Amino-functional silicone compounds
    1.
    发明授权
    Amino-functional silicone compounds 失效
    氨基官能硅氧烷化合物

    公开(公告)号:US3903082A

    公开(公告)日:1975-09-02

    申请号:US40827173

    申请日:1973-10-23

    Applicant: GEN ELECTRIC

    Inventor: BERGER ABE

    CPC classification number: C07F7/1804 C02F1/545 C08J5/08

    Abstract: wherein R, R1, R16, R12, R13, R14 and R15 are selected from hydrogen and hydrocarbon radicals, while M is selected from sulfone and ketone groups, h is a whole number that varies from 2 to 20 and a is a whole number that varies from 0 to 2. This novel class of compounds are useful as flocculents for colloidal organic matter, as ingredients for detergent resistant polishes and as bonding agents for bonding various plastic resins and rubber to glass fibers and other types of glass material.
    A novel class of silicone compounds of the formula,

    Abstract translation: 一种新一类下式的硅氧烷化合物:R 12 R 13 || RaR 16 CH-CH ||(R 1 O)3-a Si(CH)hN ANGLE ANGLE M CH-CH || R14R15其中R,R1,R16,R12,R13, R 14和R 15选自氢和烃基,而M选自砜和酮基,h是从2至20变化的整数,a是0至2的整数。这种新型化合物 可用作胶体有机物的絮凝剂,作为耐洗涤剂抛光剂的成分以及用于将各种塑料树脂和橡胶粘合到玻璃纤维和其它类型的玻璃材料的粘合剂。

    Aminoalkylesteralkylpolysiloxanes
    3.
    发明授权
    Aminoalkylesteralkylpolysiloxanes 失效
    氨基甲基丙烯酰基硅氧烷

    公开(公告)号:US3558556A

    公开(公告)日:1971-01-26

    申请号:US3558556D

    申请日:1968-07-17

    Applicant: GEN ELECTRIC

    CPC classification number: C07C255/00 C07F7/0836 C07F7/12 C07F7/1836 C08G77/26

    Abstract: TO PRODUCE A COPOLYMER CONTAINING

    (R-)A-SI(-C(-R'')2-CH(-R'')-(C(-R'')2)B-COO-(C(-R'')2)C-Z)-

    O((3-A)/2) UNITS AND

    -O-(SI(-CH3)2-O)D-


    HO-(SI(-CH3)2-O)D-H

    IS REACTED WITH A SILANOL STOPPED FLUID OF THE FORMULA,
    (C(-R'')2)C-CN

    (R-)A-SI(-X)(3-A)-C(-R'')2-CH(-R'')-(C(-R'')2)B-COO-

    (R-)A-SI(-X)(3-A)-H + CATALYST -->

    (R''-)2-C=C(-R'')-(C(-R'')2)B-COO-(C(-R'')2)C-CN +

    CATALYST -->

    (R''-)2-C=C(-R'')-(C(-R'')2)B-COOH + HO-(C(-R'')2)C-CN +

    ARE MADE BY THE FOLLOWING REACTIONS:

    (C(-R'')2)C-CN

    (R-)A-SI(-X)(3-A)-C(-R'')2-CH(-R'')-(C(-R'')2)B-COO-

    CYANOALKYLESTERALKYISILANES WITHIN THE SCOPE OF THE FORMULA:
    BLOCKS. IN THE ABOVE FORMULAS, R IS AN ORGANIC RADICAL, R'' IS AN ORGANIC RADICAL OR HYDROGEN, X IS A HYDROLYZABLE GROUP, Z IS A -CH2-NH2 OR A-CN RADICAL, A HAS A VALUE OF 0 TO 2, B HAS A VALUE OF 0 TO 4, C HAS A VALUE OF ONE TO 5, AND D HAS A VALUE OF 5 TO 500. THE COPOLYMER CONTAINING CYANOALKYLESTERALKYLSILANE UNITS IS USEFUL AS A SOLVENT RESISTANT PROTECTIVE COATING MATERIAL. THE COPOLYMER CONTAINING AMINOALKYLESTERALKYLSILANE UNITS IS THE PRIMARY INGREDIENT OF A DETERGENT RESISTANT CAR POLISH.

    AMINOALKYLESTERALKYLSILANES OF THE FORMULA:

    (R-)A-SI(-X)(3-A)-C(-R'')2-CH(-R'')-(C(-R'')2)B-COO-

    (C(-R'')2)C-CH2-NH2

    ARE MADE BY HYDROGENATING THE CORRESPONDING NITRILE. A COMPOUND WITHIN THE SCOPE OF THE FORMULA,

    (R-)A-SI(-X)(3-A)-C(-R'')2-CH(-R'')-(C(-R'')2)B-COO-

    (C(-R'')2)C-Z

    Silyl cyanurates
    5.
    发明授权
    Silyl cyanurates 失效
    硅橡胶

    公开(公告)号:US3896123A

    公开(公告)日:1975-07-22

    申请号:US32477873

    申请日:1973-01-18

    Applicant: GEN ELECTRIC

    CPC classification number: C08K5/3477 C08K5/34924 C08L83/04

    Abstract: A self-bonding, heat-vulcanizable silicone rubber composition comprising (a) an organopolysiloxane polymer of the formula RaSiO(4 a)/2, (b) a curing catalyst, and (c) an additive selected from cyanurates, isocyanurates, silyl-cyanurates and silylisocyanurates, where R is selected from monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, a varies from 1.95 to 2.01. There may also be present in the above composition a process aid and a filler, as well as other ingredients.

