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公开(公告)号：US11015131B2
公开(公告)日：2021-05-25
申请号：US16541297
申请日：2019-08-15
发明人： Matthew S. Ide , Suzzy C. Ho , Guang Cao , Brian M. Weiss , Sara L. Yohe
摘要： A system and methods for manufacturing a base oil stock from a light hydrocarbon stream are provided. An example method includes cracking a light hydrocarbon stream to form an impure olefinic stream, separating water from the impure olefinic stream, and oligomerizing the impure olefinic stream to form a raw oligomer stream. A light olefinic stream from the raw oligomer stream and linear alpha olefins are recovered from the light olefinic stream. A heavy olefinic stream is distilled from the raw oligomer stream and hydro-processed to form a hydro-processed stream. They hydro-processed stream is distilled to form the base oil stock.
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公开(公告)号：US20200063043A1
公开(公告)日：2020-02-27
申请号：US16541297
申请日：2019-08-15
发明人： Matthew S. Ide , Suzzy C. Ho , Guang Cao , Brian M. Weiss , Sara L. Yohe
摘要： A system and methods for manufacturing a base oil stock from a light hydrocarbon stream are provided. An example method includes cracking a light hydrocarbon stream to form an impure olefinic stream, separating water from the impure olefinic stream, and oligomerizing the impure olefinic stream to form a raw oligomer stream. A light olefinic stream from the raw oligomer stream and linear alpha olefins are recovered from the light olefinic stream. A heavy olefinic stream is distilled from the raw oligomer stream and hydro-processed to form a hydro-processed stream. They hydro-processed stream is distilled to form the base oil stock.
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公开(公告)号：US10717069B2
公开(公告)日：2020-07-21
申请号：US15831594
申请日：2017-12-05
发明人： Brian M. Weiss , Gerardo J. Majano , Tilman W. Beutel , Karl G. Strohmaier , John F. Brody , Samia Ilias , Scott J. Weigel , Shamel Merchant , Eugine Choi , Robert J. Colby , Walter Weissman
IPC分类号： B01J23/46 , F02M26/35 , C10L3/08 , C01B3/40 , B01J23/08 , B01J23/06 , B01J23/60 , B01J29/70 , B01J29/85 , B01J23/10 , B01J29/74 , B01J35/00 , C10G63/08 , B01J29/78 , C10G47/20 , B01J37/28 , B01J29/46 , B01J37/04 , B01J29/48 , C10G47/14 , C10G2/00 , B01J29/76 , B01J29/44 , C10G47/04 , C10G47/18 , B01J29/80 , C10G35/09 , C10G35/095 , B01J23/00 , B01J37/08 , B01J23/63 , B01J37/03 , B01J37/02 , B01J23/62 , B01D53/92
摘要： Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.
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公开(公告)号：US20220143586A1
公开(公告)日：2022-05-12
申请号：US17430758
申请日：2020-01-22
发明人： Tilman W. Beutel , Gerardo J. Majano Sanchez , Walter Weissman , Brian M. Weiss , Himanshu Gupta , John F. Brody , Scott J. Weigel
摘要： The present disclosure provides mesoporous catalyst compounds and compositions having one or more group 13 atoms. The present disclosure further relates to processes for converting hydrocarbon feedstocks to small olefins. In one aspect, a catalyst compound includes a zeolite having a structural type selected from MFI, MSE, MTW, Theta-One (TON), Ferrierite (FER), AFI, AFS, ATO, BEA, BEC, BOG, BPH, CAN, CON, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITN, IWR, IWW, LTL, MAZ, MEI, MOR, MOZ, OFF, OKO, OSI, SAF, SAO, SEW, SFE, SFO, SSF, SSY, and USI, or a combination thereof, the zeolite having a silicon to aluminum molar ratio (Si/Al ratio) of from about 5 to about 40. In one aspect, a catalyst composition includes the catalyst compound and one or more group 13 metal.
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公开(公告)号：US10858600B2
公开(公告)日：2020-12-08
申请号：US16541617
申请日：2019-08-15
发明人： Guang Cao , Jihad M. Dakka , Suzzy C. Ho , Brian M. Weiss
摘要： Systems and a method for manufacturing a base stock from a light gas stream are provided. An example method includes oxidizing the light gas stream to form a raw ethylene stream. Water is removed from the raw ethylene stream, and carbon monoxide in the raw ethylene stream is oxidized. Carbon dioxide is separated from the raw ethylene stream, and the raw ethylene stream is oligomerized to form a raw oligomer stream. A light olefinic stream is distilled from the raw oligomer stream and a light alpha olefin is recovered from the light olefinic stream. A heavy olefinic stream is distilled from the raw oligomer stream. The heavy olefinic stream is hydro-processed to form a hydro-processed stream. the hydro-processed stream is distilled to form the base stock.
