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    Method of producing a planographic printing plate
    1.
    发明授权
    Method of producing a planographic printing plate 有权
    平版印刷版的制造方法

    公开(公告)号：US08993216B2

    公开(公告)日：2015-03-31

    申请号：US13773622

    申请日：2013-02-21

    Applicant: FUJIFILM Corporation

    Inventor： Yoichiro Ara ,  Shigekatsu Fujii ,  Norio Aoshima

    IPC: B41M5/00 ,  B41N1/00 ,  G03F7/00 ,  G03F7/20 ,  B41C1/10

    CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41N1/003

    Abstract: A method for producing a planographic printing plate is provided, which includes: subjecting a planographic printing plate precursor to image-wise exposure, wherein the precursor includes plural recording layers at least one of which contains (A) an infrared absorbing agent on a support, the upper recording layer contains (B) a water-insoluble and alkali-soluble polymer compound having a repeating unit containing a fluoroalkyl group or a siloxane structure; and developing the precursor using an alkali developer containing (C)an ammonium salt compound of Formulae (C-1) to (C-3), wherein R1 represents a methyl group or an ethyl group, R2 and R3 represent a hydrocarbon group having 3 to 20 carbon atoms, R4 represents a hydrocarbon group, A represents an atomic group which forms a nitrogen-containing aliphatic ring with N+, B represents an atomic group which forms a nitrogen-containing aromatic ring with N+, and X−represents a counter anion.

    Abstract translation: 提供一种平版印刷版的制造方法，其特征在于，包括：对平版印刷版原版进行成像曝光，其中前体包括多个记录层，其中至少一层在载体上含有（A）红外线吸收剂， 上记录层含有（B）具有含氟代烷基或硅氧烷结构的重复单元的水不溶性和碱溶性高分子化合物; 并使用含有（C）式（C-1）至（C-3）的铵盐化合物的碱显影剂显影前体，其中R 1表示甲基或乙基，R 2和R 3表示具有3个 至20个碳原子，R 4表示烃基，A表示与N +形成含氮脂肪族环的原子团，B表示与N +形成含氮芳香环的原子团，X表示抗衡阴离子 。

    Method of making planographic printing plate and planographic printing plate
    3.
    发明授权
    Method of making planographic printing plate and planographic printing plate 有权
    平版印刷版和平版印刷版的制作方法

    公开(公告)号：US09091926B2

    公开(公告)日：2015-07-28

    申请号：US13756538

    申请日：2013-02-01

    Applicant: FUJIFILM CORPORATION

    Inventor： Shigekatsu Fujii ,  Yuichi Yasuhara ,  Yoshinori Taguchi ,  Norio Aoshima

    IPC: G03F7/00 ,  G03F7/20 ,  B41C1/10 ,  B41N3/08 ,  G03F7/32 ,  B41N1/00

    CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/266 ,  B41N3/08 ,  G03F7/322

    Abstract: A method of making a planographic printing plate includes exposing, to infrared light, a planographic printing plate precursor including a recording layer provided on a substrate, and developing the precursor using an aqueous alkaline solution. The recording layer comprises a copolymer containing a structural unit derived from (meth)acrylonitrile and at structural unit derived from styrene, a water-insoluble and alkali-soluble resin, and an infrared absorbing agent, the solubility of the recording layer in the aqueous alkaline solution being increased by the exposure. The aqueous alkaline solution has a pH of 8.5 to 10.8 and contains a betaine-based amphoteric surfactant and an ammonium salt represented by Formula (I): R1, R2, R3, and R4 each independently represent an alkyl or aryl group; the total number of carbon atoms in R1, R2, R3, and R4 is not more than 20; and X− represents a counter anion.

    Abstract translation: 制造平版印刷版的方法包括将包含设置在基材上的记录层的平版印刷版原版曝光于红外光，并使用碱性水溶液显影前体。 记录层包含含有衍生自（甲基）丙烯腈的结构单元和衍生自苯乙烯的结构单元，水不溶性和碱溶性树脂和红外吸收剂的共聚物，记录层在碱性水溶液中的溶解度 溶液通过曝光增加。 碱性水溶液的pH为8.5〜10.8，含有基于甜菜碱的两性表面活性剂和式（I）表示的铵盐：R1，R2，R3和R4各自独立地表示烷基或芳基; R1，R2，R3和R4中的碳原子总数不超过20; X表示抗衡阴离子。

    Positive-working lithographic printing plate precursor for infrared laser and process for making lithographic printing plate
    4.
    发明授权
    Positive-working lithographic printing plate precursor for infrared laser and process for making lithographic printing plate 有权
    用于红外激光的正性平版印刷版原版和用于制作平版印刷版的工艺

    公开(公告)号：US09046774B2

    公开(公告)日：2015-06-02

    申请号：US14079034

    申请日：2013-11-13

    Applicant: FUJIFILM Corporation

    Inventor： Yoshinori Taguchi ,  Noriaki Watanabe ,  Norio Aoshima

    IPC: G03F7/00 ,  G03F7/09 ,  B41C1/10 ,  G03F7/095 ,  G03F7/11 ,  G03F7/32 ,  G03F7/12

    CPC classification number: G03F7/091 ,  B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266 ,  G03F7/095 ,  G03F7/11 ,  G03F7/12 ,  G03F7/322

    Abstract: A positive-working lithographic printing plate precursor for infrared laser is provided that includes, layered sequentially above a support, a lower layer and an upper layer, the lower layer and/or the upper layer including an infrared absorbing agent, either the lower layer comprising an alkali-soluble group-containing graft copolymer or the upper layer comprising a sulfonamide group-, active imide group-, and/or amide group-containing graft copolymer, and the graft copolymer being a polyurethane resin having as a graft chain an ethylenically unsaturated monomer-derived constitutional unit. There is also provided a process for making a lithographic printing plate, the process including in sequence an exposure step of imagewise exposing by means of an infrared laser the positive-working lithographic printing plate precursor for infrared laser and a development step of developing using an aqueous alkali solution with a pH of 8.5 to 10.8.

    Abstract translation: 提供一种用于红外激光的正性平版印刷版原版，其包括在支撑体，下层和上层之上顺序层叠，下层和/或上层包括红外线吸收剂，下层包含 含有碱溶性基团的接枝共聚物或含有磺酰胺基，活性酰亚胺基和/或酰胺基的接枝共聚物的上层，所述接枝共聚物是具有作为接枝链的烯属不饱和基团的聚氨酯树脂 单体衍生的结构单元。 还提供了一种制备平版印刷版的方法，该方法依次包括通过红外激光成像曝光的曝光步骤，用于红外激光的正性平版印刷版原版和使用水性显影的显影步骤 pH为8.5〜10.8的碱溶液。

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