公开(公告)号：US3598853A

公开(公告)日：1971-08-10

申请号：US3598853D

申请日：1968-07-17

Applicant: GEN ELECTRIC

Inventor： FRIEDMAN NORMAN J ,  BERGER ABE ,  SELIN TERRY G

IPC: C07F7/08 ,  C07F7/10 ,  C07F7/18 ,  C08G77/26 ,  C09G1/16 ,  C11D3/16 ,  C07F7/02 ,  C07F7/04

CPC classification number: C09G1/16 ,  C07F7/0892 ,  C07F7/10 ,  C07F7/1836 ,  C08G77/26 ,  C11D3/162 ,  Y02P20/582

Abstract: A QUATERNARY AMMONIUM HYDROXIDE TYPE OF ION EXCHANGE RESIN IS USED IN A CYANOETHYLATION TYPE REACTION BETWEEN A BRANCHED CHAIN OLEFINIC NITRILE AND AN UNSATURATED ALCOHOL. THE CYANO(BRANCHED ALKOXY)ALKENE PRODUCED IS THEN REACTED WITH A SILANE BY AN SIH-OLEFIN ADDITION REACTION. THE CORRESPONDING AMINE IS MADE FROM THE NITRILE BY HYDROGENATION AT LOW PRESSURE. ONE OF THE SILANES PRODUCED BY THE ABOVE METHOD, 3-(2-METHYL-3-AMINOPROPOXY)PROPYLTRIMETHOXYSILANE, IS AN EXCEPTIONALLY VALUABLE COMPONENT IN DETERGENT RESISTANT POLISHES.