 4）-P（R 1）（R 2）= N（R 3）（I）其中：R 1基团和R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基; R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers
    8.
    发明申请
    Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers 失效
    用于烯烃单体催化低聚的催化剂体系

    公开(公告)号：US20110319579A1

    公开(公告)日：2011-12-29

    申请号：US13204020

    申请日：2011-08-05

    申请人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    发明人： Eric Johannes Maria DE BOER ,  Harry VAN DER HEIJDEN ,  Quoc An ON ,  Johan Paul SMIT ,  Arie VAN ZON

    IPC分类号： C08F4/78 ,  B01J31/00 ,  C07F9/6574

    CPC分类号： C07C2/34 ,  B01J31/0265 ,  B01J31/189 ,  B01J2231/14 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07F9/5355 ,  C07F9/6571 ,  C07F9/657154 ,  C07F11/005 ,  C08F110/02

    摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI); (R9)(R10)P—N(R3)—P(R4)  (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.

    摘要翻译： 本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（VI）的配体; （R 9）（R 10）P-N（R 3）-P（R 4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R 3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4基团是任选取代的亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或与被结合的任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合 通过亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的两个氧，硫或氮原子到磷原子。

    PREPARATION OF ALKOXYSULFATES
    9.
    发明申请
    PREPARATION OF ALKOXYSULFATES 审中-公开
    烷基糖苷的制备

    公开(公告)号：US20100010251A1

    公开(公告)日：2010-01-14

    申请号：US12500488

    申请日：2009-07-09

    申请人： Jan Hermen Hendrik MEURS ,  Jasper Roelf Smit ,  Arie Van Zon

    发明人： Jan Hermen Hendrik MEURS ,  Jasper Roelf Smit ,  Arie Van Zon

    IPC分类号： C07C305/14

    CPC分类号： C07C303/24 ,  C07C305/04 ,  C07C305/10

    摘要： A process for the preparation of alkoxysulfates from organic compounds containing one or more nucleophilic groups by reacting said organic compound, in a water-miscible solvent selected from the group consisting of sulfur-containing solvents such as dimethylsulfoxide (DMSO) or sulfolane, or polar solvents such as tetrahydrofuran (THF), dimethylformamide (DMF), dimethylacetamide (DMA) and hexamethylphosphoric triamide (HMPT), with an alkylene sulfate, in a non-water-miscible solvent selected from the group consisting of chlorinated solvents such as methylene chloride, chloroform, carbon tetrachloride, trichloroethane or chlorinated aromatics, such as chlorobenzene or dichlorobenzene, and non-chlorinated aromatics, such as toluene or xylenes, in the presence of a base selected from the group consisting of hydroxides, carbonates and hydrogen carbonates of alkali metals or alkaline earth metals.

    摘要翻译： 一种由含有一个或多个亲核基团的有机化合物制备烷氧基硫酸盐的方法，通过使所述有机化合物与选自二氧化硫（DMSO）或环丁砜的含硫溶剂或极性溶剂的水混溶性溶剂 例如四氢呋喃（THF），二甲基甲酰胺（DMF），二甲基乙酰胺（DMA）和六甲基磷酰三胺（HMPT））与亚烷基硫酸盐在非水混溶性溶剂中，选自氯化溶剂如二氯甲烷，氯仿 ，四氯化碳，三氯乙烷或氯化芳族化合物如氯苯或二氯苯，以及非氯化芳族化合物如甲苯或二甲苯，在选自碱金属或碱金属的氢氧化物，碳酸盐和碳酸氢盐的碱的存在下 地球金属。

    Transition metal complexes
    10.
    发明授权
    Transition metal complexes 失效
    过渡金属络合物

    公开(公告)号：US07547783B2

    公开(公告)日：2009-06-16

    申请号：US11088023

    申请日：2005-03-23

    申请人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    发明人： Eric Johannes Maria De Boer ,  Harry Van Der Heijden ,  Quoc An On ,  Johan Paul Smit ,  Arie Van Zon

    IPC分类号： C07F15/00 ,  B01J31/22 ,  C08F4/80

    CPC分类号： B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0244 ,  B01J2531/842 ,  B01J2531/845 ,  C07F11/005 ,  C07F15/025 ,  C07F15/065 ,  C08F10/00 ,  C08F4/60089 ,  C08F4/69224 ,  C08F4/7042

    摘要： A transition metal complex which is a bis-arylimine pyridine MXn complex or a [bis-arylimine pyridine MXp+][NC−]q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC− is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.

    摘要翻译： 作为双芳基亚胺吡啶MXn络合物或包含双芳基亚胺吡啶配体的[双芳基亚胺吡啶MXp +] [NC-] q络合物的过渡金属络合物，M为过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物; NC-是非配位阴离子; 并且p + q与过渡金属原子M的正式氧化态匹配。本发明的过渡金属络合物，其与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质中具有良好的溶解性和化学惰性非 极性溶剂，特别是芳族烃溶剂。 催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。