公开(公告)号：US20240317658A1

公开(公告)日：2024-09-26

申请号：US18694415

申请日：2021-12-10

Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES

Inventor： Zhongmin LIU ,  Zhengxi YU ,  Yue YANG

IPC: C07C15/08 ,  B01J29/40 ,  B01J37/02

CPC classification number: C07C15/08 ,  B01J29/40 ,  B01J37/0201 ,  C07C2529/40

Abstract: A method for preparing p-xylene is provided. Raw materials containing methanol, naphtha and CO2 are introduced into a reactor filled with a catalyst for a reaction to produce p-xylene. By adding the methanol, the product distribution is adjusted, and the selectivity of p-xylene is obviously improved. In addition, components containing benzene and toluene in aromatic hydrocarbon products are returned to a reaction system and co-fed with the raw materials for a reaction to produce p-xylene, so that cyclic utilization of the raw materials is achieved, and the method has extremely high economic benefits. The method has a simple process and high feasibility, can greatly improve the selectivity and yield of p-xylene, has an important application value, and provides a new way for large-scale utilization of CO2.

公开(公告)号：US20240286977A1

公开(公告)日：2024-08-29

申请号：US18438462

申请日：2024-02-10

Applicant: Exelus Inc.

Inventor： Mitrajit Mukherjee ,  Vamsi M. Vadhri ,  Narenda Joshi

IPC: C07C4/06 ,  B01J21/04 ,  B01J29/16 ,  B01J29/40 ,  B01J29/48 ,  B01J29/78 ,  B01J29/90 ,  B01J35/40 ,  B01J35/61 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J38/02 ,  B01J38/12 ,  C10G11/05 ,  C10G11/10 ,  C10G11/18

CPC classification number: C07C4/06 ,  B01J21/04 ,  B01J29/166 ,  B01J29/40 ,  B01J29/48 ,  B01J29/7815 ,  B01J29/90 ,  B01J35/40 ,  B01J35/615 ,  B01J35/617 ,  B01J35/618 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J38/02 ,  B01J38/12 ,  C10G11/05 ,  C10G11/10 ,  C10G11/182 ,  B01J2229/186 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2521/10 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/70

Abstract: The addition of small amounts of alkaline earth metal oxides (CaO, MgO) as the isomerization function and transition metal oxides (such as MoO3, WO3) as the metathesis function significantly enhances the production of propylene using zeolites. Once the light olefins are formed by cracking on the acid sites of the zeolite, the 1-butene molecules undergo isomerization catalyzed by alkali earth metal oxides and then react with ethylene to produce more propylene.

公开(公告)号：US20240246052A1

公开(公告)日：2024-07-25

申请号：US18566128

申请日：2022-06-23

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

Inventor： Hongyuan ZONG ,  Guozhen QI ,  Pan GAO ,  Xiaohong LI ,  Jing CAO ,  Zhinan YU ,  Yanxue WANG ,  Fei PENG

IPC: B01J8/18 ,  B01J8/00 ,  B01J8/26 ,  C07C1/24

CPC classification number: B01J8/1827 ,  B01J8/0055 ,  B01J8/1863 ,  B01J8/26 ,  C07C1/24 ,  B01J2208/00752 ,  B01J2208/00849 ,  B01J2208/00902 ,  B01J2208/00938 ,  C07C2529/40

Abstract: A fluidized bed reactor, a device for preparing low-carbon olefin, and a method for preparing low-carbon olefin are provided. The reaction zone of the fluidized bed reactor is sequentially, from bottom to top, provided with a raw material first distributor, a raw material second distributor and a catalyst distributor; the catalyst distributor is connected with the catalyst second feeding inlet; a dense-phase zone is formed between the raw material first distributor and the raw material second distributor, and the area where the catalyst distributor is located is formed as a catalyst distribution zone connected with the dense-phase zone; and at least one catalyst first feeding inlet(s) is provided on the side wall of reactor of the dense-phase zone. The distribution of the catalyst and the full contact of the catalyst with the raw materials can be achieved using the fluidized bed reactor and the device.

公开(公告)号：US20240166952A1

公开(公告)日：2024-05-23

申请号：US17990642

申请日：2022-11-18

Applicant: Anellotech, Inc.

