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    Metal-Organic Framework Materials Comprising A Diimine Scaffold and Methods For Production Thereof
    1.
    发明申请
    Metal-Organic Framework Materials Comprising A Diimine Scaffold and Methods For Production Thereof 有权

    公开(公告)号：US20220153757A1

    公开(公告)日：2022-05-19

    申请号：US17310622

    申请日：2020-03-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Joseph M. Falkowski ,  Carter W. Abney ,  Mary S. Abdulkarim ,  Aaron Sattler ,  Michele Paccagnini ,  Simon C. Weston

    IPC: C07F3/06 ,  C07F15/04 ,  C01B37/00

    Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Crystallization may be problematic in some instances when secondary binding sites are present in the multidentate organic ligand. Multidentate organic ligands comprising first and second binding sites bridged together with a third binding site comprising a diimine moiety may alleviate these issues, particularly when using a preformed metal cluster as a metal source to form a MOF. Such MOFs may comprise a plurality of metal centers, and a multidentate organic ligand coordinated to the plurality of metal centers to define an at least partially crystalline network structure having a plurality of internal pores, and in which the multidentate organic ligand comprises first and second binding sites bridged together with a third binding site comprising a diimine moiety. Particular MOFs may comprise N,N′-di(1H-pyrazol-4-yl)ethane-1,2-diimine as a multidentate organic ligand.

    Production Of Cyclopentadiene From Furfural
    2.
    发明申请
    Production Of Cyclopentadiene From Furfural 有权

    公开(公告)号：US20210188735A1

    公开(公告)日：2021-06-24

    申请号：US17077327

    申请日：2020-10-22

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Kun Wang ,  Aaron Sattler ,  Jihad M. Dakka

    IPC: C07C1/24 ,  C07C1/247 ,  B01J8/00

    Abstract: The application relates to processes and systems that use a furfural compound for producing five-membered carbocyclic rings that are unsaturated, such as cyclopentene and cyclopentadiene. Examples methods for conversion of furfural compounds may include converting a furfural compound to at least a five-membered, saturated carbocyclic ring, and converting the five-membered, saturated carbocyclic ring in a presence of a catalyst to at least a five-membered, unsaturated carbocyclic ring.

    Selective Hydrogen Removal
    3.
    发明申请
    Selective Hydrogen Removal 有权

    公开(公告)号：US20210155565A1

    公开(公告)日：2021-05-27

    申请号：US17084748

    申请日：2020-10-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Aaron Sattler ,  Michele L. Paccagnini ,  Pedro M. Serna Merino ,  Henry K. Klutse

    IPC: C07C5/48 ,  B01J29/74

    Abstract: Processes are provided for the removal of hydrogen from a mixture. The process can be performed by contacting a mixture comprising hydrogen, oxygen, and one or more organic compounds with a synthetic zeolite to produce water or steam. The synthetic zeolite can include Si and Al and has a SiO2:Al2O3 molar ratio of greater than 4:1, an 8-membered ring zeolite having a framework type of AEI, AFT, AFX, CHA, CDO, DDR, EDI, ERI, IHW, ITE, ITW, KFI, MER, MTF, MWF, LEV, LTA, PAU, PWN, RHO, SFW or UFI, a degree of crystallinity of at least 80% as measured by ASTM D535-197, and at least 0.01 wt % of at least one catalytic metal, based on a weight of the synthetic zeolite, where the at least one catalytic metal can include Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga, alloys thereof, or mixtures thereof. At least 95% of the catalytic metal can be disposed within a plurality of pores of the synthetic zeolite.

    PROCESSES FOR POLYMERIZING ALPHA-OLEFINS, INTERNAL OLEFINS AND COMPOSITIONS THEREOF
    5.
    发明申请
    PROCESSES FOR POLYMERIZING ALPHA-OLEFINS, INTERNAL OLEFINS AND COMPOSITIONS THEREOF 审中-公开

    公开(公告)号：US20200308316A1

    公开(公告)日：2020-10-01

    申请号：US16833992

    申请日：2020-03-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Aaron Sattler ,  Suzzy C.H. Ho ,  Michele L. Paccagnini ,  Christian E. Padilla

    IPC: C08F4/70 ,  C08F10/14

    Abstract: The present disclosure provides base stocks and or diesel fuel, and processes for producing such base stocks and or diesel fuel by polymerizing alpha-olefins and internal olefins. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes: i) introducing, neat or in the presence of a solvent, a feed comprising a branched C5-C30 internal olefin, with a catalyst compound comprising a group 8, 9, 10, or 11 transition metal and at least one heteroatom and ii) obtaining a C6-C100 polyolefin product having one olefin, a methylene content of from about 1 wt % to about 98 wt %, and or a methyl content of from about 1 wt % to about 75 wt %. The feed may further include a linear C4-C30 internal olefin, a C2-C30 alpha-olefin, or a mixture thereof.

    Selective hydrogen removal
    6.
    发明授权
    Selective hydrogen removal 有权

    公开(公告)号：US11299444B2

    公开(公告)日：2022-04-12

    申请号：US17084748

    申请日：2020-10-30

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Aaron Sattler ,  Michele L. Paccagnini ,  Pedro M. Serna Merino ,  Henry K. Klutse

    IPC: C07C5/48 ,  B01J29/74

    Abstract: Processes are provided for the removal of hydrogen from a mixture. The process can be performed by contacting a mixture comprising hydrogen, oxygen, and one or more organic compounds with a synthetic zeolite to produce water or steam. The synthetic zeolite can include Si and Al and has a SiO2:Al2O3 molar ratio of greater than 4:1, an 8-membered ring zeolite having a framework type of AEI, AFT, AFX, CHA, CDO, DDR, EDI, ERI, IHW, ITE, ITW, KFI, MER, MTF, MWF, LEV, LTA, PAU, PWN, RHO, SFW or UFI, a degree of crystallinity of at least 80% as measured by ASTM D535-197, and at least 0.01 wt % of at least one catalytic metal, based on a weight of the synthetic zeolite, where the at least one catalytic metal can include Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga, alloys thereof, or mixtures thereof. At least 95% of the catalytic metal can be disposed within a plurality of pores of the synthetic zeolite.

    PROCESSES FOR POLYMERIZING INTERNAL OLEFINS AND COMPOSITIONS THEREOF
    9.
    发明申请
    PROCESSES FOR POLYMERIZING INTERNAL OLEFINS AND COMPOSITIONS THEREOF 审中-公开

    公开(公告)号：US20200181295A1

    公开(公告)日：2020-06-11

    申请号：US16705319

    申请日：2019-12-06

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： Suzzy C. H. Ho ,  Christian E. Padilla ,  Aaron Sattler ,  Michele Paccagnini

    IPC: C08F4/06 ,  C08F10/14 ,  C10M107/10

    Abstract: The present disclosure provides base stocks and processes for producing such basestocks by polymerizing internal olefins. The present disclosure further provides base stocks, comprising low molecular weight polyolefin products, having one or more of improved flow, low temperature properties, and thickening efficiency. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes introducing a feedstream comprising C4-C30 internal-olefins with a catalyst system comprising a nickel diimine catalyst optionally in the presence of a solvent. The method includes obtaining a C6-C100 polyolefin product having one or more of a carbon fraction of epsilon-carbons of from about 0.08 to about 0.3, as determined by 13C NMR spectroscopy, based on the total carbon content of the polyolefin product.

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