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公开(公告)号:US09440893B2
公开(公告)日:2016-09-13
申请号:US14153399
申请日:2014-01-13
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Terry E. Helton , Robert G. Tinger , Lu Han , Andrea P. Wight
CPC classification number: C07C2/862 , C07C2/864 , C07C2521/16 , C07C2529/40 , Y02P20/52 , C07C15/08
Abstract: In a process for producing para-xylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions including a temperature of at least 500° C. and an H2O partial pressure of at least 12 psia (83 kPaa). The catalyst comprises from 5 to 15 wt % ZSM-5, phosphorus or a compound thereof and a binder and has been steamed at a temperature of at least 900° C. The steamed catalyst has no more than two peaks in the 31P MAS NMR spectrum in the range of 0 to −50 ppm.
Abstract translation: 在生产对二甲苯的方法中,在催化剂存在下,在甲醇的条件下,在至少500℃的温度和至少12psia(83kPaa)的H 2 O分压的条件下,用甲醇烷基化苯和/或甲苯, 。 催化剂包含5至15重量%的ZSM-5,磷或其化合物和粘合剂,并在至少900℃的温度下蒸制。蒸汽催化剂在31P MAS NMR谱中不超过两个峰 在0〜-50ppm的范围内。
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公开(公告)号:US20140213840A1
公开(公告)日:2014-07-31
申请号:US14153399
申请日:2014-01-13
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Terry E. Helton , Robert G. Tinger , Lu Han , Andrea P. Wight
IPC: C07C2/86
CPC classification number: C07C2/862 , C07C2/864 , C07C2521/16 , C07C2529/40 , Y02P20/52 , C07C15/08
Abstract: In a process for producing para-xylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions including a temperature of at least 500° C. and an H2O partial pressure of at least 12 psia (83 kPaa). The catalyst comprises from 5 to 15 wt % ZSM-5, phosphorus or a compound thereof and a binder and has been steamed at a temperature of at least 900° C. The steamed catalyst has no more than two peaks in the 31P MAS NMR spectrum in the range of 0 to −50 ppm.
Abstract translation: 在生产对二甲苯的方法中,在催化剂存在下,在甲醇的条件下,在至少500℃的温度和至少12psia(83kPaa)的H 2 O分压的条件下,用甲醇烷基化苯和/或甲苯, 。 催化剂包含5至15重量%的ZSM-5,磷或其化合物和粘合剂,并在至少900℃的温度下蒸制。蒸汽催化剂在31P MAS NMR谱中不超过两个峰 在0〜-50ppm的范围内。
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