Inventor： Torren Carlson ,  Leslaw Mleczko ,  Omar M. Basha ,  William Igoe

IPC: C10G1/00 ,  B01D21/26 ,  B01J8/24 ,  B01J29/40 ,  C07C4/06 ,  C10G1/10

CPC classification number: C10G1/002 ,  B01D21/267 ,  B01J8/24 ,  B01J29/40 ,  C07C4/06 ,  C10G1/10 ,  B01J2208/00805 ,  C07C2529/40 ,  C10G2300/1003 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30

Abstract: A two-step process is described that includes a pyrolytic first step and a catalytic fluid bed second step that without separation upgrades the resulting raw pyrolysis products, for the conversion of waste plastics, polymers, and other waste materials to useful chemical and fuel products such as paraffins, olefins, and aromatics such as BTX.

公开(公告)号：US20240158318A1

公开(公告)日：2024-05-16

申请号：US18476364

申请日：2023-09-28

Applicant: SK Innovation Co., Ltd. ,  SK Geo Centric Co., Ltd.

Inventor： Hee Jung Jeon ,  Ok Youn Kim ,  Ho Won Lee

IPC: C07C4/06 ,  B01J8/24 ,  B01J8/38 ,  B01J21/04 ,  B01J23/18 ,  B01J23/34 ,  B01J23/36 ,  B01J29/48 ,  B01J29/90 ,  B01J35/02 ,  B01J37/02 ,  B01J37/08 ,  B01J38/04

CPC classification number: C07C4/06 ,  B01J8/24 ,  B01J8/382 ,  B01J21/04 ,  B01J23/18 ,  B01J23/34 ,  B01J23/36 ,  B01J29/48 ,  B01J29/90 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J38/04 ,  B01J2208/00761 ,  B01J2208/00769 ,  B01J2229/20 ,  C07C2521/06 ,  C07C2521/16 ,  C07C2523/34 ,  C07C2529/40

Abstract: Provided is a method for converting waste plastic pyrolysis oil into light olefins with a high yield. The method includes: (1) inputting waste plastic pyrolysis oil into a reactor; (2) allowing the waste plastic pyrolysis oil to react in the reactor in the presence of a catalytic cracking catalyst containing a first metal and a second metal to form a product; and (3) recovering light olefins by separating the catalytic cracking catalyst and oil from the product obtained in step (2).

公开(公告)号：US11975309B2

公开(公告)日：2024-05-07

申请号：US16960930

申请日：2019-01-11

Applicant: Ketjen Limited Liability Company

Inventor： Amir Sabahi ,  Eswaramoorthi Iyyamperumal ,  Nataly G. Vargas ,  William Knowles ,  Andrew Loebl ,  Julie Francis

IPC: B01J29/08 ,  B01J6/00 ,  B01J29/00 ,  B01J29/06 ,  B01J29/70 ,  B01J29/80 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/06 ,  B01J37/10 ,  B01J37/28 ,  B01J37/30 ,  C10G11/05 ,  C10G11/18 ,  B01J29/40 ,  B01J29/65

CPC classification number: B01J29/088 ,  B01J6/001 ,  B01J29/005 ,  B01J29/06 ,  B01J29/061 ,  B01J29/085 ,  B01J29/70 ,  B01J29/7038 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/80 ,  B01J35/0013 ,  B01J35/1033 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/036 ,  B01J37/038 ,  B01J37/06 ,  B01J37/10 ,  B01J37/28 ,  B01J37/30 ,  C10G11/05 ,  C10G11/18 ,  B01J2029/062 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7007 ,  B01J29/7042 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2527/14 ,  C07C2527/16 ,  C07C2527/167 ,  C07C2527/18 ,  C07C2527/182 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/70

Abstract: Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high SiO2/Al2O3 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.

公开(公告)号：US11964927B2

公开(公告)日：2024-04-23

申请号：US17766411

申请日：2020-09-30

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Joseph M. Falkowski ,  Ivy D. Johnson

IPC: C07C2/66 ,  B01D15/08 ,  B01J8/02 ,  B01J20/22 ,  C07C7/12 ,  C07C7/13

CPC classification number: C07C2/66 ,  B01D15/08 ,  B01J8/0278 ,  B01J20/226 ,  C07C7/12 ,  C07C7/13 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40

Abstract: A process for producing an alkylaromatic compound comprises providing a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkylating agent, wherein at least the first feed contains an impurity compound comprising at least one of nitrogen, halogens, oxygen, sulfur, arsenic, selenium, tellurium, phosphorus, and Group 1 through Group 12 metals The first feed is passed through an adsorbent comprising a metal-organic framework material under conditions effective to reduce the amount of impurity compound in the first feed and produce a purified first feed. The purified first feed and at least part of the second feed are then contacted with an alkylation catalyst composition under alkylation conditions effective to convert at least part of the alkylatable aromatic compound in the purified first feed to the desired alkylaromatic compound and produce an alkylation effluent.

