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公开(公告)号：US5451698A
公开(公告)日：1995-09-19
申请号：US264720
申请日：1994-06-23
申请人： Helmut Bahrmann , Peter Lappe , Wolfgang A. Herrmann , Rainer Manetsberger , Guido Albanese , Klaus Bergrath
发明人： Helmut Bahrmann , Peter Lappe , Wolfgang A. Herrmann , Rainer Manetsberger , Guido Albanese , Klaus Bergrath
IPC分类号： B01J21/02 , C07B61/00 , C07F9/50 , C07C309/32
CPC分类号： C07F9/5054
摘要： The sulfonation of arylphosphines, i.e. mono-, di-, oligo- and polyphosphines, which contain at least one aromatic radical capable of being sulfonated, is carried out in the presence of a Lewis acid at 0.degree. to 80.degree. C. The process avoids side-reactions, in particular the formation of phosphine oxides. In treating the sulfonation mixture, the Lewis acid can be removed together with the sulfuric acid.
摘要翻译： 含有至少一个能够被磺化的芳族基团的芳基膦（即单 - ，二 - ，寡 - 和多膦）的磺化在路易斯酸存在下在0-80℃下进行。该方法避免了 副反应，特别是氧化膦的形成。 在处理磺化混合物时，路易斯酸可与硫酸一起除去。
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公开(公告)号：US20050171377A1
公开(公告)日：2005-08-04
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译： 通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。
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公开(公告)号：US07102034B2
公开(公告)日：2006-09-05
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07C45/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译： 通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。
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公开(公告)号：US06864387B2
公开(公告)日：2005-03-08
申请号：US10413014
申请日：2003-04-14
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07C304/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing solutions of sulfonated arylphosphines comprising reacting arylphosphines with oleum, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble organic solvent, reacting the organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solutin of sulfonated arylphosphines to a pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译： 一种制备磺化芳基膦溶液的方法，包括使芳基膦与发烟硫酸反应，用水稀释磺化混合物，用水不溶性有机溶剂的溶液萃取稀释的磺化混合物，将有机相与无机碱溶于水 通过加入酸将所得的磺化芳基膦的水溶液调节至最高达3的pH，并使惰性气体流通过包含磺化芳基膦的水溶液，直到硫从磺化芳基膦的水溶液中不再释放出来。
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公开(公告)号：US20060276669A1
公开(公告)日：2006-12-07
申请号：US11480178
申请日：2006-06-30
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： An aqueous catalyst solution comprising rhodium and an aqueous solution comprising sulfonated arylphosphines by reacting arylphosphines with oleum to form a sulfonation mixture, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble amine in a water-insoluble organic solvent, reacting the resulting water-immiscible organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solution of sulfonated arylphosphines of pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur dioxide is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译： 包含铑的水溶液和包含磺化芳基膦的水溶液，通过使芳基膦与发烟硫酸反应形成磺化混合物，用水稀释磺化混合物，用水不溶性胺在水不溶性的溶液中萃取稀释的磺化混合物 有机溶剂，使得到的与水不混溶的有机相与无机碱在水中的溶液反应，通过加入酸调节得到的pH为3的磺化芳基膦水溶液，并将惰性气流通过水溶液 包含磺化芳基膦的溶液，直到二氧化硫不再从磺化芳基膦的水溶液中释放出来。
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公开(公告)号：US06610881B1
公开(公告)日：2003-08-26
申请号：US09937640
申请日：2001-12-12
申请人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
发明人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
IPC分类号： C07C30900
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： The invention relates to a method for producing sulfonated aryl phosphines by reacting aryl phosphines with oleum. After reacting the aryl phosphines with oleum, the sulfonation mixture is firstly diluted with water and an inert gas stream is then fed through the diluted sulfonation mixture until SO2 is no longer released from the diluted sulfonation mixture. Afterwards, the sulfonation mixture is subsequently processed in a usual manner. The invention also relates to a method for producing solutions of sulfonated aryl phosphines by reacting the aryl phosphines with oleum, diluting the sulfonation mixture with water, extracting the aqueous solution using an organic solution consisting of an amine, and subsequently carrying out a reextraction using an aqueous solution having an inorganic base. According to the invention, the solution containing aqueous sulfonated aryl phosphines is adjusted to a pH value of up to 3 by adding acid, and an inert gas stream is then fed through the aqueous solution until sulfur dioxide is no longer released. The invention additionally relates to an aqueous catalyst solution containing rhodium and an aqueous solution of sulfonated aryl phosphines, treated as defined by the invention, for carrying out the hydroformylation of olefinically unsaturated compounds, and relates to the use thereof for carrying out the same.
摘要翻译： 本发明涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的方法。 在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后将惰性气体流通过稀释的磺化混合物，直到SO 2不再从稀释的磺化混合物中释放出来。 之后，磺化混合物随后以常规方式进行处理。 本发明还涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的溶液的方法，将磺化混合物与水稀释，使用由胺构成的有机溶液萃取水溶液，然后使用 具有无机碱的水溶液。 根据本发明，通过加入酸将含有磺化芳基膦水溶液的溶液的pH值调至3，然后将惰性气体流通过该水溶液直至二氧化硫不再释放。 本发明另外涉及含有铑的水性催化剂溶液和由本发明定义的磺化芳基膦的水溶液，用于进行烯属不饱和化合物的加氢甲酰化，并涉及其用于进行烯属不饱和化合物的加氢甲酰化。
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公开(公告)号：US06740773B2
公开(公告)日：2004-05-25
申请号：US10160780
申请日：2002-06-03
申请人： Hans Bohnen , Thomas Klein , Klaus Bergrath
发明人： Hans Bohnen , Thomas Klein , Klaus Bergrath
IPC分类号： C07C6974
CPC分类号： C07C67/303 , C07C2601/14 , C07C69/75
摘要： The invention relates to a process for preparing cyclohexanedicarboxylic esters (hexahydrophthalic diesters) by esterifying the corresponding benzenedicarboxylic acids and immediately hydrogenating the esterification mixture in the presence of nickel catalysts.
摘要翻译： 本发明涉及通过酯化相应的苯二甲酸并在镍催化剂存在下立即使酯化混合物加氢来制备环己烷二羧酸酯（六氢邻苯二甲酸二酯）的方法。
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公开(公告)号：US6137013A
公开(公告)日：2000-10-24
申请号：US211937
申请日：1998-12-15
CPC分类号： C07C45/86
摘要： A method of stabilizing aliphatic C.sub.3 -C.sub.14 -aldehydes against polymerization and autocondensation by the addition of alkaline substances to the aldehydes wherein the alkaline substances used are alkali metal hydroxides, alkaline earth metal hydroxides, alkali metal carbonates, alkaline earth metal carbonates or alkali metal carboxylates which are added to the aldehyde to be stabilized in amounts of 0.05-20 ppm, based on the aldehyde.
摘要翻译： 通过向醛中添加碱性物质来稳定脂肪族C 3 -C 14醛对聚合和自缩合的方法，其中使用的碱性物质是碱金属氢氧化物，碱土金属氢氧化物，碱金属碳酸盐，碱土金属碳酸盐或碱金属羧酸盐 基于醛加入到待稳定的醛中，其量为0.05-20ppm。
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