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公开(公告)号：US20200063045A1
公开(公告)日：2020-02-27
申请号：US16541617
申请日：2019-08-15
发明人： Guang Cao , Jihad M. Dakka , Suzzy C. Ho , Brian M. Weiss
摘要： Systems and a method for manufacturing a base stock from a light gas stream are provided. An example method includes oxidizing the light gas stream to form a raw ethylene stream. Water is removed from the raw ethylene stream, and carbon monoxide in the raw ethylene stream is oxidized. Carbon dioxide is separated from the raw ethylene stream, and the raw ethylene stream is oligomerized to form a raw oligomer stream. A light olefinic stream is distilled from the raw oligomer stream and a light alpha olefin is recovered from the light olefinic stream. A heavy olefinic stream is distilled from the raw oligomer stream. The heavy olefinic stream is hydro-processed to form a hydro-processed stream. the hydro-processed stream is distilled to form the base stock.
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公开(公告)号：US20190055178A1
公开(公告)日：2019-02-21
申请号：US16101790
申请日：2018-08-13
IPC分类号： C07C5/48
摘要： This disclosure relates to processes, compositions, and systems useful for the oxydehydrogenation of alkanes to form olefins (e.g., for the conversion of ethane to ethylene). The processes use an oxygen transfer agent and may be carried out in any suitable reactor, including a reverse flow reactor, a circulating fluid bed reactor, or a cyclic co-flow reactor.
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公开(公告)号：US20220274085A1
公开(公告)日：2022-09-01
申请号：US17632092
申请日：2020-07-30
发明人： Brian M. Weiss , Changmin Chun , Sophie Liu , Federico Barrai , Paul F. Keusenkothen , Zachary D. Young
摘要： A reverse flow reactor (RFR) and process having a forward reaction feed cycle, a reverse reaction feed cycle, and a reverse regeneration cycle. The heat convected in the forward feed cycle matches the heat convected in the reverse flow cycles. Compared to an RFR without the reverse feed cycle, the three-cycle RPR substantially reduces the regeneration air flow rate, associated compression requirements, and the overall reactor volume, that are required.
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公开(公告)号：US20210047181A1
公开(公告)日：2021-02-18
申请号：US16838793
申请日：2020-04-02
摘要： Systems and methods are provided for using oxycombustion to provide heat within a reverse flow reactor environment. The oxygen for the oxycombustion can be provided by oxygen stored in an oxygen storage component in the reactor. By using an oxygen storage component to provide the oxygen for combustion during the regeneration step, heat can be added to a reverse flow reactor while reducing or minimizing addition of diluents and while avoiding the need for an air separation unit. As a result, a regeneration flue gas can be formed that is substantially composed of CO2 and/or H2O without requiring the additional cost of creating a substantially pure oxygen-containing gas flow.
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公开(公告)号：US20220235282A1
公开(公告)日：2022-07-28
申请号：US17643044
申请日：2021-12-07
发明人： Brian M. Weiss , Sophie Liu , Michael R. Harper, JR. , Herbert W. Barry , Changmin Chun , Barrington S. Goldson , Justin R. Johnson , Faria Nusrat
摘要： Systems and methods are provided for using a reverse flow reactor (or another reactor with flows in opposing directions at different parts of a process cycle) for pyrolysis of hydrocarbons. The systems and methods can include a reactor that includes a combustion catalyst to initiate and/or maintain combustion within the reactor in a controlled manner during the heating and/or regeneration portion(s) of the reaction cycle. A fuel can also be used that has a greater resistance to auto-combustion, such as a fuel that is composed primarily of methane and/or other hydrocarbons. During operation, the temperature in at least an initial portion of the reactor can be maintained at a temperature so that auto-ignition of the auto-combustion resistant fuel injected during the heating step(s) is reduced or minimized. This can allow combustion to be initiated when the auto-combustion resistant fuel comes into contact with the catalyst. Additionally, the amount and positioning of the catalyst within the reactor can be controlled so that combustion of the fuel takes place over a substantially longer period of time than combustion during a conventional reactor heating step. Because the fuel is moving within the reactor during combustion, extending the combustion time results in a substantial expansion of the volume where combustion occurs. Optionally in combination with an improved reaction cycle, this can expand the portion of the reactor that is directly heated by combustion, allowing for an improved temperature distribution within the reactor during the pyrolysis step.
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