公开(公告)号：US20180162789A1

公开(公告)日：2018-06-14

申请号：US15839974

申请日：2017-12-13

Applicant: ExxonMobil Research and Engineering Company

Inventor： Sophie LIU ,  Jihad M. DAKKA ,  Partha NANDI ,  Sara YACOB ,  Quddus A. NIZAMI ,  Chuansheng BAI

IPC: C07C2/86 ,  C07C2/62 ,  C07C31/12 ,  C07C31/125 ,  C07C29/50 ,  C07C5/02

Abstract: Methods and systems for converting hydrocarbons including exposing a portion of a hydroperoxide-containing feed including tert-butyl hydroperoxide to a solid deperoxidation catalyst under decomposition conditions to form an oxidation effluent comprising tert-butyl alcohol, wherein the solid deperoxidation catalyst comprises a manganese oxide octahedral molecular sieve, are provided herein. Further methods and systems for converting the oxidation effluent to an alkylation product are also provided herein.

公开(公告)号：US20190185397A1

公开(公告)日：2019-06-20

申请号：US16203920

申请日：2018-11-29

Applicant: ExxonMobil Research and Engineering Company

Inventor： Partha NANDI ,  Steven L. SUIB ,  Sumathy RAMAN

IPC: C07C29/50 ,  B01J3/00

CPC classification number: C07C29/50 ,  B01J3/008 ,  B01J2203/06 ,  C07C27/12 ,  C07C31/04

Abstract: Systems and methods are provided for direct methane conversion to methanol. The methods can include exposing methane to an oxidant, such as O2, in a solvent at conditions that are substantially supercritical for the solvent while having a temperature of about 310° C. or less, or about 300° C. or less, or about 290° C. or less. The solvent can correspond to an electron donor solvent that, when in a supercritical state, can complex with O2. By forming a complex with the O2, the supercritical electron donor solvent can facilitate conversion of methane to methanol at short residence times while reducing or minimizing further oxidation of the methanol to other products.

公开(公告)号：US20180258023A1

公开(公告)日：2018-09-13

申请号：US15904581

申请日：2018-02-26

Applicant: ExxonMobil Research and Engineering Company

Inventor： Partha NANDI ,  Steven L. SUIB ,  Timothy D. SHAFFER

IPC: C07C51/285 ,  C07C51/25 ,  B01J23/34

CPC classification number: C07C51/285 ,  B01J23/34 ,  C07C51/25 ,  C07C67/39 ,  C07C69/54

Abstract: A process for forming allyl acrylate, comprising contacting allyl ether in solution with a solvent with one or more oxidants in the presence of a mesoporous manganese oxide (MnOx) catalyst.