公开(公告)号：US11964256B2

公开(公告)日：2024-04-23

申请号：US16494875

申请日：2018-03-16

Applicant: Ketjen Limited Liability Company

Inventor： Edward Lee Foster ,  Maria Margaret Ludvig ,  Kevin Alfonso Miller

IPC: B01J29/06 ,  B01J21/12 ,  B01J21/16 ,  B01J29/40 ,  B01J29/70 ,  B01J35/00 ,  C07C4/06

CPC classification number: B01J21/12 ,  B01J21/16 ,  B01J29/40 ,  B01J29/70 ,  B01J35/002 ,  C07C4/06 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2529/40 ,  C07C2529/70

Abstract: Provided is a Fluid Catalytic Cracking catalyst additive composition and method of making the same. The catalyst additive composition comprises zeolite about 35 wt % to about 80 wt %, preferably about 40 wt % to about 70 wt %; silica about 0 wt % to about 10 wt %, preferably about 2 wt % to about 10 wt %; about 10.5 wt % to 20 wt % alumina and about 7 wt % to 20 wt % P2O5, preferably about 11 wt % to about 18 wt %, and the balance clay which can fall between 0 and 50 wt %. The alumina is typically derived from more than one source, such as at least an amorphous or small crystallite size pseudo-boehmite alumina and then either a large crystallite size alumina or other reactive alumina.

公开(公告)号：US20240059630A1

公开(公告)日：2024-02-22

申请号：US18260971

申请日：2022-01-11

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  SINOPEC RESEARCH INSTITUTE OF PETROLEUM PROCESSING CO., LTD.

Inventor： Yibin LUO ,  Chengqiang WANG ,  Ying OUYANG ,  Enhui XING ,  Xingtian SHU

IPC: C07C4/06 ,  B01J29/40 ,  B01J29/08 ,  B01J29/80 ,  B01J37/28 ,  B01J37/00 ,  B01J21/16 ,  B01J37/10

CPC classification number: C07C4/06 ,  B01J29/40 ,  B01J29/084 ,  B01J29/80 ,  B01J37/28 ,  B01J37/0018 ,  B01J21/16 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/16 ,  B01J2229/24 ,  C07C2529/08 ,  C07C2529/40

Abstract: A catalytic cracking agent has an active component consisting of a phosphorus-modified molecular sieve and a non-phosphorus-modified molecular sieve or only consisting of a phosphorus-modified molecular sieve. According to an electron probe microanalysis (EPMA), the D value of phosphorus in the catalytic cracking agent is ≥65%, preferably ≥68%, provided that the active component consists of the phosphorus-modified molecular sieve and the non-phosphorus-modified molecular sieve, or the D value of phosphorus in the catalytic cracking agent is ≥82%, preferably ≥84%, provided that the active component only consists of the phosphorus-modified molecular sieve.

公开(公告)号：US11878292B2

公开(公告)日：2024-01-23

申请号：US18176459

申请日：2023-02-28

Applicant: UOP LLC

Inventor： Deng-Yang Jan ,  Jaime G. Moscoso ,  Lijun Xu ,  Xi Zhao

IPC: C07C1/24 ,  B01J29/40 ,  C07C4/06 ,  B01J37/10 ,  B01J35/10

CPC classification number: B01J29/40 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/105 ,  C07C1/24 ,  C07C4/06 ,  C07C2529/40

Abstract: An improved MFI zeolite having low aluminum occupation at intersection sites characterized by an ortho-xylene to para-xylene uptake ratio of 0.1 to about 0.55. Processes for converting hydrocarbon or oxygenate to a product comprising light olefins and/or aromatics using the improved MFI zeolite as catalyst are also disclosed. Para-xylene in the product may be greater than about 24% of the xylenes.