    Polyaminoalkylthioalkyl silanes
    7.
    发明授权
    Polyaminoalkylthioalkyl silanes 失效
    聚氨基甲酰基硅烷

    公开(公告)号:US3700715A

    公开(公告)日:1972-10-24

    申请号:US3700715D

    申请日:1971-08-23

    Applicant: GEN ELECTRIC

    Inventor: BERGER ABE

    CPC classification number: C07F7/182 C08G73/0206 Y10S516/07

    Abstract: WHERE R and R1 are independently selected from monovalent hydrocarbon radicals, R9, R10 and R11 are selected from the class consisting of hydrogen, alkyl radicals and aryl radicals, A is selected from hydrogen, alkyl radicals, aryl radicals and amino alkyl radicals, j varies from 2 to 20, w varies from 1 to 500 and varies from 0 to 2. The novel compounds are useful as flocculants for colloidal organic matter.

    A novel class of silicone compounds of the formula,

    Abstract translation: 一类新型的下式的硅氧烷化合物,其中R 1和R 1独立地选自一价烃基,R 9,R 10和R 11选自氢,烷基和芳基,A选自氢,烷基 ,芳基和氨基烷基,j从2到20变化,w在1到500之间变化,从0变化到2.新化合物可用作胶态有机物的絮凝剂。

    Silicone compounds containing hydrazone functional groups thereon
    8.
    发明授权
    Silicone compounds containing hydrazone functional groups thereon 失效
    含有水合物功能组合物的硅氧烷化合物

    公开(公告)号:US3700711A

    公开(公告)日:1972-10-24

    申请号:US3700711D

    申请日:1971-08-16

    Applicant: GEN ELECTRIC

    CPC classification number: C07F7/18 C02F1/545 Y10S516/07

    Abstract: A new class of silicone compounds of the formula, WHERE R, R1, R20, R21, R22, R23 and R24 are independently selected from hydrogen and hydrocarbon radicals, s varies from 0 to 1 and u varies from 0 to 20, and a is a whole number that varies from 0 to 2. These class of compounds are particularly useful for flocculating colloidal organic matter.

    Abstract translation: 新一类下式的有机硅化合物,其中,R 1,R 2,R 20,R 21,R 22,R 23和R 24独立地选自氢和烃基,其从0变化到1,u在0至20之间变化,a是 这些化合物对于絮凝胶体有机物是特别有用的。

    Functional group containing thioether silanes
    9.
    发明授权
    Functional group containing thioether silanes 失效
    含有硫代硅烷的官能团

    公开(公告)号:US3678089A

    公开(公告)日:1972-07-18

    申请号:US3678089D

    申请日:1970-02-03

    Applicant: GEN ELECTRIC

    Inventor: BERGER ABE

    CPC classification number: C07F7/182 C08L83/04 C08L2666/44

    Abstract: WHERE X is a hydrolyzable radical, R is an organic radical, R'' is a lower alkyl radical, Y is selected from the group consisting of N IS EQUAL TO 2 OR 3 AND A IS EQUAL TO 0 TO 2 INCLUSIVE. Compounds within the scope of the above formulas can be made by reacting an olefinic thioether of the formula: IN THE PRESENCE OF A PLATINUM COMPOUND CATALYST AND BY REACTING IN THE PRESENCE OF A BASIC CATALYST. The compounds are useful as glass sizing agents.

    The disclosure relates to compounds within the scope of the following formulas:

    Abstract translation: 本公开涉及下列化学式的化合物:

    Method for producing silylalkyl mercaptans with silicon hydride groups
    10.
    发明授权
    Method for producing silylalkyl mercaptans with silicon hydride groups 失效
    用硅氢化合物组合生产硅烷醇缩合物的方法

    公开(公告)号:US3632826A

    公开(公告)日:1972-01-04

    申请号:US3632826D

    申请日:1969-01-06

    Applicant: GEN ELECTRIC

    Inventor: BERGER ABE

    CPC classification number: C07F7/1896 C07C327/00 C07F7/0896

    Abstract: SILYLALKYLMERCAPTANS HAVING SILICON HYDRIDE GROUPS ARE FORMED BY REACTING DIOLEFINIC MATERIALS WITH THIOACIDS TO FORM A MONOOLEFINICALLY UNSATURATED COMPOUND HAVING A THIOACID SALT SUBSTITUENT. A SILICON HYDRIDE HAVING, AS AN ADDITIONAL SUBSTITUENT, A REDUCIBLE GROUP, IS ADDED ACROSS THE SINGLE UNSATURATION OF AN OLEFINIC COMPOUND TO FORM AN ORGANOSILICON COMPOUND WITH AN ALKYLTHIOACID SALT GROUP, THIS COMPOUND BEING REDUCED BY AN ALKALI OR ALKALINE EARTH METAL ALUMINUM HYDRIDE, TO CONVERT THE THIOACID SALT TO THE MERCAPTAN GROUP AND THE REDUCIBLE SUBSTITUENTS ON THE SILICON TO HYDRIDE SUBSTITUENTS. THE NOVEL COMPOUNDS ARE USED TO MODIFY RTV COMPOSITIONS.

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